排序方式: 共有30条查询结果,搜索用时 366 毫秒
1.
镀锌层银盐黑色钝化工艺 总被引:1,自引:0,他引:1
在含AgNO30.5~1g/L,CrO35~10g/L,H2SO40.5~1ml/L,光泽控制剂10~25mL/L的钝化液中处理镀锌层,可获得结合力良好、光亮的黑色钝化膜。 相似文献
2.
总结了弱酸性链盐镀锌和碱性锌酸盐镀锌的优缺点,并综合两者的优点,提出了一种弱酸性铵盐与碱性锌酸盐双缸套镀锌工艺。钝化膜的性能得到了改善。 相似文献
3.
镀锌层三价铬高耐蚀蓝白钝化工艺研究 总被引:10,自引:2,他引:8
三价铬钝化环境污染小,但钝化膜的耐蚀性不及六价铬钝化.为此,深入研究了三价铬钝化的耐蚀性.基于钝化液的基本组成配方,用正交试验法优化了镀锌层三价铬蓝白钝化工艺的最佳工艺参数和工艺范围:4.8g/LCrCl3,1.0mL/LH2SO4,1.0mL/LHNO3,2.5mL/L醇类添加剂,2.5mL/LHAc,钝化液温度25℃,浸渍时间15s,钝化液pH值1.8.研究了工艺参数与钝化层外观和耐蚀性的关系,在最佳工艺参数的条件下,进行镀锌层三价铬蓝白钝化处理,所得膜层经76h的中性盐雾试验不产生白锈,已超过了国家标准的48h. 相似文献
4.
Vidmantas Dikinis Violeta Rėzaitė Irina Demčenko Algirdas Seiskis Tauras Bernatavičius 《金属精饰学会汇刊》2013,91(3-4):98-104
The influence of the components of an acidic solution: Cr(III) nitrate-malonic acid-Co(II) salt and treatment conditions on zinc dissolution and formation of Chromate films as well as on their decorative and protective properties have been studied using the analytical, XPS, structural and accelerated corrosion test methods. An organic acid is the main component, which has an essential influence on zinc dissolution and formation of Chromate films as well as their decorative and protective properties. The influence of organic acid is directly related with the state of the Cr3+ ions in chromating solution. When the Cr3+ ions are in the form of hexaaquaions, the organic acid increases the quantities of the zinc dissolved and the Cr(III) deposited on the zinc surface (especially at 60°C). It also predetermines the formation of a thick, porous Chromate film with large cracks at 60°C. Its decorative and protective properties are rather poor. When Cr3+ ions are in the form of a complex with organic acid, the quantities of the zinc dissolved and the Cr(III) deposited on the zinc surface significantly decrease and thinner Chromate films with an even surface, good decorative appearance and high corrosion resistance are formed Decorative blue-bright Cr(VI)-free films with a slight iridescent tint, obtained in solution, containing Cr(III) nitrate (0.2), malonic acid (0.3) and Co(II) nitrate (0.02) mol dm?3, at p H 1.6-2.0 at room temperature over 30–60 s, possess corrosion resistance (192–240 h in a salt spray chamber) similar to that of iridescent Chromate films, obtained in acidic Cr(VI) solution. 相似文献
5.
采用伏安法测量镍盆电极在铬酸钝化液中的阴极极化曲线,本方法是先测定钝化液硫酸和硝酸存在时阴极极化的总电流峰值,然后加入适当过量的碳酸钡,使溶液中的SO^2-4离子完全沉淀,再测定此时阴极极化的电流峰值,由于电流峰值与硝酸,硫酸浓度呈线性关系,从而分别测得硝酸和硫酸的浓度。 相似文献
6.
7.
镀锌层蓝白钝化工艺研究 总被引:6,自引:0,他引:6
镀锌蓝白钝化是应用最广泛的镀锌钝化工艺。阐述了钝化液中各成分的作用及工艺条件的影响。介绍了钝化液的配方、配制、维护、钝化工艺流程及几个主要工序。探讨了钝化膜常见故障的原因并提出了解决方法。 相似文献
8.
锌镀层彩色低铬钝化工艺 总被引:1,自引:0,他引:1
提出了一种锌镀层彩色低铬钝化工艺采用TX-9511添加剂,讨论了钝化温度时间及干燥温度等对钝化膜层性能的影响。 相似文献
9.
10.
在加入硅烷偶联剂γ-APS的苯胺中性溶液中采用恒电流法在电镀锌钢板上制备聚苯胺膜,采用SEM观测其表面形貌,测试不同条件下聚合膜的厚度.交流阻抗和盐雾实验表明,加入γ-APS后,聚苯胺膜层的致密性和防护性明显提高,接近铬酸盐钝化膜.通过XPS分析,得到γ-APS改性聚苯胺膜掺杂度为11%、氧化度为64%;与改性前聚苯胺膜相比较,掺杂度降低、氧化度增高.结合红外光谱和XPS分析,发现聚苯胺膜中存在4种化学环境:C-Si-O-Si,C-Si-OH,C-Si-O-C,C-Si-O-Zn. 相似文献