Synergistic flame retardant effects of activated carbon and molybdenum oxide in poly(vinyl chloride)

The synergistic effects of activated carbon (AC) and molybdenum oxide (MoO₃) in improving the flame retardancy of poly(vinyl chloride) (PVC) were investigated. The effects of AC, MoO₃ and their mixture with a mass ratio of 1:1 on the flame retardancy and smoke suppression properties of PVC were studied using the limiting oxygen index and cone calorimeter tests. It was found that the flame retardancy of the relatively cheaper AC was slightly weaker than that of MoO₃. In addition, the incorporation of AC and MoO₃ greatly reduced the total heat release and improved smoke suppressant property of PVC composites. When the total content of AC and MoO₃ was 10 phr, PVC/AC/MoO₃ had the lowest peak heat release rate and peak smoke production rate values of 173.80 kW m^?2 and 0.1472 m² s^?1, which represented reductions of 47.3 and 59.9%, respectively, compared with those of PVC. Furthermore, thermogravimetric analysis and gel content tests were used to analyze the flame retardant mechanism of AC and MoO₃, with results showing that AC could promote early crosslinking in PVC. Char residue left after heating at 500 °C was analyzed using scanning electron microscopy and Raman spectroscopy, and the results showed that MoO₃ produced the most compact char, with the smallest and most organized carbonaceous microstructures. © 2017 Society of Chemical Industry     

阻尼胶囊的生产工艺研究

通过对胶料配方、工艺规程、模具结构的试验研究，成功地解决了胶囊制造过程中的难点问题。     

原位插层聚合制备PVC/蒙脱土纳米复合材料

采用氯乙烯单体直接插层到蒙脱土中进行原位插层聚合，制备纳米复合材料，并用小角X射线衍射（XRD）、扫描电子显微镜（SEM）和电子探针技术对复合材料进行了结构表征。实验结果表明：采用原位插层聚合法制得的PVC／蒙脱土（MMT）复合材料为剥离型纳米复合材料。     

探讨电石法PVC烟气治理方法

分析了电石法PVC生产链中电石炉烟气及电厂烟气二氧化硫的排放情况,指出利用电石炉烟气中的CO合成氨、再将合成氨用于燃煤电厂烟气的"氨法"脱硫是具有较大应用潜力的循环经济产业链。     

PVC树脂聚合用有机过氧化物引发剂

介绍了目前国内外引发剂的使用及开发方向,并对引发剂的选择及其对树脂质量的影响进行了讨论。     

Centum-CS3000系统在PVC聚合装置上的应用

介绍了70m^3悬浮法PVC聚合生产工艺的特点、控制的要求，以及Centum—CS3000系统在该生产装置上的应用。主要讨论了系统配置、组态、控制方案和配方管理。     

高透明耐冲击聚氯乙烯接枝聚合研究

研究高透明耐冲击聚氯乙烯接枝聚合工艺，讨论了加料顺序、复合分散体系以及采用聚集粒子乳液、并用碱性物质调节其ｐＨ值等对接枝聚合物性能的影响，确定了接枝聚合最佳工艺条件。     

SHS法陶瓷衬管的研究现状及应用前景

回顾了自蔓延高温合成陶瓷衬管的发展历史，对国内外的研究现状进行归纳总结，介绍了离心ＳＨＳ法生产陶瓷衬管的工艺特点及产品性能，展望了离心ＳＨＳ陶瓷衬管的应用前景。     

Economic Model to Optimize Underground Utility Protection

The need for better protecting our vital infrastructure from being damaged or destroyed has received increased attention since the terrorist attacks on September 11, 2001. The tragedy of having thousands of innocent people die before the eyes of an entire nation awakened people to the reality of “managed” attacks of unthinkable magnitudes. However, tragedies of a smaller scale are a daily occurrence but accepted as “collateral damage” of work in an unsafe environment. This paper presents a cost-benefit analysis to address the question of how much money should be spent in protecting underground utilities from damage. During the study of an actual incident it was found that the total costs of such accidents are vastly underreported because only costs for emergency responses and repair are tallied up. This paper makes the case that a comprehensive approach for assessing the total economic impact of such incidents on the public, business, and government is the critical stepping stone to a mathematical optimization of expenditure for damage prevention. In addition, the reader will quickly realize that the use of the presented optimization model provides theoretical underpinning for the engineering profession in its effort to better protect our critical infrastructure from terrorist attacks.