Enhanced photodegradation of Rhodamine B under visible light by N-K2Ti4O9/MIL-101 composite

N-K₂Ti₄O₉/MIL-101 composites were successfully synthesized by a facile hydrothermal method, and were characterized by powder X-ray diffraction, UV–vis diffuse reflectance spectroscopy, the valence band X-ray photoelectron spectroscopy, field emission transmission electron microscopy, photoluminescence emission spectra, N₂ adsorption–desorption and thermogravimetric analysis. Photocatalytic activities of N-K₂Ti₄O₉, MIL-101 and the composites were investigated by the degradation of Rhodamine B (RhB) under visible light irradiation. The results show that the composites exhibit higher photocatalytic activity as compared with the pure materials. The synergistically enhanced photocatalytic activity of the composites is due to big adsorption capacity of MIL-101 and high separation efficiency of photogenerated electron-hole pairs through interfaces between N-K₂Ti₄O₉ and MIL-101.     

ZL101合金锶变质效果及热处理工艺的改进

对现场生产的ZLl01合金铸件材质进行了全面分析，针对存在的产品成分不准，变质效果不好，力学性能不合格的问题，通过改进合金的锶变质工艺和热处理工艺，改善了合金的组织和性能，达到了对材料的成分、性能的各项要求。     

基于TS101型DSP链路口的多通道高精度数据采集电路设计

介绍一种基于数字信号处理器(DSP)TS101链路口的多通道高精度数据采集电路的设计方法,详细阐述利用多个ADS8361型A/D转换器进行数据采集,并经TS101链路口传输数据的FP-GA和DSP设计实现,讨论如何提高A/D转换精度的问题.     

Study on diffusion welding SiCp/ZL101 with Cu interlayer

Through the vacuum diffusion welding SiCp/ZL101 aluminum with Cu interlayer,the effect of welding parame-ter and the thickness of Cu on the welded joint property was investigated,and the optimal welding parameters were putforward at the same time.The microstructure of joint was analyzed by means of optical-microscope,scanning electron mi-croscope in order to study the relationship between the macro-properties of joint and the microstructure.The results showthat diffusion welding with Cu interlayer could be used for welding aluminum matrix composites SiCp/ZL101 successfully.     

免疫荧光定量分析仪设计

设计了免疫荧光定量分析仪,用以对人体血液和尿液中的各种分析物(CRP、PCT、NTpro BNP、c Tn I等)含量进行快速准确的定量分析。光源采用大功率LED灯珠,采用窄带干涉滤光片对激发光和荧光进行滤光,采用内置运放的光电转换芯片OPT101进行荧光强度的检测。采用步进电机驱动,皮带传动方式带动双排滚珠宽体滑块在单根精密直线导轨上滑动,实现对检测样品的扫描式检测。通过与标准仪器进行对比试验,结果表明样机在小型化、快速性以及低成本的基础上,测量结果准确,测量精度高,稳定性好,能满足临床应用要求。     

Alteration of aspartate 101 in the active site of Escherichia coli alkaline phosphatase enhances the catalytic activity

The function of aspartic acid residue 101 in the active siteof Escherichia coli alkaline phosphatase was investigated bysite-specific mutagenesis. A mutant version of alkaline phosphatasewas constructed with alanine in place of aspartic acid at position101. When kinetic measurements are carried out in the presenceof a phosphate acceptor, 1.0 M Tris, pH 8.0, both the k_cat andthe K_m, for the mutant enzyme increase by –2-fold, resultingin almost no change in the k_cat/K_m ratio. Under conditions ofno external phosphate acceptor and pH 8.0, both the k_cat andthe K_m for the mutant enzyme decrease by {small tilde}2-fold,again resulting in almost no change in the k_cat/K_m ratio. Thek_cat for the hydrolysis of 4-methyl-umbelliferyl phosphate andp-nitrophenyl phosphate are nearly identical for both the wild-typeand mutant enzymes, as is the K₁ for inorganic phosphate. Thereplacement of aspartic acid 101 by alanine does have a significanteffect on the activity of the enzyme as a function of pH, especiallyin the presence of a phosphate acceptor. At pH 9.4 the mutantenzyme exhibits 3-fold higher activity than the wild-type. Themutant enzyme also exhibits a substantial decrease in thermalstability: it is half inactivated by treatment at 49°C for15 min compared to 71°C for the wild-type enzyme. The datareported here suggest that this amino acid substitution altersthe rates of steps after the formation of the phospho-enzymeintermediate. Analysis of the X-ray structure of the wild-typeenzyme indicates that the increase in catalytic rate of themutant enzyme in the presence of a phosphate acceptor may bedue to an increase in accessibility of the active site nearSerl02. The increased catalytic rate of this mutant enzyme maybe utilized to improve diagnostic tests that require alkalinephosphatase, and the reduced heat stability of the mutant enzymemay make it useful in recombinant DNA techniques that requirethe ability to heat-inactivate the enzyme after use.     

Nanocomposite route to the stabilization of porous ϑ-alumina

Stabilization of -alumina phase by silica was studied in nanocomposite (diphasic) alumina-silica gels by XRD and BET surface areas measurements. Five wt.% of silica (22 nm particles) increased the crystallization temperature of to -alumina by about 100°C from boehmite (10 nm particles) derived alumina. Stabilization of -alumina was caused by the formation of intimate contact (Al-O-Si) between components by diffusion of silica into the defect alumina structure.Also with the Department of Agronomy.     

低过热度浇注ZL101铝合金半固态组织研究

采用低过热度浇注技术制备半固态ZL101铝合金,研究了冷却强度、保温时间、浇注温度对铸造显微组织的影响。研究结果表明,在液相线附近,冷却强度大,晶粒细小;随着保温时间的延长,晶粒变大,形状变得圆整,结晶组织均匀;浇注温度越高,晶粒越粗大;铸锭中心部位组织比边缘部位组织粗大,且均匀,球化明显。低过热度浇注可以获得理想的ZL101铝合金半固态浆料。半固态坯料重熔加热温度为585℃,保温30min,α-Al相逐渐变成球状,此时,晶粒平均等级圆直径为42.6μm,晶粒平均圆度为2.13。     

8P1.553.026 L型座的金属型铸造工艺

分析论证了几种可供选择的浇注方案 ,从中选出最佳方案进行浇道、冒口及铜芯等工艺要素的设计计算 ,确定了L型座铸件的金属型铸造工艺 ,并进行了试验验证 ,结果表明铸件质量稳定可靠 ,完全满足各项产品性能要求