菱镁矿固硫特性的理论分析

对菱镁矿在固体燃料燃烧过程中的固硫特性进行了理论研究，所得结论对进一步将菱镁矿作为固体燃料燃烧过程中的固硫剂具有非常重要的意义。     

十二烷基磷酸酯作为捕收剂浮选分离菱镁矿与白云石的探索

通过对菱镁矿及其主要伴生脉石矿物白云石性质的研究可知：探讨用阴离子表面活性剂──十二烷基磷酸酯作为捕收剂浮选分离菱镁矿和白云石的可能性很有意义。在本论文实验中，首先用十二醇、三氯氧磷为主要原料合成了十二烷基磷酸酯，研究了它对菱镁矿和白云石的捕收作用；并探讨了配合使用水玻璃作为抑制剂，用十二烷基磷酸脂作为捕收剂，浮选分离菱镁矿与白云石分离的可能性和条件。     

Fabrication of high-density magnesia using vacuum compaction molding

High-density magnesia was fabricated using vacuum compaction molding, and effects of forming pressure and sintering temperature on bulk density, apparent porosity, diameter shrinkage ratio, volume shrinkage ratio, pore size distribution, cold compressive strength, and thermal shock resistance of the magnesia samples were investigated. There were two ranges of pore distribution in samples that were formed via conventional compaction molding, and these ranges were about 350–2058 nm and 6037–60527 nm. It was considered that the range of larger pores mainly influenced the densification of magnesia. Using vacuum compaction molding, large size pores were removed, and high-density magnesia (with a density greater than 3.40 g cm^?3) was easily prepared when forming pressure was higher than 200 MPa and sintering temperature was higher than 1600 °C. Magnesia samples prepared via vacuum compaction molding showed better performance compared to that of samples prepared via conventional compaction molding.     

菱镁矿粉体颗粒摩擦荷电实验与仿真研究

为了对粉体颗粒摩擦荷电过程进行数值模拟,以菱镁矿粉体颗粒为研究对象,利用离散元模型和电荷转移模型对粉体颗粒运动过程和摩擦荷电过程分别进行理论建模。在EDEM仿真软件中建立了适用于粉体颗粒摩擦荷电仿真的计算模块,并应用该模块进行菱镁矿粉体摩擦荷电仿真分析,考察给料量和滑槽倾斜角度对摩擦荷质比的影响,同时利用振动槽摩擦荷电装置进行菱镁矿粉体颗粒摩擦荷电对比实验研究。结果表明,菱镁矿粉体摩擦荷质比随给料量的增加而减小,随滑槽倾斜角度的增大而减小。试验结果得到了与仿真结果相似的变化趋势,验证了所建粉体颗粒摩擦荷电数值模型的准确性。本文研究结果对更精确粉体颗粒摩擦荷电模型的建立和粉体颗粒摩擦带电的进一步应用具有重要意义。     

用蛇纹石等生产耐火材料的试验研究

以蛇纹石、白云石为原料,根据不同的饱和系数配料,并加入一定的稳定剂,在1200～1300℃煅烧,制得稳定的镁钙质耐火材料。经X-射线衍射分析证实所得矿物为MgO和C2S等,耐火度达到1680℃以上。     

菱苦土模型在铸造生产中的应用

简要介绍了菱苦土模型的制作流程 ,并介绍了铸造生产中采用菱苦土模型的工艺优势和经济优势     

From magnesite directly to lightweight closed-pore MgO ceramics: The role of Si and Si/SiC

Partial/full replacement of traditional dense refractory aggregates (for furnace lining) with lightweight aggregates is considered to be an effective and promising strategy for energy saving and emission reduction. In this work, lightweight magnesia refractory ceramics with tailored closed porosity were prepared by one-step sintering at 1600 °C from high-purity magnesite added with silicon kerf waste in different ratios, with the emphasis on the evolution of their phase compositions, micromorphologies, and various properties. With the addition of additives, Mg_2–xFe_xSiO₄ solid solution was formed at the grain boundaries of the MgO matrix, and then the volumetric expansion effect (interfacial reaction) and activated sintering effect (vacancy defect) promote the decrease of apparent porosity and the increase of closed porosity, respectively. Consequently, MgO ceramics with apparent/closed porosity of 0.6%/6.5%, bulk density of 3.25 g cm⁻³, and lightweight index of 7.8% were successfully prepared, suitable for the working lining of metallurgical furnaces.     

回转窑烧成带镁铬砖的使用与窑衬寿命的关系

根据回转窑烧成带镁铬砖的损坏机理，找出提高窑衬周期的具体措施，阐明水泥生产过程中回转窑烧成带镁铬砖的使用与窑衬寿命的关系。     

Effect of fluxing agents on reduction degradation behaviour of hematite pellets

During induration at a high temperature, a considerable amount of slag/melt phase forms inside the iron ore pellets, comprising SiO₂, Al₂O₃, CaO, MgO and FeO. After cooling, the slag phase solidifies and acts as an important bonding phase in the finished pellets and influences their room temperature as well as high temperature properties, especially reduction degradation. Fluxing agents play an important role in forming these bonding phases depending on the type and amount of flux. In the present study, the effect of different fluxing agents, namely, limestone, dolomite, magnesite and pyroxenite, on melt formation and microstructure during induration and on reduction degradation behaviour during reduction was examined. From the results, it was understood that to reduce the disintegration during reduction it is essential to increase the amount and distribution of bonding phases like silicates, which are more stable as compared to oxide phases like hematite. Acid pellets exhibited highest reduction degradation due to the presence of more hematite bonds and less silicate bonds. In limestone fluxed pellets, reduction degradation index dropped considerably with increasing CaO content due to the formation of more amount of bonding phase. Dolomite–pyroxenite pellets, on the other hand, showed lower reduction degradation index up to 0.4 basicity, and beyond that, higher degradation was observed due to the increased pore size, which resulted in poor strength of the reduced pellet matrix and hence more degradation. Low reduction degradation observed in pyroxenite and magnesite fluxed pellets could be due to the formation of magnesioferrite and silicate melt, which are more stable phases compared to hematite.     

影响镁炭质捣打料导电性的因素

研究了不同热处理温度下,石墨含量及颗粒尺寸、结合剂加入量及种类和金属粉末对镁炭质干式捣打料导电性能的影响。认为随着热处理温度的提高,捣打料的电阻率降低。经800℃以上处理的某些材料,其电阻率可达到10-4·m;石墨含量增大,电阻率下降;酚醛树酯是导电材料的良好结合剂,但引入部分沥青,亦能满足实用要求;金属粉末对导电性的提高无明显贡献。