Bamboo biochar-catalytic degradation of lignin under microwave heating

Abstract

Lignin biochar-catalytic depolymerization using biochar Fe-600, Fe-800, Ni-600, Ni-800 catalysts under microwave-heating (180?°C for 30?min) was explored in an ethanol/formic acid (1:1) media. Non-catalyst depolymerization was also studied and compared with the biochar-catalysts results. Characteristics of the bio-char catalysts were analyze by BET, XRD, and FT-IR. GPC, FT-IR, and MALDI-TOF MS spectrometry were also used to characterize the depolymerization products. The experimental results showed that the S_BET, V_t, and V_mec and average pore diameter of the biochars are considerably dependent on the preparation temperature and type of cation (Ni²⁺ or Fe³⁺). The maximum yield of bio-oil product was obtained as 85?wt% with the addition of biochar Ni-600 and the total amount of oligomers or monomers with a molecular weight of 164 to 446 reaches 80.4%.     

动态高压微射流处理对方竹笋膳食纤维理化及结构特性的影响

以方竹笋中提取的膳食纤维为研究对象，采用动态高压微射流（dynamic high-pressure micro-fluidization, DHPM）在不同压力条件（0，50，100，150，200 MPa）下进行处理，探究其对竹笋膳食纤维（bamboo shoots dietary fiber, BSDF）理化和结构特性的影响。结果表明，随着处理压力的增大，BSDF粒径先增大后减小，当处理压力为150 MPa时，粒径最小，为（370±11） nm，此条件下BSDF的持水力、持油力和膨胀力达到最大，较对照组分别提高了47.74%，50.54%，61.27%，且差异显著（P<0.05）。红外光谱分析表明DHPM处理不会改变BSDF的官能团，但会使BSDF内部的部分氢键断裂和半纤维素、木质素等发生降解；X射线衍射和热重分析表明DHPM处理不会引起BSDF的晶体结构改变，但晶体有序度会下降，进而导致其热稳定性降低；微观结构分析显示DHPM处理会使BSDF颗粒尺寸减小、表面粗糙、组织松散，且当处理压力为200 MPa时，颗粒发生团聚。综上，DHPM可以有效改善BSDF的理化性质，在膳食纤维改性方面具有一定的应用价值。     

小麦、玉米控制灌溉技术研究

198 6～ 1998年 ,在山东省的 3个灌溉试验站 ,对冬小麦、秋玉米进行了控制灌溉试验 ,对农作物的多个生育阶段 ,按高产的要求 ,分别给予适时、适量的灌溉水 ,来控制作物不同生长期的根层土壤含水量 ,从而控制作物不同生长期根系对水分的吸收 ,培植农作物的“丰产群体结构”和与之相适应的“高产理想株型” ,适当降低无效的蒸腾量 ,使农作物能在高产的基础上再增产 .该项控制灌溉技术获得了明显的节水、增产效果 ,灌溉水的生产效率超过了 10kg/m3,产量超过了 8t/hm2 .     

竹/玻璃钢复合建筑材料的研制及性能分析

竹/玻璃钢复合建筑材料是一种新型三维复合材料.本文对其进行了结构设计的研究,并通过大量试验对其力学性能进行了分析,结果证明竹/玻璃钢复合建筑材料确实是一种重量轻、性能好、工艺简单、价格便宜的材料,具有广阔的应用前景.     

Tasting green leaf volatiles by larvae and adults of Colorado potato beetle,Leptinotarsa decemlineata

Larvae and adults of the Colorado potato beetle,Leptinotarsa decemlineata (Say), are shown to have galeal gustatory cells that are highly sensitive to distillate of potato leaf extracts, (E)-2-hexen-1-ol, (E)-2-hexenal, and other saturated and unsaturated six-carbon alcohols. In larvae and adults, the sensory response patterns elicited by leaf homogenate, leaf distillate and a mixture of these two extracts differ in subtle ways. Beetle larvae feed most readily on Millipore disks treated with leaf homogenate and the mixture, but they did not feed on disks treated with leaf distillate. The differences in behavioral response and sensory input are used to derive a potential gustatory code that may stimulate different levels of feeding. This code may be disrupted by compounds present in nonhost leaves, thus leading to reduced feeding. Possible interactions of sapid leaf volatiles, amino acids, sugars, and potentially deterrent plant compounds are discussed.     

