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排序方式: 共有656条查询结果,搜索用时 31 毫秒
1.
The methanol‐to‐olefins reaction (MTO) was studied in a small‐scale fluidized‐bed reactor over synthesized silicoaluminophosphate (SAPO‐34) catalysts. Mesoporous nanocrystalline SAPO‐34 molecular sieves were synthesized hydrothermally by ultrasonic and microwave‐assisted aging processes in the presence of hexadecyltrimethylammonium bromide (CTAB) and tetradecyldimethyl(3‐trimethoxysilylpropyl)ammonium chloride (TPOAC) as surfactant agents. The Box‐Behnken experimental design method was applied to determine the optimum operating parameters of this process conducted in the fluidized‐bed reactor. The optimum conditions in terms of reaction temperature, ratio of inlet gas velocity to minimum fluidizing velocity, and MeOH weight fraction were evaluated. 相似文献
2.
Vinit D. Makwana L. Javier Garces Jia Liu Jun Cai Young-Chan Son Steven L. Suib 《Catalysis Today》2003,85(2-4):225-233
Manganese oxides having a tunnel structure (OMS-2) have been utilized as selective catalysts for alcohol oxidation. In this study manganese oxide catalysts were synthesized in different media and modified by exchanging the tunnel cation by H+, using acid treatment or exchanging with NH4+ followed by thermolysis. Various alcohol oxidations were performed using these catalysts to ascertain the influence of synthesis method on their activity. A correlation is made between lattice oxygen instability and activity of the catalysts, which indicates involvement of the lattice oxygen in the mechanism. The exchange of the tunnel cation with the smaller H+ ions leads to weakening of the Mn–O bond, as verified by temperature programmed desorption (TPD) results. Only the chemisorbed oxygen on the surface (O−) and the lattice oxygen in the layers close to the surface is involved in the oxygen transfer during the reaction. 相似文献
3.
Anjana Bhattacharya Jagannath Das Swapan Mitra Sisir K. Roy 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1992,54(4):399-407
Silicoaluminophosphate (SAPO-5) molecular sieves have been synthesised from reaction mixtures having a molar composition of: 0.7–1.0 Al2O3:0.7–1.0 P2O5:0.01–2.0 SiO2:xR:40 H2O (where R = (C2H3)3N or (C2H3)4NOH and x = 1.5–2.5 for (C2H5)5N and 0.5 for (C2H5)4NOH, at 473 K using various sources of alumina and silica. The effects of (i) varying the crystallinity of the alumina source (boehmite) and (ii) the use of different silica sources such as freshly prepared silica either from sodium silicate or paddy husk extract, silica gel from commercial water-glass, and tetraethyl orthosilicate have been studied. The crystallinity of boehmite has been found to have a strong effect on its reactivity towards the formation of SAPO-5. The activity of boehmite for SAPO-5 formation increased with a decrease in its crystallinity (or with increase in its moisture content). Any silica source devoid of sodium ions could be employed for the synthesis of SAPO-5. The process of crystallisation started as early as within 1.5 h of reaction and incorporation of silicon into the AlPO4 framework has been noted at this stage. Formation of some tridymite phase as impurity has been observed under conditions such as (i) SiO2 concentration > 1.7 mole and (ii) x > 2.0 when R = (C2H5)3N. 相似文献
4.
近年来铈(Ce)基脱硝催化剂成为低温脱硝领域的研究热点,按载体类型可分为金属氧化物催化剂、二氧化钛载体催化剂、分子筛载体催化剂、活性炭及氧化铝载体催化剂等。按催化剂种类分别介绍了掺杂改性、制备工艺、反应条件等对催化剂性能的影响,并阐述了可能的原因机理。目前,铈基催化剂大多处于实验室阶段,工业化应用尚存在问题,尤其作为低温脱硝催化剂,活性中心堵塞问题更加突出,并且催化剂成本较高。未来可从催化剂制备工艺入手解决催化剂成型问题,以实现工业应用。同时探讨催化剂中毒机理,进一步提升其抗中毒能力。另外,寻求适宜的材料与铈掺杂组合,达到高效脱硝和经济效益最大化。 相似文献
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Carbon membranes from cellulose and metal loaded cellulose 总被引:1,自引:0,他引:1
Jon Arvid Lie 《Carbon》2005,43(12):2600-2607
The focus of this work was to find a low-cost precursor for carbon molecular sieve (CMS) membranes, and a simple way of producing them. In addition, several ways of modifying a carbon material are described. The modification method used in this study was metal doping of carbon. CMS membranes were formed by vacuum carbonization of cellulose and metal loaded cellulose. Metal additives include oxides of Ca, Mg, Fe(III) and Si, and nitrates of Ag, Cu and Fe(III).The carbon membrane containing Fe-nitrate has promising separation performance for the gas pairs O2/N2 and CO2/CH4. Carbon containing nitrates of Cu or Ag show high selectivity, but reduced O2 and CO2 permeability compared to carbon with Fe-nitrate. Element analysis indicates that Cu migrates to the carbon surface, creating an extra layer resistance to gas transport. A silver mirror is also seen on the surface of Ag-nitrate-containing carbon. However, the Ag- and Cu-containing membranes show a high H2 permeability. Adding metal oxides makes the carbon membranes retard the transport of easily condensable gases (e.g. CO2). This can be exploited for enhanced H2/CO2 separation efficiency. 相似文献
9.
碳沉积法制富氮用炭分子筛的研究 总被引:1,自引:0,他引:1
本文提出的碳沉积法是用煤焦油馏分油的有机溶液浸渍煤炭化物,然后热解以进行“孔调变”。确定了最佳工艺条件,制得富氮性能良好的炭分子筛。并用D-A方程求取了各种样品的微孔结构参数。 相似文献
10.
环己烷催化氧化催化剂的研究进展 总被引:1,自引:0,他引:1
综述了国内外环己烷选择性氧化催化剂的研究进展,对目前环己烷氧化所用催化剂体系进行了总结及比较分析,重点介绍了分子筛催化剂体系中TS-1、MCM、SBA-15等分子筛催化体系. 相似文献