Photo-Fenton removal of water-soluble polymers

This paper presents the results of experiments carried out in a laboratory-scale photochemical reactor on the photodegradation of different polymers in aqueous solutions by the photo-Fenton process. Solutions of three polymers, polyethyleneglicol (PEG), polyacrylamide (PAM), and polyvinylpyrrolidone (PVP), were tested under different conditions. The reaction progress was evaluated by sampling and analyzing the total organic carbon concentration in solution (TOC) along the reaction time. The behavior of the different polymers is discussed, based on the evolution of the TOC–time curves. Under specific reaction conditions, the formation and coalescence of solid particles was visually observed. Solids formation occurred simultaneously to a sharp decrease in the TOC of the liquid phase. This may be favorable for the treatment of industrial wastewater containing polymers, since the photodegradation process can be coupled with solid separation systems, which may reduce the treatment cost.     

薄板坯连铸生产SS400钢工艺技术研究

对唐钢薄板坯连铸机生产的SS400钢的生产工艺进行了分析,认为薄板坯连铸机生产的SS400钢,在采取了精炼站在线定氧,将钢水全氧控制在25×10~(-6)左右,同时连铸采取保护浇注和轻压下等技术后,能够确保薄板坯连铸SS400钢的顺利浇注,轧制的板带材表面质量良好,机械性能符合要求。     

混酸PEG酯的合成及性能研究

用从大豆油脚水解制得的脂肪酸合成混酸聚乙二醇酯，通过测定酸值的方法确定了最佳反应时间为16h。与油酸聚乙二醇酯相比，混酸聚乙二醇酯具有更优良的乳化性、润湿性，可以替代油酸聚乙二醇酯用于纺织、农药和化妆品工业中。     

酸催化二甘醇脱水环化反应研究

以硫酸、磷钨酸、ZRP-5分子筛为催化剂,研究了二甘醇(DEG)脱水环化的反应规律。结果表明,DEG发生分子内脱水环化反应,生成1,4-二氧六环(DOX),DEG分子间脱水不仅可以生成四甘醇、六甘醇等,同时可生成三甘醇、五甘醇等一系列的多甘醇(PEG)。不仅DEG可以脱水环化生成DOX,在反应中生成的PEG也同样可以进行生成DOX的反应。对于二甘醇(DEG)脱水环化反应,硫酸是性能优良的催化剂,反应可以在较低的温度下进行,馏出产物中DOX选择性大于95％。     

龙滩工程按正常蓄水位400m方案一次建成效益巨大

2003年11月龙滩工程将实现大江截流，随着工程建设的全面推进，越发显出实施龙滩水电站正常蓄水位400m一次建成方案的重要性和紧迫性。相对分期建设而言，400m水位一次建成，工程效益大、增加投资少、无后期加高过程中的各种技术难题，基本不影响电站的初期发电效益，水轮机设计与运行问题少、机组运行条件好，电站规模效益与社会综合效益巨大，有利于移民安置和库区经济的发展，对国家、地方、企业均十分有利，因此应尽快决策实施400m一次建成方案。     

分组交换网上的增值业务

本文介绍了公用和专用分组交换数据网的现状后，说明了开展标准的增值业务系统的重要性。论述了典型的增值业务系统－电子邮件和传真存储转发系统。     

HRB400月牙型螺纹钢筋试制

本文详细介绍了包钢采用平炉冶炼工艺试制HRB400钢筋的生产过程和检验结果，对试制中出现的问题提出了改进措施，并初步研究了稀土对HRB400钢筋质量与性能的影响。结果表明，采用平炉冶炼工艺可生产出符合GBl499—1988的HRB400钢筋。本次试验研究尚未看出稀土对HRB400钢筋的质量与性能产生明显影响。     

Synthesis and applications of heterobifunctional poly(ethylene oxide) oligomers

Poly(ethylene oxide) (PEO) oligomers are employed extensively in pharmaceutical and biomedical arenas mainly due to their excellent physical and biological properties, including solubility in water and organic solvents, lack of toxicity, and absence of immunogenicity. PEO can be chemically modified and reacted with, or adsorbed onto, other molecules and surfaces. Sophisticated applications for PEO have increased the demand for PEO oligomers with tailored functionalities, and heterobifunctional PEOs are often needed. This review discusses the synthesis and applications of heterobifunctional PEO oligomers possessing amine, carboxylate, thiol, and maleimide functional groups.     

西门子PLC在合金钢棒材连轧机上的应用

介绍基于西门子S7-400PLC的控制系统,通过Ethernet、Profibus-DP、MPI网完成系统数据的采集、交换与监控,满足合金钢棒材轧制线高动态品质、高调速精度的要求。     

No Direct Postconditioning Effect of Poloxamer 188 on Mitochondrial Function after Ischemia Reperfusion Injury in Rat Isolated Hearts

Myocardial infarction is a leading cause for morbidity and mortality worldwide. The only viable treatment for the ischemic insult is timely reperfusion, which further exacerbates myocardial injury. Maintaining mitochondrial function is crucial in preserving cardiomyocyte function in ischemia reperfusion (IR) injury. Poloxamer (P) 188 has been shown to improve cardiac IR injury by improving cellular and mitochondrial function. The aim of this study was to show if P188 postconditioning has direct protective effects on mitochondrial function in the heart. Langendorff prepared rat hearts were subjected to IR injury ex-vivo and reperfused for 10 min with 1 mM P188 vs. vehicle. Cardiac mitochondria were isolated with 1 mM P188 vs. 1 mM polyethylene glycol (PEG) vs. vehicle by differential centrifugation. Mitochondrial function was assessed by adenosine triphosphate synthesis, oxygen consumption, and calcium retention capacity. Mitochondrial function decreased significantly after ischemia and showed mild improvement with reperfusion. P188 did not improve mitochondrial function in the ex-vivo heart, and neither further P188 nor PEG induced direct mitochondrial protection after IR injury in this model.