全文获取类型
收费全文 | 5671篇 |
免费 | 499篇 |
国内免费 | 260篇 |
专业分类
电工技术 | 51篇 |
技术理论 | 1篇 |
综合类 | 368篇 |
化学工业 | 3133篇 |
金属工艺 | 214篇 |
机械仪表 | 40篇 |
建筑科学 | 179篇 |
矿业工程 | 266篇 |
能源动力 | 77篇 |
轻工业 | 507篇 |
水利工程 | 52篇 |
石油天然气 | 405篇 |
武器工业 | 116篇 |
无线电 | 44篇 |
一般工业技术 | 424篇 |
冶金工业 | 491篇 |
原子能技术 | 41篇 |
自动化技术 | 21篇 |
出版年
2024年 | 31篇 |
2023年 | 49篇 |
2022年 | 99篇 |
2021年 | 138篇 |
2020年 | 137篇 |
2019年 | 125篇 |
2018年 | 115篇 |
2017年 | 165篇 |
2016年 | 223篇 |
2015年 | 197篇 |
2014年 | 307篇 |
2013年 | 351篇 |
2012年 | 397篇 |
2011年 | 410篇 |
2010年 | 319篇 |
2009年 | 336篇 |
2008年 | 283篇 |
2007年 | 348篇 |
2006年 | 347篇 |
2005年 | 305篇 |
2004年 | 259篇 |
2003年 | 225篇 |
2002年 | 203篇 |
2001年 | 166篇 |
2000年 | 162篇 |
1999年 | 138篇 |
1998年 | 115篇 |
1997年 | 82篇 |
1996年 | 59篇 |
1995年 | 48篇 |
1994年 | 55篇 |
1993年 | 43篇 |
1992年 | 34篇 |
1991年 | 22篇 |
1990年 | 20篇 |
1989年 | 16篇 |
1988年 | 19篇 |
1987年 | 29篇 |
1986年 | 14篇 |
1985年 | 9篇 |
1984年 | 8篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1964年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有6430条查询结果,搜索用时 15 毫秒
1.
实验研究了以工业硫酸亚铁及废硫酸为原料,分别采用NaClo_3、KClO_3、H_2O_2及(o_2+NaNO_2)为氧化剂成聚硫酸铁的条件。在以(O_2+NaNO_2)为氧化剂的合成过程中,发现添加微量助催化剂(型号为HG-1、HG-2和HG-3),对提高合成速度及反应过程的稳定性具有重大作用。 相似文献
2.
María P. Albano Liliana B. Garrido 《Journal of Materials Synthesis and Processing》2002,10(4):211-218
Si3N4powders coated with 6 wt% Y2O3and 4 wt% Al2O3were prepared by coprecipitation. The resulting powders were dispersed in water at different pH values and with addition of various amounts of ammonium polyacrylate (NH4PA) to produce 32 vol% slips. The influence of the amount of NH4PA solution added and pH on the rheological properties of 32 vol% coated Si3N4slips were studied. In addition, the sintered density of cast samples was determined and related to the degree of slip dispersion. The adsorption of the NH4PA on the coated particle surface was rather high and the surface became saturated near 0.86 mg/m2at pH 9.2. High NH4PA concentrations (1.7–3 wt%) were necessary to obtain well dispersed 32 vol% coated Si3N4slips at pH 9.2. The best stabilization was obtained with the addition of 2.3 wt% NH4PA; in this condition, the viscosity reached a minimum value of 35 mPa.s at 100 s–1. The slip viscosity increased with increasing pH from 9.2 to 10.2. Slips with low viscosities gave a more dense packing of cast samples and consequently higher sintered density values. 相似文献
3.
十二酰胺丙基二甲基羟乙基氯化铵与十二烷基硫酸钠水溶液的表面吸附和胶束形成 总被引:1,自引:0,他引:1
利用十二酰胺丙基二甲胺和氯乙醇反应 ,合成了十二酰胺丙基二甲基羟乙基氯化铵 (DDHA)阳离子表面活性剂 ,将其与十二烷基硫酸钠 (SDS)以不同摩尔比进行混合 ,测定了混合系统的表面张力 ,计算了单一系统和混合系统的饱和吸附量、分子最小截面积 ,表面层和胶束中 DDHA的摩尔分率及分子间相互作用参数 ,目视观察了混合系统的浑浊情况。结果表明 :在降低γcmc和 cmc方面 ,DDHA SDS混合系统有协同效应 ,表面层和胶束的组成与二组分配比有关 ,但是非对称的 ,等物质的量混合物中 ,DDHA在胶束和表面层中具有较大的摩尔分数。DDHA与 SDS在实验测定的各混合系统中都不出现混浊 相似文献
4.
