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Jianglei Qin Hongzhi Liu Pei Zhang Michael Wolcott Jinwen Zhang 《Polymer International》2014,63(4):760-765
In this study, an epoxy based on eugenol and an anhydride curing agent based on rosin were prepared. Curing of the eugenol epoxy with a commercial anhydride curing agent and with the rosin‐derived anhydride curing agent was studied. For comparison, a commercial bisphenol A type epoxy, DER353, was also selected in the curing study. The syntheses of the eugenol epoxy and rosin anhydride were investigated and the chemical structures of the products and intermediates were characterized using 1H NMR and Fourier transform infrared spectroscopies. Non‐isothermal curing of the eugenol epoxy with hexahydrophthalic anhydride and the rosin‐derived maleopimaric acid was studied using differential scanning calorimetry. Thermomechanical properties and thermal stability of the cured epoxy resins were evaluated using dynamic mechanical analysis and thermogravimetric analysis, respectively. Addition of 2‐ethyl‐4‐methylimidazole as catalyst greatly decreased the curing temperature and promoted the completion of cure reactions. The results suggest that the eugenol epoxy and the bisphenol A type epoxy have similar reactivity, dynamic mechanical properties and thermal stability. © 2013 Society of Chemical Industry 相似文献
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Mohammed Khalifa Alexander Berndt Shamitha C. Stefan Pichler Herfried Lammer Guenter Wuzella 《应用聚合物科学杂志》2023,140(2):e53297
An ever-increasing rise in demand for sustainable materials has received significant attention in developing biocomposites for structural applications. In this regard, natural fibers replacing synthetic fibers as reinforcement in epoxy composite could be a significant gain toward sustainability, especially in automobile and structural applications. Herein, flax fiber/cellulose paper–reinforced epoxy biocomposite (FREC-X) was fabricated via a vacuum infusion process. The influence of postcuring conditions (time and temperature) and cellulose paper density on the mechanical properties of FREC-X was studied. The tensile strength and modulus of FREC-X increased by 37% and 64%, respectively, upon the integration of paper. Postcuring FREC-X further augmented the tensile and flexural properties of the composite, which could be attributed to the increase in cross-linking of the epoxy and yields a strong polymer network. Fractography analysis confirmed that the composites integrated with paper showed fewer defects with improved interfacial adhesion. In addition, the water absorption and thickness swelling results revealed that the presence of cellulose paper marginally increased the water uptake and thickness swelling of FREC-X. Furthermore, there was no significant change in the tensile and flexural properties of FREC-X observed even after immersing in water for >200 h. Such properties of FREC-X seen as a fascinating alternative to synthetic fibers and petroleum-based epoxy and are promising material for sustainable development. 相似文献
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The current study aims to identify the preferred combination of factors for manufacturing bioepoxy/clay nanocomposites based on epoxidised soybean oil (ESO), including material formulation and manufacturing parameters for maximising tensile strengths of nanocomposites according to Taguchi design of experiments (DoEs). A Taguchi mixed-level DoEs with an L 16 orthogonal array was selected. The response was set to achieve the maximum tensile strengths of nanocomposites with a preferred combination of factors determined by the Pareto analysis of variance (ANOVA). The associated results revealed that the ESO content was found to be the most significant factor with a contribution percentage of 66.63% amongst nine factors investigated. This result was followed by two less significant factors, namely mechanical mixing speed and clay content with contribution percentages of 19.09 and 7.01%, respectively. However, other factors of clay type, curing agent type, mechanical mixing temperature and time, as well as sonication frequency and time, were categorised as non-significant factors from the manufacturing and economical point of view. A confirmation test was conducted based on the preferred combination of factors showing good agreement with statistically predicted results. 相似文献
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