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研究了Fe(Ⅲ)-5-Br-PADAP-Triton x-100析相显色体系,建立了测定痕量铁的析相光度法。实验表明,在pH=9.0硼酸-氢氧化钠介质中,Fe(Ⅲ)-5-Br-PADAP-Triton x-100在95℃加热1h形成的配合物被Triton x-100相完全富集,配合物最大吸收波长为556nm,表观摩尔吸光系数为7.10×10~4L·mol~(-1)·cm~(-1),铁含量在0~3.6×1.5~(-5)mol·L~(-1)范围内符合比尔定律,以EGTA、乙二胺、亚氨基二乙酸为联合掩蔽剂,测定人发、面粉中的痕量铁,获得满意结果。 相似文献
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研究了在乳化剂OP存在下,利用5-Br-PADAP测定电镀废水中微量锌的显色条件。实验表明,在P来7.5-10.0硼酸-硼酸钠缓冲溶液中,锌与5-Br-PADAAP,乳化剂OP形成紫红色3元配合物,其λmax=552nm,∑552=1.3*10^5L/mol cm配位比为1:2,在0-25μg/50mL服从朗伯-比一律。该方法应用于电镀废水微量锌的测定具有灵敏度高,准确度好,操作简便安全,快速的特 相似文献
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煤矸石中痕量钍的光度法测定 总被引:1,自引:1,他引:0
研究了 2 (5 溴 2 吡啶偶氮 ) 5 二乙氨基苯酚 (5 Br PADAP)作为微量钍的显色剂。在pH 5 .0的HAc NaAc缓冲体系中和非离子OP乳化剂的存在下 ,5 Br PADAP和钍 (Ⅳ )的络合物在λmax=5 85nm处的表观摩尔吸光系数为 1.3 5× 10 5L·mol- 1 ·cm- 1 。钍 (Ⅳ )的质量浓度在 0~ 0 .5 0mg·L- 1 范围内符合比耳定律。钍的加标回收率在 98.5 %~ 10 3 .6%之间 ,结合PMBP萃取分离 ,可用于测定煤矸石中的微量钍 相似文献
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Krishankant Singh Chetan Shah Charu Dwivedi Manmohan Kumar Parma N. Bajaj 《应用聚合物科学杂志》2013,127(1):410-419
Polyacrylonitrile beads, containing the amidoximated polyacrylonitrile, were prepared for adsorption of uranium. The synthesized amidoximated polyacrylonitrile chelating beads were evaluated, for their ability to adsorb uranium from aqueous solution, at different temperatures and pH values. The kinetic measurement showed that about 120 min of equilibration time was enough, to remove saturation amount of uranium from the solution. The pseudo first‐order and pseudo second‐order equations were used to analyze the kinetic data, and the rate constants were determined. The equilibrium adsorption data were examined by the Langmuir, Freundlich, and Temkin isotherms. The data showed a better fit to the Langmuir isotherm. The loaded uranium could also be leached out from the beads, by treating with dilute acids. The uranium uptake capacity of the polymeric beads was found to be 3.5 mg/g of the swollen beads. Reusability of the beads was also established by multiple adsorption–desorption experiments. The pore volume and the surface area of the dried beads, measured by BET method, were found to be 1.93 cc/g and 320 m2/g, respectively. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
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DeterminationofMicroamountofScandiuminRareEarthWenMeijuanandLengChunhua(温美娟)(冷春华)DepartmentofChemistry,UniversityofScienceand... 相似文献
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