分子筛绿色化合成技术的开发

对现有分子筛合成废液中氨氮及还原性物质的来源进行分析，确定降低排放废水中氨氮浓度及COD的方案。对现有ZRP-5分子筛制备流程进行优化，增加母液及赶胺水回用工序；建立母液浓缩装置，将钛硅分子筛及Β分子筛的合成母液及重排母液应用于ZSM-5分子筛的合成，实现废液的梯级利用。上述措施既解决了因分子筛生产废液的排放造成的环境污染，亦因废物资源化降低了ZSM-5分子筛的生产成本。     

Fluorescence and IR characterization of epoxy cured with aliphatic amines

Cure reactions of the stoichiometric mixtures of diglycidyl ether of bisphenol A (DGEBA) and two very low molecular weight aliphatic polyether diamines (PED) were studied by using fluorescence and mid- and near-IR spectroscopic techniques. As the cure proceeded, the primary amine groups in PED are converted to the secondary and the tertiary amines. Near-IR spectral analysis was used to calculate the concentration of the three amine groups as a function of cure time. The decrease in the fluorescence intensity of DGEBA at about 307 nm was observed due to more effective quenching of the tertiary amine groups in PED, in comparison to the primary and the secondary amine groups. A large decrease in fluorescence intensity at 75 and 95 °C cure was observed. The amount of all the amine species was estimated from NIR spectra to shed light on the cure kinetics of PPO (polypropylene oxide) in comparison with PEO (polyethylene oxide) epoxy, as well as to explain their fluorescence behavior.The fluorescence intensity changes were correlated to the extent of epoxy reaction obtained by mid- and near-IR spectroscopy.     

月桂醇聚氧乙烯醚硝酸酯助燃降污性能的研究

通过柴油发动机台架试验证明 ,月桂醇聚氧乙烯醚硝酸酯用作柴油添加剂 ,既可提高柴油的燃烧性能 ,又可降低排放尾气中的一氧化碳 (CO)、未燃碳氢化合物 (HC)、氮氧化物 (NOx)含量及烟度等多种功能 ,是一种良好的多功能柴油助燃消烟添加剂。     

镁钴铝类水滑石催化合成安息香甲醚

采用共沉淀法制备了镁钴铝类水滑石化合物(MgCoAl-HTLcs),并用 X 射线衍射、扫描电子显微镜、NH_3程序升温脱附等方法对 MgCoAl-HTLcs 进行了表征,并以 MgCoAl-HTLcs 为催化剂催化苯甲醛与甲醇反应合成安息香甲醚,研究了n(Mg):n(Co):n(Al)、催化剂用量、原料配比、反应温度、反应时间对合成反应的影响。表征结果显示,MgCoAl-HTLcs 的晶相完整,表面主要为弱酸、弱碱性。催化合成安息香甲醚的适宜条件为:MgCoAl-HTLcs 催化剂用量0.10 g(约为原料总质量的0.23%),n(Mg):n(Co):n(Al)=0.4:1.6:1.0,V(苯甲醛):V(甲醇)=3:50,反应温度50℃,反应时间150 min。在此条件下,苯甲醛的平衡转化率达77.49%,安息香甲醚选择性接近100%。为洁净合成安息香甲醚开辟了一条新的途径。     

相转移催化合成芳基烷基醚

报道了以四丁基溴化铵为相转移催化剂，简便地合成了１０个芳基烷基醚，反应几乎是定量地快速进行。     

由碳五馏分合成甲基叔戊基醚工艺的研究

以催化裂化C_5馏分与工业甲醇为原料,D005型大孔强酸型阳离子交换树脂为催化剂,采用筒式膨胀床双反应器,考察了甲基叔戊基醚的合成工艺条件。一阶反应器的操作条件为：循环比为2：1,醇烯比为1.2：1,入口温度为70℃,空速为6 h~(-1),平均转化率为53.63%；二阶反应器的操作条件为：入口温度为50℃,空速为1.2h~(-1),平均转化率为71.32%,全调合方案可以使催化裂化汽油的辛烷值平均提高0.55个单位。     

水分对高碱值硫化烷基酚钙结构和清净性的影响

采用傅立叶红外光谱仪，分析了水分对清净剂高碱值硫化烷基酚钙结构组成的影响；采用热管氧化试验法和曲轴箱模拟试验法，考察了高碱值硫化烷基酚钙在加水前后清净性能的变化；采用四球试验机和高频往复试验机，分析了水分对高碱值硫化烷基酚钙润滑性能的影响。结果表明，油中的水含量对高碱值硫化烷基酚钙的水解安定性能影响较大，并且随着水含量的增加，油品的清净性能和抗磨性能变差。     

烃类在三甘醇和四甘醇中无限稀释活度系数的测定与关联

用气相色谱法分别测定了苯、甲苯、乙苯、正庚烷、正辛烷、正壬烷和正癸烷在三甘醇和四甘醇中的无限稀释活度系数 ,测定温度范围为 5 0～ 13 0℃。用修正的UNIFAC模型 (Dortmund)对上述不同温度下的无限稀释活度系数实验数据进行关联 ,得到了三甘醇和四甘醇与其它基团的相互作用参数 ,并将计算结果与实测值进行了比较。     

Inter- and intra-molecular ionic interactions of polyampholyte: Carboxymethyl-2-diethylaminoethylcellulose

Carboxymethyl-2-diethylaminoethylcellulose (CM-DEAE cellulose) was prepared by etherification of carboxymethylcellulose with diethylaminoethyl chloride in a NaOH solution. The behaviour of CM-DEAE cellulose in aqueous solution was studied by viscosity and GPC measurements. The degree of substitution (DS) and existing states of DEAE substituents were examined by the use of proton NMR, and those of the CM substituents were observed with FT-IR. The results reveal that the reduced viscosity and apparent molecular size of CM-DEAE cellulose vary with the concentration of sodium chloride and changes in pH and DS. These phenomena can be explained in terms of inter- and intra-molecular ionic interactions.