Grain orientation evolution and multi-scale interfaces enhanced thermoelectric properties of textured Sr0.9La0.1TiO3 based ceramics

Sr_0.9La_0.1TiO₃ based textured ceramics (SLTT-S3T) with a texture fraction of 0.81 are successfully fabricated by the reactive template grain growth method, in which Sr_0.9La_0.1TiO₃/20 wt%Ti was used as matrix and 10 wt% plate-like Sr₃Ti₂O₇ template seeds were used as templates. The phase transition, microstructure evolution, and the anisotropic thermoelectric properties of SLTT-S3T ceramics were investigated. The results show that the ceramics are mainly composed of Sr_0.9La_0.1TiO₃ and rutile TiO₂ phases. Grains grow with a preferred orientation along (h00). A maximum ZT of 0.26 at 1073 K was achieved in the direction perpendicular to the tape casting direction. The low lattice thermal conductivity of 1.9 W/(m K) at 1073 K was obtained decreased by 34%, 40%, and 38% compared with non-textured, SrTiO₃ and Sr_0.9La_0.1TiO₃ ceramics prepared by the same process, can be attributed to the enhanced phonon scattering by the complex multi-scale boundaries and interfaces. This work provides a strategy of microstructural design for thermoelectric oxides to decrease intrinsic lattice thermal conductivity and further regulate thermoelectric properties via texture engineering.     

Effects of strontium gallate additions on sintering behavior of gadolinia-doped ceria

The densification behavior and grain growth of Ce_0.8Gd_0.2O_1.9 ceramics were investigated with the strontium gallate concentration ranging from 0 to 5 mol%. Both the sintered density and grain size were found to increase rapidly up to 0.5 mol% Sr₂Ga₂O₅, and then to decrease with further addition. Dense Ce_0.8Gd_0.2O_1.9 ceramics with 97% of the theoretical density could be obtained for 0.5 mol% Sr₂Ga₂O₅-added specimen sintered at 1250^∘C for 5 h, whereas pure Ce_0.8Gd_0.2O_1.9 ceramics needed to be sintered at 1550^∘C in order to obtain an equivalent theoretical density. The addition of Sr₂Ga₂O₅ was found to promote the sintering properties of Gd₂O₃-doped CeO₂.     

Structural properties of inorganic materials: tungsten bronze SBN ceramics

Rare-earth doped strontium barium niobates were synthesized using usual ceramic technique. The dopants are La, Ce, Gd, Sm and Nd. The materials were characterized by XRD and density measurements. The grain sizes were determined from SEM analysis. Lattice parameters changed uniformly with rare-earth dopants in unfilled structures. Density measurements and SEM analysis confirmed only minute changes in the densities of the ceramics.     

钙钛矿型钛酸锶的制备、结构与性能

钛酸锶是一种具有重要电性质的陶瓷材料 ,因而在工业上得到了广泛的应用。本文介绍了钛酸锶的几种常见的合成方法 ,并简要的介绍了钛酸锶的结构与性能     

锶合金化在镁合金中的作用

锶加入镁合金中可以提高合金的铸造性能;少量的锶加入到镁合金中,能够细化镁合金的组织,提高镁合金的室温力学性能;锶对不同系列镁合金力学性能的影响不尽相同;锶合金化可以改善镁合金的高温力学性能以及蠕变性能.锶是提高镁合金耐蚀性的有效合金元素,含锶镁合金有望成为新型的轻质耐高温材料.     

First evidence of grass carp recruitment in the Great Lakes Basin

We use aging techniques, ploidy analysis, and otolith microchemistry to assess whether four grass carp Ctenopharyngodon idella captured from the Sandusky River, Ohio were the result of natural reproduction within the Lake Erie Basin. All four fish were of age 1 +. Multiple lines of evidence indicate that these fish were not aquaculture-reared and that they were most likely the result of successful reproduction in the Sandusky River. First, at least two of the fish were diploid; diploid grass carp cannot legally be released in the Great Lakes Basin. Second, strontium:calcium (Sr:Ca) ratios were elevated in all four grass carp from the Sandusky River, with elevated Sr:Ca ratios throughout the otolith transect, compared to grass carp from Missouri and Arkansas ponds. This reflects the high Sr:Ca ratio of the Sandusky River, and indicates that these fish lived in a high-strontium environment throughout their entire lives. Third, Sandusky River fish were higher in Sr:Ca ratio variability than fish from ponds, reflecting the high but spatially and temporally variable strontium concentrations of southwestern Lake Erie tributaries, and not the stable environment of pond aquaculture. Fourth, Sr:Ca ratios in the grass carp from the Sandusky River were lower in their 2011 growth increment (a high water year) than the 2012 growth increment (a low water year), reflecting the observed inverse relationship between discharge and strontium concentration in these rivers. We conclude that these four grass carp captured from the Sandusky River are most likely the result of natural reproduction within the Lake Erie Basin.     

Grain dependence of ferroelectric domain switching on SrBi2Ta2O9 thin films observed by Kelvin probe force microscope

We have studied grain-shape dependence of Kelvin probe force microscopy of SrBi₂Ta₂O₉ thin films on epitaxial La_0.5Sr_0.5CoO₃/LaAlO₃ substrates. By changing the growth condition in pulsed laser deposition, we have grown the SrBi₂Ta₂O₉ thin films with various grain shapes. The shape and the orientation of SrBi₂Ta₂O₉ the thin films with various growth conditions have been analyzed by X-ray diffraction and scanning electron microscope. The large number of the long rectangular grains was observed accompanied with relatively larger (220) peaks than other peaks. From the Kelvin probe force microscope study, it has been observed that the long rectangular grains showed characteristics of easy ferroelectric domain switching at a low writing bias and weaker influence of surface charges.     

超级铁精矿提纯与锶铁氧体预烧料试验研究

对武钢金山店的磁铁精矿进行提纯，得到了超纯磁铁精矿（TFe〉71．5％，SiO2〈0．5％）。以该超纯磁铁精矿与分析纯碳酸锶及添加剂为原料，通过对配比、预烧温度、保温时间等条件进行优化得到了性能较好的锶铁氧体预烧料。     

超纯磁铁精矿原料制备高σs的锶铁氧体预烧料的研究

以超纯磁铁精矿为原料 ,配合适当的添加剂 ,严格控制混料、制粒、预烧等工艺环节 ,成功地开发了磁铁精矿氧化与铁氧体生成反应同时完成新工艺 ,生产出高σs 的预烧料 ,其σs >71 5(A·m2 ) /kg ,含Fe2 +<0 2 %。     

锶离子掺杂对NiO薄膜离子传输和电致变色性能的改善作用

电致变色材料在智能显示和军事伪装等领域具有非常重要的应用前景。为了改善NiO薄膜在碱性电解液中变色响应时间长,循环稳定性差的问题,本文采用水热法制备了锶离子掺杂纳米片状NiO电致变色薄膜,离子掺杂引起的晶格畸变与微纳结构的协同作用,使NiO薄膜展现出了优异的电致变色性能。锶离子掺杂一方面改善了NiO薄膜的电化学特性,从而缩短了电致变色响应时间(着色时间约为4.5 s,褪色时间约为2.7 s),提高了着色效率(CE, 85.2 cm₂^C_-1⁾。另一方面为NiO晶体结构提供了支撑,增强了电致变色过程中晶体结构的稳定性,从而显著提升了薄膜的循环稳定性(循环次数超过了10000次)。本文的研究结果对促进电致变色材料的工程化应用具有一定的借鉴和指导意义。