Mechanisms of inclusion formation in low alloy steels deoxidised with titanium

Abstract

In the present investigation, the conditions for inclusion formation in two Ti deoxidised steels and one Al–Ca deoxidised steel have been examined by means of optical and electron microscopy, in combination with a thermo dynamic analysis of the phase relations involved. It is concluded that the Ti containing inclusions form as a result of a series of reactions occurring in the ladle, during solidification and in the solid state. The important solid state reaction products are MnS, TiN, and MnOTiO₂ . The presence of Mn rich compounds at the surface of the inclusions is consistent with the observation of a Mn depleted zone in the surrounding steel matrix. In contrast, the primary inclusions in the Al–Ca deoxidised steel are complex oxysulphides, which are thermodynamically more stable and can therefore form in the liquid state.     

Ultrahigh strength hot rolled microalloyed steel: microstructure and properties

Abstract

A low carbon steel alloyed with Ni, Mn, Mo, Cu and microalloyed with Nb and Ti was prepared. Continuous cooling transformation behaviour of the steel was evaluated. Formation of polygonal or Widmanstätten ferrite is suppressed at high temperature and the 'C' curve is shifted to an extreme right. At lower temperatures a flat top 'C' curve with a mixed structure of bainite and martensite was obtained and the transformation temperatures do not vary much with a wide range of cooling rates. The steel was thermomechanically processed at different finishing temperatures and ultrahigh strength values were obtained as a result of austenite grain refinement, highly dislocated fine lath martensite structure along with tiny precipitates of microalloying carbide and carbonitride at all finish rolling temperatures. The stable and large TiN/TiCN particles formed during casting have impaired the impact toughness values at ambient and at ?40°C temperatures.     

METAL INERT GAS WELDING OF 2519-T87 HIGH STRENGTH ALUMINUM ALLOY

20 mm thick plates of 2519-T87 high strength aluminum alloy have been welded.The effects of the compositions of filler wires,the heat input and the compositions of shielding gas on the mechanical properties and microstructure of the welded joint have been investigated.The results indicate that finer microstructure,better mechanical properties and higher value of hardness of HAZ can be obtained by using lower heat input.The use of Ar/He mixed shielding gas has several advan- tages over pure Ar shielding gas.With the increase of the proportion of He in the mixed shielding gas, the grain size of the weld metal as well as porosity susceptibility decreases.When the volume ratio of He to Ar reaches 7:3,the porosity and the grain size of weld metal reach the minimum,and the po- rosity can be further reduced by filling some CO_2.     

Estimation of Weibull parameters with linear regression method

Abstract

Based on minimum mean square error, a modified probability estimator is proposed by a Monte Carlo simulation for estimating the Weibull parameters with the linear regression method. It is shown that compared with the commonly used estimators, the modified probability estimator gives a more accurate estimation of the Weibull modulus and the same estimation precision of the scale parameter. Furthermore, it is more conservative than the commonly used estimator recommended by previous authors and hence results in a higher safety in reliability predictions.     

The development and control of a flexible-spine for a human-form robot

In this paper, the development of a robot which has a flexible spine is presented. By embedding a multi-d.o.f. soft structure into a robot body as a spine, the robot can increase its ability to absorb shock and to work in various environment such as narrow places. As a result of these abilities, the robot can expand its opportunity to work in the human environment. Moreover, its motion could be more natural. The developed full-body human-form robot has a five-jointed flexible spine. Each joint (vertebra) has 3 d.o.f. Between each vertebrae is a 'disk' made of silicone rubber. The spine is controlled by eight tendons, whose tensions can be controlled using tension sensors and locally distributed microcontrollers. This paper describes the development of the flexible spine and the control of the posture of the spine and body.     

