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1.
Monomers and their polymers containing 3-arylcarbazolyl electrophores have been synthesized by the multi-step synthetic route. The materials were characterized by thermo-gravimetric analysis, differential scanning calorimetry and electron photoemission technique. The polymers represent materials of high thermal stability having initial thermal degradation temperatures in the range of 331–411 °C. The glass transition temperatures of the amorphous polymeric materials were in the rage of 148–175 °C. The electron photoemission spectra of thin layers of monomers showed ionization potentials in the range of 5.6–5.65 eV. Hole-transporting properties of the polymers were tested in the structures of organic light emitting diodes with Alq3 as the green emitter. The device containing hole-transporting layers of polyether with 3-naphthylcarbazolyl groups exhibited the best overall performance with a maximum current efficiency of 3.3 cd/A and maximum brightness of about 1000 cd/m2. 相似文献
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H-bond and conformations of donors and acceptors in model polyether based polyurethanes 总被引:1,自引:0,他引:1
The molecular mechanics (MM) method with COMPASS force field was used to study the H-bonds in the polyether based polyurethane model molecules. Availability of the calculation was firstly verified in comparison of some H-bonded model molecules, which were studied by using ab initio calculation, and those calculated by MM. Based on a urethane model molecule 1,3-dimethylcarbamate, which can be donor or acceptor and behaves in various conformations, it is reasonable to have a large number of H-bond interactions between various conformational donors and acceptors. For examining all the possible interaction patterns, we studied 57H-bond complexes. This systematic modeling covers well-known four types of interaction patterns, such as NH?OC (Type I), NH?O-CO (Type II), NH?NH (Type III), NH?COC (Type IV) in the system. Obtained H-bond energies were used to analyze the probabilities of the complexes. For the interaction within the hard segments, or Type I, Type II and Type III, a predominant H-bond complex has been found in the present study, which belongs to Type I. For the interaction between the hard segment and the soft segment, two conformations of Type IV were calculated to be existed. 相似文献
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云2-平1多台阶变方位水平井钻井液技术 总被引:1,自引:0,他引:1
云2-平1井是位于复杂断块油气田上的一口中曲率半径水平井,水平段长820.86 m,水平段多台阶、方位角变化幅度大(29.6°),井下摩阻大,钻井液的携砂、润滑及防卡能力是该井钻井成功的关键。该井选用有机正电胶-聚合物钻井液体系,用高分子量聚合物胶液进行维护,以提高体系的悬浮携岩及防塌能力,通过加入液体磺化沥青、原油及与之相配伍的固体乳化剂来提高润滑性,配合良好的四级固控设备及时清除有害固相,使钻井液性能稳定且易于调整,增强了泥饼的韧度和强度,完全达到了充分悬浮携带岩屑、润滑防卡、稳定井壁的要求。在钻进过程中仔细观察钻井液的动切力、动塑比、静切力初终值、固相含量、含油量、膨润土含量等性能参数的变化,“细化、超前、配套”是该井钻井液性能稳定、效果良好的主要维护处理经验。下套管、钻杆输送测井顺利,井下摩阻始终小于10 kN,全井安全无事故,仅用45d8 h钻完3200 m的进尺。 相似文献
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M.S. Thompson Author Vitae Author Vitae 《Polymer》2008,49(2):345-373
Poly(ethylene oxide) (PEO) oligomers are employed extensively in pharmaceutical and biomedical arenas mainly due to their excellent physical and biological properties, including solubility in water and organic solvents, lack of toxicity, and absence of immunogenicity. PEO can be chemically modified and reacted with, or adsorbed onto, other molecules and surfaces. Sophisticated applications for PEO have increased the demand for PEO oligomers with tailored functionalities, and heterobifunctional PEOs are often needed. This review discusses the synthesis and applications of heterobifunctional PEO oligomers possessing amine, carboxylate, thiol, and maleimide functional groups. 相似文献
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Manqi Zhang Degang Li Tianbao Dong Xiaoxiao Hou Xiao Zhang Hongliang Liu Lihong Liu Shouyu Tang Shaomin Liu 《乙烯基与添加剂工艺杂志》2021,27(3):519-532
Global bacterial infections associated with conventional polyvinyl chloride (PVC) medical devices place a heavy burden on healthcare systems and thus it will be desirable if medical devices are made from antimicrobial PVC. There are numerous studies focusing on polymer surface modifications to either leach antimicrobial agents or kill pathogenic microbes upon direct contact. In this work, mannitol fumarate ester-based aluminum metal alkoxide (MFE-Al) additive was developed to confer simultaneously improved antibacterial property and enhanced high temperature sterilization resistance of the resultant PVC. Data obtained confirm that the MFE-Al stabilized PVC sheets significantly inhibit 98% bacterial growth. They also show biocompatibility with cultured H9C2 cardiomyocytes and hemocompatibility in vitro. Dry heat sterilization is generally not suitable for PVC medical wares due to their poor thermal compatibility. Surprisingly, our antimicrobial-biocompatible PVC can maintain stability at 180°C for 90 min. Such a high thermal stability indicates the MFE-Al stabilized PVC can endure 90 cycles of dry-heat sterilization without significant damage. This study may provide a solution to reduce PVC medical waste for a maximum benefit without compromising human health or the environment. 相似文献
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本法采用乙醇水溶解试样,以经过处理的无钾,钠离子聚醚鸩元醇作为基体,配制标准样品,用火焰光度法检测聚醚多元醇中间品的钾(钠)离子的含量。由于样品处理简单,应用浓度直读取数据,可快速准确地测定试样,适用于聚醚多元醇生产过程中间品的检验。 相似文献
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