高性能透明PU复印机刮板的研制

探讨异氰酸酯、扩链剂、交联剂和聚合工艺对高性能透明PU复印机刮板物理性能、工艺性能和透明性的影响。试验确定 ,以聚四亚甲基醚二元醇 (PTMEG)为主体材料 ,异氰酸酯选用 4,4′ 二苯基甲烷二异氰酸酯 (MDI) ,扩链剂选用 1,4 丁二醇 (1,4 BDO) ,交联剂选用三羟基丙烷 (TMP) ,按PTMEG/MDI/(BDO TMP) (其中BDO/TMP摩尔比为 6 5∶1)摩尔比为 1∶2∶1、预聚反应条件为 (70～ 80 )℃× 0 5h、扩链反应条件为 (12 5～ 13 0 )℃× 1h聚合PU浇注料 ,利用离心浇注成型法制备出透明PU弹性体 ,经机加工可以制得透明性和物理性能好的复印机刮板     

HCFC-141b的生产现状与市场前景

介绍了聚氨酯发泡剂CFC-11的主要替代品HCFC-141b的生产工艺和生产现状,并分析了该产品的市场前景。     

聚氨酯弹性体复合抗磨环的研制

介绍了聚氨酯弹性体复合抗磨环的设计及制作过程，并将该产品应用于挖泥船泥泵中。经过试验证明，该产品比传统的钢质抗磨环耐气蚀、耐磨损，使用寿命可延长3倍以上。     

增强聚氨酯硬泡塑料的冲击性能研究

本文研究了SiO2和纤维增强剂对于聚氨酯硬泡塑料冲击性能的增强效应.试验结果表明,加入SiO2并不能增强聚氨酯硬泡塑料冲击性能.然而以2.5% KH550偶联剂四氢呋喃溶液处理的玻璃纤维作为增强剂,能使聚氨酯硬泡塑料的冲击性能有显著的提高.     

湿法聚氨酯树脂浆料配方的改进

通过对湿法PU合成革用聚氨酯(PU)树脂浆料配方的改进，降低了浆料的生产成本，浆料的后期加工性能提高，并且PU膜的性能也有所改善。     

Preparation of stable polyurethane-polystyrene copolymer emulsions via RAFT polymerization process

Stable polyurethane-polystyrene (PU-PS) copolymer emulsions were prepared by the polymerization of 2-hydroxyethyl acrylate (HEA)-capped PU macromonomer and styrene, using azobis(isobutyronitrile) (AIBN), a radical initiator, and 4-((benzodithioyl)methyl)benzoic acid, a reversible addition-fragmentation chain transfer (RAFT) agent. As the molar ratio of the RAFT agent to AIBN increased, the zeta potential of the resulting copolymer emulsion increased, but the average size and size distribution of the emulsion droplets decreased. A living polymerization of HEA end-capped PU macromonomer and styrene was characterized by a linear increase in the molecular weight and decrease in the molecular weight distribution with consumption of monomers. The tensile strength, hardness and water-resistance of the copolymer films, prepared from the PU-PS copolymer emulsions, were much greater than those of the films prepared from the pure PU emulsion. The copolymer emulsions, prepared via the RAFT polymerization process, are expected to exhibit better storage stability than those prepared via the conventional free radical polymerization process, due to the presence of carboxyl groups derived from the RAFT agent at the PS block termini.     

国外聚氨酯硬泡发泡剂最新进展

零ODP(臭氧消耗能)发泡剂是在聚氨酯硬泡中替代CFCs的新一代发泡剂,阐述了美国、日本、欧洲CFCs替代的现状,并详细介绍了国外零ODP发泡剂的最新进展。     

氨纶氯水降解及耐氯机理的探讨

应用红外光谱分析方法，对氨纶（ＰＵ纤维）氯水降解及耐氯机理进行了初步的研究。结果表明，ＰＵ浸氯水后，因受活性氯原子的攻击，ＰＵ大分子软链段的碳－碳键发生断裂，形成碳－氯化合物，添加剂加入后，因与ＰＵ大分子的软链段形成螯合物，从而避免了活性氯原子的攻击，有效地保护了软链段，使氨纶耐氯性能明显改善。     

德国用环戊烷代替氟里昂（CFC）作为硬质PU泡沫发泡剂的新技术

本文介绍了环戊烷的运输，多元醇／环戊烷混合装置及混合料储存的技术并详细叙述使用环戊烷作为发泡剂的安全方法。     

Preparation and properties of microcapsule with EVA core‐PU shell structure

Microcapsule with poly(ethylene‐co‐vinylacetate) (EVA) core‐polyurethane (PU) shell structure was synthesized by interfacial polymerization in aqueous polyol dispersion with ethylene diamine as the chain extender of toluene diisocyanate in poly(vinyl alcohol) aqueous solution as the stabilizing agent. The effects of polyol constituent on the average particle size and distributions, morphologies, color strength, and friction fastness of core‐shell particles were investigated to design microcapsule. The friction fastness of printed fabrics with EVA core‐PU shell microcapsules became the increase to 4–5 grades. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 893–902, 2007