In situ formation of multi scale reinforcing phases to improve performance of Al2O3-SiC C castables

In order to improve the physical properties and slag corrosion resistance of refractory materials for hot metal pretreatment, different contents of composite metal powders (CMP) were introduced into Al2O3-SiC-C refractory castables. The effect of CMP on the microstructure, physical properties and slag corrosion resistance of Al2O3-SiC-C refractory castables were studied. The results show that the multi scale reinforcing phases including flake crystals, rod shaped fibers, filamentous fibers and whiskers are in situ formed in the samples with addition of CMP, which result to the improvement of the cold modulus of rupture and cold crushing strength. When the addition of CMP is 6 wt.%, the high temperature modulus of rupture increases by 231%, the thermal shock resistance increases by 77% after thermal shock by water cooling 5 times and the percentage of the slag resistant area reduces by 37.2%.     

红柱石在烧结刚玉基窑口浇注料中的应用

以烧结刚玉、碳化硅等为主要原料,分别以红柱石0%、5%、10%、15%替换相同比例的烧结刚玉,同时外加少量的改性剂A制备四组浇注料,对比四种浇注料经1 400 ℃处理后的常温性能、线变化、抗热震性、抗碱侵蚀能力。结果表明,添加红柱石10%和改性剂1%的烧结刚玉基窑口浇注料表现出较好的使用性能。     

电冶矾土刚玉质自流浇注料的研究

以电冶矾土刚玉为骨料有利于提高浇注料的自流性能 ;六偏磷酸钠分散剂对Al2 O3泥浆流变性能有较理想的改善作用 ;电冶矾土刚玉质自流浇注料具有优良的抗渣性能 ,这主要同浇注料的显微结构和电冶矾土刚玉骨料的性能相关。     

Al2O3-SiC-C质主铁沟浇注料的结合相研究

对高炉主出铁沟用Al2O3-SiC-C质浇注料的结合相变化进行了分析，其中涉及到溶胶结合、氮化硅铁为添加物形成的sialon结合、水泥形成的水硬性结合。溶胶结合强度主要来自于化学结合；而sialon结合、水泥结合的强度仍然来自少量水泥形成的水硬性凝固相的作用，因此对烘烤工艺、使用效果的影响不同。     

尖晶石粒度对高纯刚玉-尖晶石浇注料性能的影响

研究了尖晶石粒度对高纯刚玉 -尖晶石浇注料的抗折强度、抗热震性、抗侵蚀性等性能的影响。实验表明 :(1)随着配料中尖晶石颗粒含量的增加 ,试样的烧后强度呈先升高后降低趋势 (烘后强度变化不明显 ) ,烧后收缩减少 ,然后变为膨胀 ;(2 )尖晶石细粉与颗粒为 1:3的试样抗热震性较好 ;(3)对于高碱度渣 ,尖晶石颗粒加入量较多的试样抗侵蚀性较好 ;(4)对于低碱度渣 ,尖晶石细粉加入量较多的试样抗侵蚀性和抗渗透性均较好。     

粘土结合耐火浇注料的研制

选用山东特级焦宝石、贵州焦宝石、河南三级高铝矾土熟料和山西阳泉特级高铝矾土熟料为骨料 ,河南三级高铝矾土熟料和山西阳泉特级高铝矾土熟料的球磨粉为基质 ,广西软质粘土为结合粘土 ,三聚磷酸钠、六偏磷酸钠、柠檬酸钠、酒石酸钠、酒石酸钾钠、碳酸钠 6种钠盐作分散剂 ,铝 60高铝水泥作促凝剂 ,配制了 4种不同组成的粘土结合耐火浇注料。在试验研究的基础上 ,分析了不同分散剂对广西软质粘土的分散效果 ,分散剂在粘土 -水体系中的分散机理和不同骨料对粘土结合耐火浇注料性能的影响。结果表明 :分散剂的分散效果以六偏磷酸钠为最好 ;以广西软质粘土作结合剂 ,用烧结良好的特级高铝矾土熟料作耐火骨料研制的粘土结合耐火浇注料 ,用水量少 ,气孔率低 ,结构致密 ,强度高     

Flow and Flow Decay of Refractory Castables

Installation of refractory castables depend not only on flow,but also on how soon the flow is lost because of setting.The loss of flow(flow decay)has always been one of the main problems of refractory castable manufacturers,a problem that has not been too well described in literature.The flow decay has been studied for a castable system based on alumina,pointing out some general trends.The flow decay was found very temperature sensitive,being strongly accelerated by temperature increases.To compensate for excessive flow loss,a retarder like citric acid may be used.Thus flow decay was measured as a function of citric acid(retarder) addition at 35℃.     

纳米碳酸钙加入量对刚玉质浇注料性能的影响

以纯铝酸钙水泥为结合剂,研究纳米碳酸钙的加入量对刚玉质浇注料性能和显微结构的影响。结果表明,添加的纳米碳酸钙在热处理后与基质中的氧化铝反应形成片状的六铝酸钙,影响了浇注料的性能;随着纳米碳酸钙加入量的增加,在110℃热处理后浇注料的显气孔率和体积密度变化不大,耐压强度和抗折强度都略有增大,而在1000、1500、1600℃热处理后,浇注料显气孔率均逐渐增大,相应的体积密度均逐渐减小,耐压强度和抗折强度均逐渐降低。纳米碳酸钙的加入量能提高试样的强度保持率,但热震后试样的强度均明显降低;浇注料经1000～20℃一次水冷后强度保持率逐渐提高,热震性能有所改善;XRD和SEM分析结果表明,在高温热处理过程中纳米碳酸钙与刚玉反应形成片状的六铝酸钙,对结构产生不利影响,从而导致在高温热处理后,随着纳米碳酸钙加入量的增加,浇注料的显气孔率逐渐上升,强度逐渐降低。     

On the calibration of cohesive parameters for refractories from notch opening displacements in wedge splitting tests

Cohesive elements are commonly used to describe crack propagation in heterogeneous materials with toughening mechanisms. This work aims to provide a guideline on how these fracture parameters can be calibrated using notch opening displacements (NODs) measured via digital image correlation and force data from wedge splitting tests (WSTs). Weighted finite element model updating was applied to calibrate material and boundary condition parameters in the same framework. The influence of each parameter on force and NOD data are given together with uncertainties for the calibrated parameters. Numerical results were in very good agreement in terms of splitting force, NOD, displacement and gray level residual fields. It is shown that images obtained during WSTs focusing on the crack path (i.e., hiding the loading region) can be used to drive numerical simulations and obtain cohesive parameters.     

硅铝溶胶结合剂对钢包耐火浇注料性能的影响

以致密刚玉、尖晶石细粉、氧化铝微粉、镁砂细粉等为原料,硅铝溶胶为结合剂制备钢包浇注料.研究不同硅铝溶胶含量对浇注料试样体积密度、显气孔率、抗折强度、耐压强度和抗渣性等性能的影响.结果表明:随着硅铝溶胶含量的增加,浇注料的显气孔率降低、体积密度增加;浇注料的耐压强度及抗折强度随着硅铝溶胶含量的增加先增大,硅铝溶胶质量分数...