Structural silicone sealants after exposure to laboratory test for durability assessment

During the service life of structural sealant glazing (SSG) facades, the load-bearing capacity of the silicone bonds needs to be guaranteed. Laboratory tests can assess the durability of SSG-systems based on mechanical characteristics of the bond after simultaneous exposure to both climatic and mechanical loads. This article studies how the material characteristics of two common structural sealants are affected by laboratory and field exposure. Dynamic mechanical analysis (DMA) confirms a reduction in the dynamic modulus of exposed silicone samples. Results from thermogravimetric analysis, Fourier-transform infrared spectroscopy, differential scanning calorimetry, and small-angle X-ray scattering/wide-angle X-ray scattering show differences between the two sealants and indicate no/minor changes in the composition and morphology of the laboratory and field exposed sealants. Mechanical characterization methods, such as DMA, and tensile and shear testing of the structural bond, are shown to be sensitive toward the combined climatic and mechanical loadings, and are hence suitable for studying degradation mechanisms of structural sealants.     

Chromophore-Free Sealing and Repair of Soft Tissues Using Mid-Infrared Light-Activated Biosealants

Poor strength, infection, leakage, long procedure times, and inflammation limit the efficacy of common tissue sealing devices in surgeries and trauma. Light-activated sealing is attractive for tissue sealing and repair, and can be facilitated by the generation of local heat following absorption of nonionizing laser energy by chromophores. Here, the inherent ability of biomaterials is exploited to absorb nonionizing, mid-infrared (midIR) light in order to engender rapid photothermal sealing and repair of soft tissue wounds. In this approach, the biomaterial simultaneously acts as a photothermal convertor as well as a biosealant, which dispenses the need for exogeneous light-absorbing nanoparticles or dyes. Biomechanical recovery, mathematical modeling, histopathology analyses, tissue strain mapping using digital imaging correlation, and visualization of the biosealant-tissue interface using hyperspectral imaging indicate superior performance of midIR sealing in live mice compared to conventional sutures and glue. The midIR-biosealant approach demonstrates rapid sealing of soft tissues, improves cosmesis, lowers potential for scarring, obviates safety concerns because of the nonionizing light used, and allows adoption of a wide diversity of biomaterials. Taken together, the studies demonstrate a novel advance both in biomaterials for surgical sealing along with the use of nonionizing midIR light, with high potential for clinical translation.     

丙烯酸酯单体对聚氯乙烯密封胶粘剂的改性作用

丙烯酸酯有较大的反应活性，能与聚氯乙烯发生接技共聚反应。本文中，我们着重研究不同结构丙烯酸酯单体对聚乙烯基密封胶粘剂的改性作用。以PVC为100份，分别加入甲基丙烯酸一缩二乙二醇双脂（DEGDMA），甲基丙烯酸乙二醇双酯（EGDMA）和丙烯酸一缩二乙二醇双酯（DEGDA）各为10份、20份、30份的试验结果看出，随着丙烯酸酯单体添加量的增加，PVC片基的硬度增大，拉伸强度提高，而伸长率降低。不同的单体其影响也不同。就硬度和拉伸强度有EGDMA＞DEGDA＞DEGDMA的规律伸长率的降低则为DEGDMA＞DEGDA＞EGDMA。就丙烯酸…     

Development of sealing compositions with nanostructure iron-based fillers

The possibility of utilizing nanopowders of iron and Fe-Co-Ni produced bu a thermochemical method in the fabrication of sealing composition materials is investigated. It is established that such hermetic sealing composition materials function reliably under extremal conditions and guarantee elevated strength of adhesion to the surface of the metal and high corrosion and temperature stability. __________ Translated from Poroshkaya Metallurgiya, Nos. 3–4(448), pp. 112–117, March–April, 2006.     

PVC薄膜—尼龙织物复合用胶粘剂的研制

介绍 PVC 薄膜—尼龙织物复合用胶粘剂试制的情况。主要包含胶粘剂主体聚合物、增粘组分、增塑剂、反应促进剂及其它助剂的选择。并阐述了胶粘剂的放大试验情况及应用工艺条件。     

蒙脱土-有机硅复合改性硅烷化聚氨酯密封胶

采用2,4-甲苯二异氰酸酯、聚醚多元醇、蒙脱土、有机硅(α,ω-二羟基聚二甲基硅氧烷)和硅烷偶联剂为原料,制备了有机蒙脱土/聚醚多元醇复合物(OMMT/330N)-有机硅复合改性的硅烷化聚氨酯(SPU)密封胶。通过广角X射线衍射、透射电子显微镜和傅里叶变换红外光谱手段表征了蒙脱土在复合材料中的分散情况,表征结果显示,有机蒙脱土以平均层间距不小于4.12nm的宽分布分散在SPU基体中。同时对密封胶的力学性能进行测试,测试结果表明,经OMMT/330N-有机硅复合改性的SPU密封胶具有性能互补效果,当添加质量分数为5%(基于330N)的OMMT和8%的有机硅时,复合改性的SPU密封胶的拉伸强度和断裂伸长率比纯SPU密封胶提高了65.8%和71.6%。     

Process development and accurate low‐cost characterization for OLED sealants by using a calcium test

Abstract— A calcium measurement setup was built for testing encapsulation especially for OLED applications. This setup is able to measure both reflective and transmissive cells. For the characterization of sealants, a method to compare them with other sealing products will be described. This includes the use of spacers, a homogeneous surface energy, and the geometry of the sealant line. The effects of different geometries will be discussed. The setup was designed to achieve good accuracy at a very reasonable component cost, which will allow other facilities to replicate this setup. Therefore, the construction plan as well as the list of components can be downloaded from our website (Ref. 3).     

多用户MIMO系统低复杂度收发联合波束成形方案

基于多用户多输入多输出(MIMO)有限反馈系统提出了一种收发联合波束成形方法。该方法在发送端采用每个用户酉速率控制(PU2RC)波束成形技术,在接收端采用基于信干噪比(SINR)最大化的天线合并算法。天线合并算法利用用户SINR的广义Rayleigh熵特性寻找最佳的天线合并矢量。仿真结果表明,该方法能充分利用信道信息,不仅改善了传统PU2RC系统的和速率性能,相对于已有的迫零(ZF)联合波束成形方法,对信道状态信息的量化误差的敏感性更低,用户选择算法的复杂度更低,且低速率反馈条件下和速率性能更优。     

冰箱用聚氨酯泡沫塑料的密度分布机理及配方优化

对冰箱用聚氨酯泡沫塑料的密度分布机理进行了探讨,为配方和工艺优化提供了有价值的参考,并通过对密度分布的研究来解决冰箱泡沫的其他性能缺陷。     

高性能透明PU复印机刮板的研制

探讨异氰酸酯、扩链剂、交联剂和聚合工艺对高性能透明PU复印机刮板物理性能、工艺性能和透明性的影响。试验确定 ,以聚四亚甲基醚二元醇 (PTMEG)为主体材料 ,异氰酸酯选用 4,4′ 二苯基甲烷二异氰酸酯 (MDI) ,扩链剂选用 1,4 丁二醇 (1,4 BDO) ,交联剂选用三羟基丙烷 (TMP) ,按PTMEG/MDI/(BDO TMP) (其中BDO/TMP摩尔比为 6 5∶1)摩尔比为 1∶2∶1、预聚反应条件为 (70～ 80 )℃× 0 5h、扩链反应条件为 (12 5～ 13 0 )℃× 1h聚合PU浇注料 ,利用离心浇注成型法制备出透明PU弹性体 ,经机加工可以制得透明性和物理性能好的复印机刮板