Fully renewable limonene‐derived polycarbonate as a high‐performance alkyd resin

Limonene‐derived polycarbonate‐based alkyd resins (ARs) have been prepared by copolymerization of limonene dioxide with CO₂, catalysed by a β‐diiminate zinc–bis(trimethylsilyl)amido complex, and subsequent chemical modification with soybean oil fatty acids using triphenylethylphosphonium bromide as the catalyst. This quantitative partial modification was realized via epoxy–carboxylic acid chemistry, affording ARs with higher oil lengths, lower polydispersities and higher glass transition temperatures (T_g) in comparison to a conventional polyester AR based on phthalic acid, multifunctional polyol pentaerythritol and soybean fatty acid. The novel limonene polycarbonate AR and the conventional polyester AR were evaluated as coatings and both the physical drying (without the presence of the oxidative drying accelerator Borchi® Oxy Coat) and chemical curing (with Borchi® Oxy Coat) processes of these coatings were monitored by measuring the König hardness and complex modulus development with time. A better performance was obtained for the alkyd paint containing polycarbonates modified with fatty acids (FA‐PCs), which showed a faster chemical drying, a higher König hardness and a higher T_g in coating evaluation, demonstrating that the fully renewable FA‐PCs are promising resins for alkyd paint applications. © 2019 Society of Chemical Industry     

气相二氧化硅生产现状及其在涂料中的应用

介绍了气相二氧化硅国内外生产状况,根据气相二氧化硅在涂料方面的应用特点及主 要技术关键的分析,提出了建议。     

粉末涂料在汽车涂装中的应用

介绍了粉末涂料的组成、优越性以及各种性能，分析了粉末涂料在汽车涂装中的经济性，肯定了粉末涂料在汽车工业中的应用前景。     

水溶性丙烯酸涂料的环氧树脂改性

本实验论述了水溶性丙烯酸钢铁底漆涂料制备、性能以及用环氧树脂对其进行改性。原水溶性丙烯酸钢铁底漆涂料在进行耐盐雾测定试验时仅为 72h ,未通过国家规定标准。本实验的目的在于 ,以丙烯酸树脂为主要成膜物质 ,加入其他的辅助成膜物质 ,如环氧树脂来改善其抗盐雾、抗腐蚀、耐候等性能。结果表明 ,一定温度下在水溶性丙烯酸钢铁底漆涂料中加入 1/ 7的环氧树脂后 ,经测定其耐盐雾性可达 10 6h ,达到了国家的规定标准     

城市形象的建筑环境美学设计问题

城市形象是创造富于个性化城市的关键,而建筑环境美学设计水准则是体现城市形象的要素之一。据此,作者从分析中国城市形象的美学误区出发,研究了不同城市建筑品位的形成特点,进而提出塑造好宜人城市美学空间的科学思考。     

Effect of powder painting procedures on the filiform corrosion of aluminium profiles

In this work, the filiform corrosion behaviour of powder painted aluminium profiles was studied, and the coating barrier properties together with adhesion to the substrate were analysed. Samples coated with a traditional painting procedure (one powder layer application followed by curing), and other samples coated using a special cycle to obtain wood grain effect were compared using accelerated filiform corrosion tests. Moreover, in order to better understand the degradation mechanisms of painted metal substrates, thermal stresses were applied to accelerate the natural weathering. The effects of the thermal aging were analysed by electrochemical impedance spectroscopy.     

建筑制图标准中图形符号适宜性、区分性的研究

应用线段长短、间距大小视觉反应的量化规律，提出设计图形符号大小的原则——既更使其大小满足“长”“短”“大”“小”的心理要求，又要互相之间在大小上有区分性。根据图形组织的相似、接近、连续三原则提出设计图形符号形状的原则——图形符号之间尽量减少相似、接近、连续，以保证较好的区分性。通过分析发现，现行建筑制图标准中的图形符号绝大部分在大小和形状具有适宜性、区分性。     

居住建筑设计的点滴体会

根据石河子的地理位置、自然环境和居住建筑发展的历史,为当地设计了功能较全,布局合理,实用性强的住宅楼。通过设计实践对住宅设计提出了一些看法。     

钠水玻璃涂料的固化技术及其应用

论述了五种固化剂改性钠水玻璃的原理及在涂料中的应用，重点介绍了用可溶性金属盐必性钠水玻璃制作涂料的技术关键。