高水头船闸一字闸门水动力特性数值模拟

针对某山区高水头船闸30 m淹没水深下一字闸门的水动力特性进行研究,借助FLUENT软件提供的Realizable k-ε紊流模型对门体启闭过程非恒定流场进行动态模拟,通过建立由二维平面混合网格纵向拉伸成的三维棱柱体网格,结合2.5D重构和弹性光顺动网格法,在降低网格数量、提高计算效率的同时,实现一字闸门启闭全过程三维流场模拟。引入VOF法对自由水面迭代求解,得到一字闸门启闭过程门前后水位差及动水阻力矩变化规律,将计算结果与模型试验进行比较,两者吻合较好。模拟计算发现:门底间隙对闸门运行整个阶段动水阻力矩均有影响,动水阻力矩峰值随门底间隙增大而变小。     

Variation among and within mountain birch trees in foliage phenols,carbohydrates, and amino acids,and in growth ofEpirrita autumnata larvae

Leaf quality of the mountain birch (Betula pubescens ssp.tortuosa) for herbivores was studied at several hierarchical levels: among trees, among ramets within trees, among branches within ramets, and among short shoots within branches. The experimental units at each level were chosen randomly. The indices of leaf quality were the growth rate of the larvae of a geometrid,Epirrita autumnata, and certain biochemical traits of the leaves (total phenolics and individual phenolic compounds, total carbohydrates and individual sugars, free and protein-bound amino acids). We also discuss relationships between larval growth rate and biochemical foliage traits. Larval growth rates during two successive years correlated positively at the level of tree, the ramet, and the branch, indicating that the relationships in leaf quality remained constant between seasons both among and within trees. The distribution of variation at different hierarchical levels depended on the trait in question. In the case of larval growth rate, ramets and short shoots accounted for most of the explained variation. In the case of biochemical compounds, trees accounted for most of the variance in the content of total phenolics and individual low-molecular-weight phenolics. In the content of carbohydrates (total carbohydrates, starch, fructose, glucose, and sucrose) and amino acids, variation among branches was generally larger than variation among trees. Variation among ramets was low for most compounds. No single leaf trait played a paramount role in larval growth. Secondary compounds, represented by phenolic compounds, or primary metabolites, particularly sugars, may both be important in determining the suitability of birch leaves for larvae. If phenols are causally more important, genet-specific analyses of foliage chemistry are needed. If sugars are of primary importance, within-genet sampling and analysis of foliage chemistry are necessary.     

Chlorosis in sugarcane: Associated soil properties,leaf mineral composition,and crop response to iron and manganese

Attempts were made to find out the nature and cause of a widespread sugarcane chlorosis in a cane growing area. Soils from chlorotic and nonchlorotic fields did not differ markedly in pH, CaCO₃, electrical conductivity, organic C, and soil test P, Zn, Cu, and Mn levels, but the chlorotic field soils had relatively more NH₄OAc-extractable K and less clay and DTPA-extractable Fe. Chlorotic and green leaf blades contained about the same concentration of P, S, Mg, Fe, Zn, Cu, and Mo, but the former leaf blades had more K and less Ca and HCl soluble Fe than the green ones. Green leaves of plants that seemed to have naturally recovered in chlorotic fields were higher in Mn. A foliage spray with 2.5% FeSO₄.7H₂O solution resulted in greening of leaves and a field experiment showed marked crop response to Fe and some response to Mn. The results thus suggest that the chlorosis is due to a lime-induced Fe-deficiency with the possibility of some role of Mn in Fe nutrition in calcareous soil conditions.Deceased 22 September 1988