全文获取类型
收费全文 | 10785篇 |
免费 | 939篇 |
国内免费 | 265篇 |
专业分类
电工技术 | 25篇 |
综合类 | 524篇 |
化学工业 | 6308篇 |
金属工艺 | 108篇 |
机械仪表 | 103篇 |
建筑科学 | 347篇 |
矿业工程 | 302篇 |
能源动力 | 75篇 |
轻工业 | 1610篇 |
水利工程 | 15篇 |
石油天然气 | 749篇 |
武器工业 | 36篇 |
无线电 | 73篇 |
一般工业技术 | 1419篇 |
冶金工业 | 137篇 |
原子能技术 | 115篇 |
自动化技术 | 43篇 |
出版年
2024年 | 50篇 |
2023年 | 117篇 |
2022年 | 214篇 |
2021年 | 254篇 |
2020年 | 251篇 |
2019年 | 272篇 |
2018年 | 251篇 |
2017年 | 323篇 |
2016年 | 292篇 |
2015年 | 302篇 |
2014年 | 480篇 |
2013年 | 592篇 |
2012年 | 675篇 |
2011年 | 675篇 |
2010年 | 582篇 |
2009年 | 559篇 |
2008年 | 507篇 |
2007年 | 661篇 |
2006年 | 737篇 |
2005年 | 631篇 |
2004年 | 547篇 |
2003年 | 479篇 |
2002年 | 390篇 |
2001年 | 354篇 |
2000年 | 350篇 |
1999年 | 305篇 |
1998年 | 259篇 |
1997年 | 200篇 |
1996年 | 132篇 |
1995年 | 111篇 |
1994年 | 116篇 |
1993年 | 97篇 |
1992年 | 73篇 |
1991年 | 41篇 |
1990年 | 26篇 |
1989年 | 32篇 |
1988年 | 10篇 |
1987年 | 8篇 |
1986年 | 3篇 |
1985年 | 8篇 |
1984年 | 7篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 1篇 |
1980年 | 5篇 |
1978年 | 1篇 |
1951年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 19 毫秒
1.
Yuhang Xing Ruyi Li Lu Xue Mianhong Chen Xuli Lu Zhihao Duan Wei Zhou Jihua Li 《International Journal of Food Science & Technology》2022,57(8):5268-5279
Mangiferin (MGF) is a phenolic compound isolated from mango, but its poor solubility significantly limits its use. In this study, MGF was embedded into the inner aqueous phase of W1/O/W2 emulsions. Firstly, the dissolution method of MGF was determined. MGF remained stable in solution with pH 13 at 30 min, and its solubility reached 10 mg mL−1. When the pH of MGF solutions was adjusted from pH 13 to pH 6, MGF did not immediately crystallise, providing sufficient time to construct the MGF-loaded W1/O/W2 emulsions. Subsequently, the MGF-loaded W1/O/W2 emulsions were constructed using polyglycerol polyricinoleate (PGPR) and calcium caseinate (CAS). The formation and stability of the W1/O/W2 emulsions were investigated. The MGF-loaded W1/O/W2 emulsions stabilised with 1% PGPR and 1% – 3% CAS exhibited a low viscosity, limited loading capacity, and poor stability. Conversely, the MGF-loaded W1/O/W2 emulsions stabilised by 3%PGPR–3%CAS exhibited optimal loading capacity (encapsulation efficiency = 95.31% and loading efficiency = 0.91%) and stability, which was attributed to the fact that high viscosity and gel state retarded the migration of inner aqueous phase. These results indicated that the W1/O/W2 emulsions stabilised by PGPR and CAS may be a potential alternative for encapsulating mangiferin. 相似文献
2.
An ecofriendly and biodegradable porous structure was prepared from drying aqueous foams based on nano fibrillated cellulose (NFC), extracted from softwood pulp by subcritical water/CO2 treatment (SC-NFC). The primary aim of this work was to use the modified SC-NFC as stabilizer for a water-based Pickering emulsion which upon drying, yielded porous cellulosic materials, a good dye adsorbent. In order to exploit the carboxymethylated SC-NFC (CMSC-NFC, with a degree of substitution of 0.35 and a charge density of 649 μeqv/g) as a stabilizer for water-based Pickering emulsion in subsequent step, an optimized quantity of octyl amine (30 mg/g of SC-NFC) was added to make them partially hydrophobic. A series of dry foam structures were prepared by varying the concentrations of treated CMSC-NFCs and 4 wt% was found to be the optimum concentration to yield foam with high porosity (99%) and low density (0.038 g/cc) along with high compression strength (0.24 MPa), superior to the conventionally extracted NFC. The foams were applied to capture as high as 98% of methylene blue dyes, making them a potential green candidate for treating industrial effluent. In addition, the dye adsorption kinetics and isotherms were found to be well suited with second order kinetics and Langmuir isotherm models. 相似文献
3.