Thermomechanical response of 50.7 at.-%Ni-Ti alloy in the pseudoelastic regime

Abstract

The thermomechanical response of 50.7 at.-%Ni-Ti superelastic alloy has been investigated for a range of applied strains and strain rates. Parameters of interest include the critical stresses for nucleation and completion (σ _ms and σ _mf respectively) of the stress induced martensite (SIM) transformation, as well as the magnitude of the endothermal and exothermal reactions as a function of the applied strain and rate of deformation. Novel techniques including infrared thermometry and laser extensometry have been utilised, and are found to be particularly suited to experimentation with nitinol. The transformation temperatures and values of entropy and enthalpy of formation have been determined using differential scanning calorimetry.     

16—THE PREPARATION,FINE STRUCTURE,AND PHYSICAL PROPERTIES OF PARTLY METHYLATED COTTON FABRICS

Cotton fabric has been methylated under a variety of conditions. The extent of methylation has been shown to be dependent on the time of methylation and on the degree of swelling or disruption of structure. The latter is caused by the alkali pretreatment or by the swelling of the partly methylated cellulose. Fabric physical properties have been measured and the influence of the methylation treatment has been examined.     

Development of process for thermomechanical treatment of ultrahigh strength steel prepared by electroslag refining

Abstract

Thermomechanical treatment (TMT) is the simultaneous use of work hardening, and grain refinement along with solid solution and precipitation strengthening. In this investigation, four alloys, with a base composition of 0·28%C, 1·0%Mn, 4·2%Cr, 1·0%Mo, 0·34%V, were prepared by electroslag refining (ESR) and by addition of small amounts of Ti and Nb and by increasing Cr and V to 4·8 and 0·48% respectively. In two of the alloys a yield strength in excess of 1550 MPa was obtained in the as cast quenched and tempered condition. Attempts were made to further increase the yield strength by thermomechanical treatment. The process parameters for thermomechanical treatment were optimised by adopting procedures such as calculation of stability of precipitates, hot compression test, determination of cooling rates in different coolants, and modelling of TTT and CCT diagrams. The process involved prerolling of the ESR ingot to a bar at 1200°C, followed by hot rolling in two passes starting from 950°C and finishing at 850°C with equal deformation of 25% in each pass to convert the bar into plates. These were immediately cooled in one of the cooling media: air, polymer–water solution (1 : 1·5) and oil. Yield strength in excess of 1750 MPa was obtained in oil cooled specimens of the alloy with titanium addition and that where Cr and V were increased. The niobium added specimen gave strengths, similar to that obtained for the base alloy, in spite of the fact that the as cast alloy had shown very high strengths, presumably because of the high soaking temperatures and grain growth. Air cooling gave the lowest strengths and oil cooling the highest.     

Investigation of tensile strength of hydroxyapatite with various porosities by diametral strength test

Abstract

It is appropriate to administer the diametral test to biomedical materials used in dental applications because stresses formed on dental implants are similar to those that formed in this test. To show this similarity, an experimental study of diametral strength testing of hydroxyapatite was performed. The influence of porosity on hydroxyapatite was investigated experimentally to determine how the diametral strength was affected. Hydroxyapatite was air sintered at 1100°C for 1 h with porosities ranging from 1 to 32%. The results indicated that hydroxyapatite with improved densification had higher diametral strength values. X-ray diffraction analysis showed that sintered samples were pure hydroxyapatite.     

33—THE SNARLING OF HIGHLY TWISTED MONOFILAMENTS. PART II: CYLINDRICAL SNARLING

An account is given of an experimental investigation of the cylindrical snarling of highly twisted monofilaments.

The theory underlying cylindrical snarling is set out, and an expression is derived for calculating the critical twist level at which normal snarling will be replaced by cylindrical snarling. Experiments on rubber filaments are described, and it is shown that there is good agreement between the theoretical and experimental results. Further experiments, in which the specimen was allowed to contract freely or forced into other forms, are also described.

It is shown from these experiments that it is difficult to establish the true equilibrium behaviour, since the situation appears to be dominated by frictional effects or by direct barriers to relative movement.