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考察了温度、振幅、钢球直径等对PVC在振动磨中降解的影响,确定PVC力化学降解为无规断链过程。用力化学方法在振动磨中合成了MMA-PVC共聚物,通过IR和NMR对MMA-PVC共聚物结构进行了鉴定,研究了PVC/MMA配比和振磨时间对共聚反应产率及共聚物组成的影响。热失重分析、SEM观察和冲击强度测定结果表明,MMA-PVC共聚物比PVC具有较高的热稳定性;MMA-PVC共聚物对PVC/PHMA(聚甲基丙烯酸己酯)体系有增容作用 相似文献
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Mehmet Atilla TasdelenMuhammet U. Kahveci Yusuf Yagci 《Progress in Polymer Science》2011,36(4):455-567
Telechelic polymers, defined as macromolecules that contain two reactive end groups, are used as cross-linkers, chain extenders, and important building blocks for various macromolecular structures, including block and graft copolymers, star, hyperbranched or dendritic polymers. This review article describes the general techniques for the preparation of telechelic polymers by living and controlled/living polymerization methods; namely atom transfer radical polymerization, nitroxide mediated radical polymerization, reversible addition-fragmentation chain transfer polymerization, iniferters, iodine transfer polymerization, cobalt mediated radical polymerization, organotellurium-, organostibine-, organobismuthine-mediated living radical polymerization, living anionic polymerization, living cationic polymerization, and ring opening metathesis polymerization. The efficient click reactions for the synthesis of telechelic polymers are also presented. 相似文献
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