全文获取类型
收费全文 | 3162篇 |
免费 | 154篇 |
国内免费 | 40篇 |
专业分类
电工技术 | 32篇 |
综合类 | 77篇 |
化学工业 | 1453篇 |
金属工艺 | 86篇 |
机械仪表 | 48篇 |
建筑科学 | 200篇 |
矿业工程 | 28篇 |
能源动力 | 328篇 |
轻工业 | 165篇 |
水利工程 | 59篇 |
石油天然气 | 82篇 |
武器工业 | 5篇 |
无线电 | 55篇 |
一般工业技术 | 395篇 |
冶金工业 | 153篇 |
原子能技术 | 52篇 |
自动化技术 | 138篇 |
出版年
2024年 | 5篇 |
2023年 | 38篇 |
2022年 | 62篇 |
2021年 | 70篇 |
2020年 | 79篇 |
2019年 | 53篇 |
2018年 | 68篇 |
2017年 | 65篇 |
2016年 | 61篇 |
2015年 | 52篇 |
2014年 | 106篇 |
2013年 | 131篇 |
2012年 | 154篇 |
2011年 | 257篇 |
2010年 | 171篇 |
2009年 | 195篇 |
2008年 | 182篇 |
2007年 | 201篇 |
2006年 | 194篇 |
2005年 | 184篇 |
2004年 | 153篇 |
2003年 | 149篇 |
2002年 | 91篇 |
2001年 | 89篇 |
2000年 | 100篇 |
1999年 | 81篇 |
1998年 | 82篇 |
1997年 | 57篇 |
1996年 | 33篇 |
1995年 | 41篇 |
1994年 | 30篇 |
1993年 | 16篇 |
1992年 | 18篇 |
1991年 | 27篇 |
1990年 | 24篇 |
1989年 | 10篇 |
1988年 | 8篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 4篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有3356条查询结果,搜索用时 15 毫秒
1.
《Ceramics International》2022,48(14):20062-20069
Photocatalytic N2 fixation is a promising and sustainable manufacturing process of ammonia (NH3); however, the NH3 production rate by this method is very low, thus severely restricting further application of this sustainable technology. Therefore, developing an efficient photocatalyst for N2 fixation under mild conditions is urgently required. Herein, ferroelectric Bi2WO6 materials with different surface oxygen defects were prepared, and the concentration of corresponding defects was controlled by adjusting the thermal reduction time. The abundant oxygen defects in Bi2WO6 can provide more reactive sites to promote the effective adsorption of N2, and the photogenerated charge carrier can be efficiently separated benefiting from the internal electric field. These would weaken the N2 triple bond and reduce the activation energy barrier for the conversion of N2 to NH3 under mild conditions. In the absence of sacrificial agents and cocatalysts, the optimized Bi2WO6 with oxygen defects shows an indigenous NH3 yield of 132.175 μmol·g-1·L-1·h-1, which is more than two times higher than that of the original Bi2WO6. Surprisingly, the Bi2WO6 with oxygen defects produced more than eight times NH3 (471.13 μmol·g-1·L-1·h-1) than that of the original Bi2WO6 when assisted by an external magnetic field, thus providing a new perspective for further enhancing the N2 fixation performance. 相似文献
2.
《International Journal of Hydrogen Energy》2019,44(11):5189-5202
Independent hydrogen production from petrochemical wastewater containing mono-ethylene glycol (MEG) via anaerobic sequencing batch reactor (ASBR) was extensively assessed under psychrophilic conditions (15–25 °C). A lab-scale ASBR was operated at pH of 5.50, and different organic loading rates (OLR) of 1.00, 1.67, 2.67, and 4.00 gCOD/L/d. The hydrogen yield (HY) progressed from 134.32 ± 10.79 to 189.09 ± 22.35 mL/gMEGinitial at increasing OLR from 1.00 to 4.00 gCOD/L/d. The maximum hydrogen content of 47.44 ± 3.60% was achieved at OLR of 4.0 gCOD/L/d, while methane content remained low (17.76 ± 1.27% at OLR of 1.0 gCOD/L/d). Kinetic studies using four different mathematical models were conducted to describe the ASBR performance. Furthermore, two batch-mode experiments were performed to optimize the nitrogen supplementation as a nutrient (C/N ratio), and assess the impact of salinity (as gNaCl/L) on hydrogen production. HY substantially dropped from 62.77 ± 4.09 to 6.02 ± 0.39 mL/gMEGinitial when C/N ratio was increased from 28.5 to 114.0. Besides, the results revealed that salinity up to 10.0 gNaCl/L has a relatively low inhibitory impact on hydrogen production. Eventually, the cost/benefit analysis showed that environmental and energy recovery revenues from ASBR were optimized at OLR of 4.0 gCOD/L/d (payback period of 7.13 yrs). 相似文献
3.
