直接氯化法合成对硝基氯化苄

介绍了以对硝基甲苯和氯气为原料 ,在催化剂存在下合成对硝基氯化苄的方法 ,考察了催化剂种类、反应温度、溶剂配比等因素对反应的影响 ,优化的反应条件为 :对硝基甲苯用量 1 3 7g,对硝基甲苯 /邻二氯苯 (摩尔比 ) =1∶ 0 .6,w (偶氮二异丁腈 ) =0 .6% ,反应时间 3 h,反应温度 1 60℃ ,产物单程收率大于 65 % ;将反应混合物中未反应的原料分离后 ,以无水乙醇为溶剂结晶纯化 ,物料 /溶剂 (摩尔比 ) =1∶ 1 .5时晶体含量在 99.0 %以上 ,结晶收率达 67     

A procedure to prepare cross-sectional samples for TEM

Cross-sectional transmission electron microscopy (XTEM) is an imaging technique particularly suited to the study of layered structures. For integrated electronic devices it has become a common practice to use XTEM to assess the shape and crystallinity of component layers as well as defect structures introduced by processing. A procedure for preparing samples to be viewed by XTEM is described.     

2-环戊基环戊酮香料的制备与应用

以尼龙酸副产物2-亚环戊基环戊酮为原料，液体镍为催化剂，催化加氢制得了2-环戊基环戊酮。经元素分析、GCMS、IR、^1HNMR、^13C NMR检测，认为结构正确，色谱纯度大于99．9％。大鼠口服LD50雄性5381．5mg／kg，雌性5087．5mg／kg。具有留兰香样的香气，可用作食用和日用香料。     

Preparation of Plate Fe_(60)Co_8Zr_(10)Mo_5W_2B_(15) Bulk Amorphous Alloy and Its Fracture Toughness

1Introduction Duwez[1]synthesizedthefoilAu Siamorphousalloyforthefirsttimewithrapidsolidification,whichinitiatedthepreparationofamorphousalloysintheprocessofalloysolidification,andthereaftertheresearchonamorphousal loysdevelopedrapidly.Since1980s,withthec…     

Low temperature synthesis of aluminium titanate by an aqueous sol-gel route

Formation of aluminium titanate (AT) has been achieved at low temperature through sol-gel process using boehmite and titanium hydroxide as precursors by controlling the particle size at nanoscale followed by in-situ peptisation. The formations of AT phase, particle size distributions, sintering and thermal expansion characteristics, and microstructural features have been reported. DTA and XRD analysis have been performed to confirm the formation of AT. A 94% relative density was obtained for aluminium titanate sintered at 1550 °C with controlled grain size in the range of 2-3 μm.     

化学还原法制备纳米铜粉的研究

本文采用KBH4在液相中化学还原CuSO4,并加入KOH和络合剂EDTA ,制得了纳米级的纯净的铜粉 ,通过调整反应物的浓度 ,可以消除Cu2 O等杂质。制备的纳米铜粉还存在一定程度的团聚 ,需试验加入分散剂来改善。