Kinetic analysis of magnesium aluminate spinel formation: Effect of MgO:Al2O3 ratio and titania dopant

The mechanistic pathway of MgO-Al₂O₃ reaction in solid state to form MgAl₂O₄ spinel was investigated to correlate the kinetic parameters with ratio of reactants (MgO:Al₂O₃) and with the presence of a doping agent, TiO₂. The time-temperature-expansion data of oxide compacts was analyzed using several model free analyses and model based (linear and non-linear) kinetic algorithms. These indicated that spinel formation process can be best described by single step with n-dimensional Avrami equation for every MgO:Al₂O₃ ratio, irrespective of titania dopant. The activation energy (E_a) of the process was proportional to % spinel formed in each system and validated with quantitative XRD analysis. The higher value of Avrami coefficient (n) in 90 wt% Al₂O₃ compositions has been explained with geometric considerations of powder packing. Incorporations of 1% TiO₂ in the MgO: Al₂O₃ oxide compact did not markedly affect the reaction model, frequency factor and Activation energy.     

RH-KTB耐材长寿技术研究及应用

介绍了宝钢RH-KTB工艺条件下RH用镁铬砖的应用和提高浸渍管管龄、下部槽槽龄的方法.     

纳米Fe2O3对镁铬耐火材料烧结及力学性能的影响

在镁铬耐火材料中添加纳米Fe2O3,研究了它对镁铬耐火材料烧结性能与常温力学性能的影响.结果发现,在相同的工艺条件下,加入1%(外加)的纳米Fe2O3即可使镁铬砖的烧成温度降低150℃左右,并在相同烧成温度下能使试样的常温抗折强度和耐压强度大幅度提高.分析认为,在镁铬耐火材料中添加少量纳米级Fe2O3,可促进MgO-FeO固溶体中Cr3+和Al3+含量的提高,增强镁铬砖的直接结合程度,从而提高其力学性能.     

B级钢中频感应熔炼用镁砂坩埚的失效与防护

根据B级钢中频感应熔炼过程中镁砂坩埚的工作环境特点,指出坩埚失效的主要形式:热应力开裂、侵蚀变薄、表层剥落、钢液渗透、表面结渣等,并对其失效机理进行分析。通过调整镁砂的颗粒级配,采用多相复合技术,在坩埚的特定区域使用特定坩埚材料的分区捣筑、合理安排烧结工艺、精心操作、精心修补。从而提高了坩埚使用寿命。     

Effects of Admixtures on the Anti—oxidation Property of MgO／Si3N4 Composite Refractory

The effect of the admixtures of Al and Si metals and B4C and MgAlON compounds on the oxideation of MgO/Si3N4 composite refractory has been studied,which is a promising carbon free refractory for steel-making applicatlon.The four kinds of admixtures can be used as anti-oxidants for Si3N4,ut the mixture of Al and Si achieved the best result .The mixture can not only play the role as antioxidant,but also assist the sintering process and help form dense sintering layer,improving the property of the composite.     

Catalytic Degradation of Nitrobenzene and Aniline in Presence of Ozone by Magnesia from Natural Mineral

In this work, magnesia from natural brucite mineral has been used firstly for catalytic degradation of nitrobenzene and aniline in presence of ozone. Compared with single ozonation, the catalytic ozonation accelerated markedly the degradation of nitrobenzene and aniline. The influences of hydroxyl radical scavengers, pH values, and reaction temperatures on degradation were investigated. It was found that the essential of catalysis was the homogeneous catalysis of hydroxyl ions in water, which accelerated the generation of hydroxyl radicals. As a catalyst, magnesia from natural brucite has supplied an economical and feasible choice for catalytic ozonation of nitrobenzene and aniline in industrial wastewater.     

转炉用快速烧结镁r质投补料

根据转炉大面耐火材料的使用条件 ,研究了影响沥青结合及树脂结合镁质投补料使用性能的主要因素。结果表明 ,控制配入合适溶剂的沥青或树脂的加入量 ,掺加少量外加剂 ,可获得性能良好的修补料。二者相比 ,沥青结合镁质投补料的烧结时间较长 ,容易出现凹坑 ;树脂结合投补料与砖体间的粘结性比沥青的稍差 ,容易出现翘曲。     

Insights into the long-term stability of the magnesia modified H-ZSM-5 as an efficient solid acid for steam reforming of dimethyl ether

The long-term performance of the bifunctional catalyst composed of MgO-modified H-ZSM-5 and Cu/ZnO/Al₂O₃ for steam reforming of dimethyl ether (SRD) is studied under the same conditions. Although the surface chemical state and acid property of 1.55–2.47 wt% MgO modified H-ZSM-5 are almost the same, a significant impact of MgO contents on the stability of the bifunctional catalyst is observed from the 50 h SRD results. The initial dimethyl ether conversion (around 100%) and H₂ yield (∼95%) over the optimal bifunctional catalyst with 2.17 wt% MgO modified H-ZSM-5 is still kept over 90% at 50 h. Combining the characterization data of spent catalysts and SRD results, the synergetic effect between the MgO-modified H-ZSM-5 and Cu/ZnO/Al₂O₃ is rigorously revealed as the key factor in determining the stability of the bifunctional catalyst for SRD. These results demonstrate that MgO-modified H-ZSM-5 is a promising and efficient solid acid for SRD.     

镁质晶须对油井水泥石力学性能的影响

为提高油井水泥石强度,选用镁质晶须MBW为增强剂,研究了MBW在不同掺量下对水泥浆体的基本性能及水泥石力学性能的影响,并通过XRD、MIP及SEM等表征方法进行了探讨。结果表明,油井水泥中掺入1%~5%的镁质晶须后,其浆体密度及凝结时间基本不变;流动度随晶须掺量的增加而降低,通过加入减阻剂USZ来改善;水泥石的抗压强度、抗折强度随晶须掺量的增加得到明显提高,当晶须掺量为4%时,80℃下水泥石1、3、7和28 d抗压强度比净浆水泥石分别提高8.3%、15.4%、21.5%和18.8%,抗折强度分别提高9.4%、19.4%、13.1%和0.3%。镁质晶须属于惰性微填料,可填充水泥石内部的有害孔隙,增加水泥石密实度,同时作为微纤维,在水泥石内部通过桥连、拔出、剥离、折断等作用机制起到对水泥石增强增韧的双重功效。     

Reconstruction and hydration of hydrotalcite response to thermal activation temperature: Enhancement of properties for magnesia castables

Optimization binding system for refractory castables is significant to enhance the service performance. Hydrotalcite has been considered a promoter for high-temperature performance of basic castables, however, its binding property remains to be improved before practical application. In this work, the thermal activated Mg–Al hydrotalcites were incorporated in magnesia castables, and the mutual influence of pre-calcination temperature on the hydration, microstructure, and strength of castables was investigated. The obtained results indicated that the reconstruction of calcined hydrotalcite took place in the hydration process and effectively motivated the hydrolysis. Hydrate was thus promoted and a relatively dense microstructure of magnesia castables was confirmed by X-ray computed tomography analysis. Hydrotalcite pre-calcinated at 300 °C contributed to the highest early strength for castable, and the high-temperature properties also performed better than that of other pre-calcinated hydrotalcite-adding. The enhancement mechanisms of calcined hydrotalcite were attributed to the two following reasons: (ⅰ) the modified microstructure of magnesia castables from the early stage by hydration process, (ⅱ) the further enhanced sinterability inspired by the appropriate thermal activation effect.