《International Journal of Hydrogen Energy》2020,45(1):1151-1157
The paper presents a calculated analysis of the equilibrium emission of nitrogen oxides on the exhaust of carburetor and diesel internal combustion engines. The temperature of fuel oxidation is assumed to be 1,400 °C while the pressure for carburetor and diesel engines is assumed to be 60 atm and 80 atm respectively. The studies have been carried out for natural and synthetic fuels such as hydrogen, ethanol, methanol, petroleum, diesel fuel and methane at the excess air coefficient corresponding to the fuel oxidation temperature of 1,400 °C. In the paper, the method for calculating the equilibrium composition based on the equilibrium constant and mass conservation equations has been applied. It is shown that with an increase in pressure from 1 atm to 60 atm for carburetor engines and up to 80 atm for diesel engines, the reaction of nitrogen dioxide formation may shift towards an increase in NO2. The formation of NO may be not affected by the increase in pressure by virtue of the fact that the reaction proceeds without changes in the amount. It has been determined that NO is the major atmospheric pollutant. However, it would be advisable to use more extensively the fuels characterized by the lowest output of nitrogen dioxide (methane and methanol), since nitrogen dioxide (NO2) related to the 2nd hazard class is appeared to be the most dangerous to humans. It has been revealed that the reduction in oxidation temperature using hydrogen as a fuel for electrochemical current generators may allow reducing nitrogen oxide emissions by more than an order of magnitude as compared to the best results for ICE. 相似文献
4.
5.
NBR/PP热塑性弹性体研究进展 总被引:12,自引:0,他引:12
阐述了NBR/PP共混热塑性弹性体动态硫化胶的国内外研究进展、微观相态结构、性能、应用及展望。 相似文献
6.
7.
The effects of NOx on the performance of proton exchange membrane (PEM) fuel cell were investigated through the introduction of a mixture containing NO and NO2, in a ratio of 9:1, into the cathode stream of a single PEM fuel cell. The NOx concentrations used in the experiments were 1480 ppm, 140 ppm and 10 ppm, which cover a range of three orders. The experimental results obtained from the tests of durability, polarization, reversibility and electrochemical impedance spectroscopy (EIS) showed a detrimental effect of NOx on the cell performance. The electrochemical measurements results suggested that the impacts of NOx are mainly resulted from the superposition of the oxygen reduction reaction (ORR), NO and HNO2 oxidation reactions, and the increased cathodic impedance. Complete recovery of the cell performance was reached after operating the cell with clean air and then purging with N2 for hours. 相似文献
8.
SVK8 3S型氮气压缩机是由沈阳鼓风机厂制造、为义马煤气配套的低压氮气压缩机 ,共两套 ,于 2 0 0 0年 1 2月开始调试。为节约工程基建资金 ,取消原设计两台中压氮气压缩机 ,由杭氧产两台3TYS89+2TYS60型氧气透平压缩机临时压送氮气 ,向外供中压氮 ,来取代中压氮气压缩机 ,流程示意图如图 1所示。图 1 氧、氮压机工艺流程配置图1 事故情况2 0 0 0年 1 2月 2 7日中午 1 1∶3 5 ,接总调度室通知 ,要求中午 1 2∶0 0向长输管线供中压氮气。当时 ,一台氮压机试车完毕正在运行 ,一台氧压机试车完毕压氧正在运行 ,将由氧压机临时压送氮气外供… 相似文献
9.
E. M. Abdel-Bary H. H. Hassan A. M. El-Lawindy M. K. Abu-Assy F. K. El-Tantawy 《Polymer International》1993,30(3):371-374
Butyl rubber mixtures loaded with 70 phr general purpose furnace black (GPF) and tetramethyl thiuram disulphide (TMTD)/S as vulcanizing system were prepared. The kinetics of their electrical conductivity development during the vulcanization process were followed by using an especially devised system. It was found that the increase in the electrical conductivity during vulcanization obeys an exponential growth function with time constant τ, which markedly decreases with increasing vulcanization temperature as well as with the efficiency of the vulcanizing system. After completion of the vulcanization process, about 80 min, the samples obtained possess reasonable stability and reproducibility of electrical conductivity. 相似文献
10.
本文总结了近年冶金炉渣氮酸盐容量的研究方法,氮在炉渣中存在形态与炉渣氧分压的关系,炉渣氮化物容量与温度及炉渣成分的关系,并给出设计钢液脱氮渣系的基本原则。 相似文献