Material encapsulation is a relatively new technique for coating a micro/nanosize particle or droplet with polymeric or inorganic shell. Encapsulation technology has many applications in various fields including drug delivery, cosmetic, agriculture, thermal energy storage, textile, and self-healing polymers. Poly(methyl methacrylate) (PMMA) is widely used as shell material in encapsulation due to its high chemical stability, biocompatibility, nontoxicity, and good mechanical properties. The main approach for micro/nanoencapsulation of materials using PMMA as shell comprises emulsion-based techniques such as emulsion polymerization and solvent evaporation from oil-in-water emulsion. In the present review, we first focus on the encapsulation techniques of liquid materials with PMMA shell by analyzing the effective processing parameters influencing the preparation of PMMA micro/nanocapsules. We then describe the morphology of PMMA capsules in emulsion systems according to thermodynamic relations. The techniques to investigation of mechanical properties of capsule shell and the release mechanisms of core material from PMMA capsules were also investigated. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48039. 相似文献
4.
5.
Interactions of hexamethylenetetramine ligand in atom transfer radical polymerization initiated by activator generated by electron transfer were studied. Polymerization of methyl methacrylate was done using two-step experimental procedure in 2 L emulsion batch reactor at 50, 60, and 80°C. The selection of reactant ratios was quite challenging for a reactor of this size. Replicate runs were conducted for data reproducibility purpose. Gravimetry method and gel permeation chromatography were used to determine monomer conversion, Mn, and PDI of polymer samples. PMMA produced was also characterized by means of dynamic light scattering, Fourier-transform infrared spectroscopy and nuclear Magnetic Resonance spectroscopy. Results showed high monomer conversion up to 93% and Mn ranging 243–274 kg/mol with PDI from 1.45 to 1.60. Besides, combining HMTA with sodium dodecyl sulfate, an anionic surfactant, a well-controlled polymer with a lower Mn of 201 kg/mol and PDI of 1.56 was obtained in 3 hr reaction time. 相似文献
6.
高温高压下甲烷在油里的溶解度大,水包油乳化钻井液中存在油相,钻井作业中钻井液静置期间如起下钻、工具故障抢修等时间过长,储层中的甲烷气体会扩散到井眼里。在钻高含硫化氢及二氧化碳气井时,高温高压条件下天然气更有可能到达与油完全互溶的状态。文章将储层内的水平段井眼的气体扩散区域划分为4个区,外滤饼区、内滤饼区、滤液滞留区、滤液未污染区,根据外滤饼区、内滤饼区、滤液滞留区不同计算参数条件,计算预测了在使用水包油乳化钻井液情况下,储层中天然气通过扩散穿过3个区后,进入储层内井眼段环空导致的环空含气质量浓度变化,对环空内含气质量浓度随扩散时间、含油浓度因素的变化进行了定量计算。用伽略金有限元方法求解,计算表明,气体扩散量随钻井液静置时间延长而增加,水基钻井液加入油后与不加油的钻井液相比增大了气体扩散量。 相似文献
7.
改性乳化沥青的发展和应用概况 总被引:1,自引:0,他引:1
综述了改性乳化沥青的发展及应用概况,重点讨论了改性乳化沥青的生产、制备工艺、稳定性影响因素,并对国内外改性乳化沥青的应用情况加以概述。 相似文献
8.
采用辐照接枝的方法,在高密度聚乙烯(HDPE)上接枝丙烯酸(AA)和对苯乙烯磺酸钠(SSS),从而削备出了一种含羧酸基团和磺酸基团的阳离子交换膜。详细研究了接枝体系中引入添加剂醋酸钠或氯化钠对接枝率的变化规律.实验表明,在预辐照接枝和共辐照接枝中,当AA接技PE或AA与SSS共同接枝PE时,强碱弱酸盐醋酸钠通过pH效应同离子效应对接枝率呈现复杂的影响,而中性盐氯化钠经离子对效应显著提高接枝率。 相似文献
9.
10.
高分子表面活性剂对超声辐照下苯乙烯乳液聚合的影响 总被引:1,自引:0,他引:1
在超声辐照引发苯乙烯乳液聚合中加入一种新型的以羧甲基纤维素为基础的高分子表面活性剂(CMC—A9),讨论了高分子表面活性剂对反应动力学的影响。实验表明,超声辐照下初级自由基并非由通常认为的高分子表面活性剂产生,而是十二烷基硫酸钠在超声辐照下断裂,产生自由基。通过对反应动力学的研究,发现超声辐照下乳液聚合机理不同于常规乳液聚合,聚合反应过程只有两个阶段,即加速期和减速期,不存在恒速期。加入CMC—A9高分子表面活性剂,可以在较短的时间内和较低的超声功率下达到较高的单体转化率。 相似文献