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硼酸在润滑油添加剂领域的应用现状 总被引:1,自引:0,他引:1
硼元素引入润滑油添加剂中可改善和提高油品的抗磨性能以及热稳定性能等。硼元素是通过硼酸与碱性化合物反应而引入添加剂分子上的,因而,硼酸已逐步成为润滑油添加剂的重要原料之一。介绍了硼酸在润滑油添加剂中的应用现状,包括含硼清净剂、含硼分散剂、含硼极压抗磨剂、含硼防锈剂。主要介绍了世界各大石油公司生产含硼润滑油添加剂的商品牌号、合成方法等。指出随着中国汽车工业的发展,环保、节能法规的不断出台与执行力度的加大,含硼等环保、节能型润滑油添加剂将得到广泛的使用,其中硼化丁二酰亚胺市场潜力巨大。 相似文献
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硼化丁二酰亚胺添加剂的合成及性能考察 总被引:1,自引:1,他引:0
为了提高丁二酰亚胺添加剂的抗氧化安定性和热稳定性,采用两条路线合成了硼化丁二酰亚胺并对其性能考察。热管氧化试验及热分析结果表明,硼化丁二酰亚胺的抗氧化性及热稳定性均优于未硼化丁二酰亚胺,是一种有前途的润滑油添加剂。 相似文献
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Stereodefined cyclohexene and cyclopentene derivatives were prepared by the coupling of allylic alcohols and other allylic precursors with unsaturated aldehydes. These reactions are based on a multicatalytic one‐pot approach involving palladium pincer complex‐catalyzed boronation, allylation and ring‐closing metathesis reactions. This reaction sequence can be performed in an operationally simple procedure affording the cycloalkene products in high overall yields and excellent regio‐ and stereoselectivities. The presented procedure has a broad synthetic scope and high functional group tolerance, which allows the synthesis of bicyclic lactone and spirane skeletons and various substitution patterns including hydroxy, silyl, vinyl, allyl, and sulfonyl groups. The studied catalytic one‐pot reactions involve up to three individual processes performed by up to four acid‐ and transition metal‐catalyzed events. 相似文献
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