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排序方式: 共有431条查询结果,搜索用时 46 毫秒
1.
Qingzhao Yao Yuming Zhou Yanqing Sun Xiaoyun Ye 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(4):477-484
TiO2 hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane
coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation
method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as
testified by UV spectrometric method. KH570 modified TiO2 nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the
reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron
microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed
for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting
cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive
adsorption capacity were achieved, which made it promising in chemical sensor applications. 相似文献
2.
Jeong Ho Moon Hak Soo Han Yong Gun Shul Do Hoon Jang Muyng Do Ro Du Suk Yun 《Progress in Organic Coatings》2007
This study relates to the development of coatings for optical discs in high-density digital versatile disc systems (HD-DVD or blue lay disk) that use a high numerical aperture of 0.85 at 405 nm wavelength and have a protective top layer over a primer layer for protection against damage and dust. Ultraviolet-curable raw materials of two acrylic monofunctional monomers ( isobornylacrylate, IBA and tetrahydrofurfurylacrylate, THFA) and two kinds of urethaneacrylate oligomers (OUMD and OUME) have been easily mixed with photoinitiators. Curing rate of these materials was characterized by FT-IR. In case of top coats, VTES (vinyltriethoxysilane) and acrylic acid were added to enhance the abrasion resistance. These two kinds of UV-curable resinous materials having no solvent were synthesized and investigated as means for making a blue ray disk having good optical and mechanical properties. In addition, dynamic characteristics including reflectivity, fluctuation of RF signal and noise level were also investigated. 相似文献
3.
磷化工艺在油管接箍上的应用 总被引:2,自引:0,他引:2
磷化工艺取代镀锌工艺在油管接箍上的成功应用,大大提高了油管的产品质量,并且解决了接箍的防腐蚀问题。 相似文献
4.
5.
本文研究了γ-流基丙基三甲氧基硅烷(KH590)对白炭黑填充的SBR胶料的光接枝反应。通过接枝反应,提高了橡胶填料间界面粘合性,也提高了硫化胶的300%定伸模量,改善了撕裂强度、压缩永久变形及耐磨耗性等、此外,在NBR中也取得同样改性效果。尤其是,改善了耐碱性。但经照射后在室内放置会增加凝胶化,影响到加工性能. 相似文献
6.
硅烷改性炭黑对胶料性能的影响 总被引:3,自引:0,他引:3
通过试验讨论了用TESPT改性处理的炭黑在橡胶配方中对胶料性能的影响。试验结果表明,TESPT改性后不仅可改善胶料的动态特性,而且有益于橡胶的补强。 相似文献
7.
Environmental etch damage to automotive coatings, and scratch and mar of these coatings are an important element of customer satisfaction as well as a significant warranty repair consideration for automotive companies. The conditions that result in environmental etch are examined and a laboratory test proposed. Data from this test are compared to automotive hoods exposed in Florida. The performance of various crosslinking chemistries is discussed and the requirements for improved environmental etch are outlined. Scratch and mar performance of these systems is also reviewed. We have found that coatings respond to physical stress by elastic recovery, by plastic flow and by brittle fracture. Classifying types of damage in this way is important for understanding the chemistry needed for improved scratch and mar of coatings. 相似文献
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10.
Tinh Nguyen W. Eric Byrd David Alshed Joannie Chin Cyril Clerici Jon Martin 《The Journal of Adhesion》2007,83(6):587-610
Water at the polymer/substrate interface is often the major cause of adhesion loss in coatings, adhesives, and fiber-reinforced polymer composites. This study critically assesses the relationship between the interfacial water layer and the adhesion loss in epoxy/siliceous substrate systems. Both untreated and silane-treated Si substrates and untreated and silane-treated E-glass fibers were used. Thickness of the interfacial water layer was measured on epoxy/Si systems by Fourier transform infrared-multiple total internal reflection (FTIR-MTIR) spectroscopy. Adhesion loss of epoxy/Si systems and epoxy/E-glass fiber composites was measured by peel adhesion and short-beam shear tests, respectively. Little water accumulation at the epoxy/Si substrate interface was observed for silane-treated Si substrates, but about 10 monolayers of water accumulated at the interface between the epoxy and the untreated Si substrate following 100 h of exposure at 24 °C. More than 70% of the initial epoxy/untreated Si system peel strength was lost within 75 h of exposure, compared with 20% loss after 600 h for the silane-treated Si samples. Shear strength loss in composites made with untreated E-glass fiber was nearly twice that of composites fabricated with silane-treated fiber after 6 months of immersion in 60 °C water. Further, the silane-treated composites remained transparent, but the untreated fiber composites became opaque after water exposure. Evidence from FTIR-MTIR spectroscopy, adhesion loss, and visual observation strongly indicated that a water layer at the polymer/substrate interface is mostly responsible for the adhesion loss of epoxy/untreated siliceous substrate systems and epoxy/untreated glass fiber composites and that FTIR-MTIR is a viable technique to reliably and conveniently assess the adhesion loss attributable to water sorption at the interface. 相似文献