In this work, we examine the effect of small additions of cationic quaternary ammonium salts (QAS) of different molecular weight on the rheology of an industrial ceramic suspension deflocculated with sodium polyacrylate and sodium metasilicate. The observed shear thinning behaviors obey the typical power law of fluid rheology. In order to characterize the rheological behavior of these slurries, three new parameters are introduced: a low shear rate consistency index and two transient viscosities, distant from the equilibrium, after increasing and decreasing the shear rates. These parameters vary with polyacrylate molecular weight and on additions of small quantities of QAS, which we found to be useful for decreasing the slurry viscosity. 相似文献
5.
Sipra Mahapatra Turaga P. Prasad 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1992,53(2):201-203
Hydrolysis of Fe(OH)SO4 was carried out in the presence of metallic iron in order to prevent the formation of iron(III) oxides with strongly bonded sulphate. Under the conditions of the experiment, the products were found to be mixtures of ?-Fe2O3 and α-FeOOH. The occluded sulphate, if any, could be easily washed out with water. The hydrolysis reaction passes through an equilibrium state before coming to completion. The entropy with enthalpy of the hydrolysis corresponding to the equilibrium state were found to be 4 e.u. and 0·5 kJ/mol, respectively. The activation energy of the hydrolysis reaction was found to be 21 kJ/mol. 相似文献
6.
7.
A series of long-chain quaternary ammonium halogen esters (UKK-chemicals), quaternary dimethyl tallow epoxypropyl ammonium
halogens (EPK1), quaternary ditallow methyl epoxypropyl ammonium halogens (EPK2), and EPK2 oligomers (EPK2P) were synthesized.
At acidic, neutral, or slightly basic conditions, EPK1-, EPK2-, EPK2P-, and UKK-chemicals operate as cationic chemicals. They
can be used, for example, as stock sizings, surface sizings, or fixatives. Stock sizing, surface sizing, and fixative experiments
indicate that EPK1-, EPK2-, EPK2P-, and UKK-chemicals function at least as well as or better than the corresponding synthetic
chemicals used in papermaking. 相似文献
8.
废电解液除杂制取硫酸铜和粗镍 总被引:1,自引:0,他引:1
介绍了废电解液除杂制取硫酸铜和粗镍的主要工艺条件及试验结果。在废电解液中加入CH80调节pH值到一定范围后,再加入CH64将电解液中Fe2+等杂质除去,铁的去除率可达到94%~98%。然后向滤液中加入CH80调节pH值沉淀铜。过滤后的滤饼用H2SO4溶解后再结晶,可得到CuSO4·5H2O晶体。滤液中加入Na2CO3沉淀镍,过滤后的滤饼即为粗镍(NiCO3)。铜和镍的回收率分别达96%和90%。该流程简单,投资少,效益高,环境保护好,在工业上有较广的应用前景。 相似文献
9.
Shuichi Osanai Yoshiro Abe 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1985,35(1):43-45
Optically active and racemic quaternary ammonium cationics containing a chiral alkyl group, such as N,N-dimethyl-N-(1-phenylethyl)alkylammonium bromides were prepared and showed excellent antimicrobial properties against Gram positive and negative bacteria, with some exceptions, and against fungi. The influence of optical isomerism on their antimicrobial properties showed that the antimicrobial properties between racemic and optically active cationics were obscure. The order of activity of substituted alkyl groups was tetradecyl > dodecyl ° hexadecyl. 相似文献
10.
钼酸铵生产中杂质的分离方法 总被引:1,自引:0,他引:1
简要地介绍了钼酸铵生产中有害杂质的各种分离方达及应用情况,并就各种方法的利弊作了对比说明。 相似文献