全文获取类型
收费全文 | 5439篇 |
免费 | 408篇 |
国内免费 | 826篇 |
专业分类
电工技术 | 25篇 |
综合类 | 407篇 |
化学工业 | 519篇 |
金属工艺 | 2722篇 |
机械仪表 | 127篇 |
建筑科学 | 145篇 |
矿业工程 | 101篇 |
能源动力 | 172篇 |
轻工业 | 121篇 |
水利工程 | 39篇 |
石油天然气 | 111篇 |
武器工业 | 58篇 |
无线电 | 194篇 |
一般工业技术 | 1091篇 |
冶金工业 | 692篇 |
原子能技术 | 121篇 |
自动化技术 | 28篇 |
出版年
2024年 | 28篇 |
2023年 | 127篇 |
2022年 | 195篇 |
2021年 | 217篇 |
2020年 | 183篇 |
2019年 | 176篇 |
2018年 | 151篇 |
2017年 | 179篇 |
2016年 | 156篇 |
2015年 | 157篇 |
2014年 | 226篇 |
2013年 | 376篇 |
2012年 | 296篇 |
2011年 | 358篇 |
2010年 | 261篇 |
2009年 | 264篇 |
2008年 | 225篇 |
2007年 | 347篇 |
2006年 | 349篇 |
2005年 | 301篇 |
2004年 | 265篇 |
2003年 | 247篇 |
2002年 | 215篇 |
2001年 | 209篇 |
2000年 | 197篇 |
1999年 | 167篇 |
1998年 | 121篇 |
1997年 | 95篇 |
1996年 | 122篇 |
1995年 | 92篇 |
1994年 | 85篇 |
1993年 | 67篇 |
1992年 | 57篇 |
1991年 | 35篇 |
1990年 | 35篇 |
1989年 | 37篇 |
1988年 | 14篇 |
1987年 | 9篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 7篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1975年 | 4篇 |
1974年 | 1篇 |
1959年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有6673条查询结果,搜索用时 15 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(36):16121-16131
Ammonia is considered as a promising hydrogen or energy carrier. Ammonia absorption or adsorption is an important aspect for both ammonia removal, storage and separation applications. To these ends, a wide range of solid and liquid sorbents have been investigated. Among these, the deep eutectic solvent (DES) is emerging as a promising class of ammonia absorbers. Herein, we report a novel type of DES, i.e., metal-containing DESs for ammonia absorption. Specifically, the NH3 absorption capacity is enhanced by ca. 18.1–36.9% when a small amount of metal chlorides, such as MgCl2, MnCl2 etc., are added into a DES composed of resorcinol (Res) and ethylene glycol (EG). To our knowledge, the MgCl2/Res/EG (0.1:1:2) DES outperforms most of the reported DESs. The excellent NH3 absorption performances of metal–containing DESs have been attributed to the synergy of Lewis acid–base and hydrogen bonding interactions. Additionally, good reversibility and high NH3/CO2 selectivity are achieved over the MgCl2/Res/EG (0.1:1:2) DES, which enables it to be a potential NH3 absorber for further investigations. 相似文献
2.
3.
《材料科学技术学报》2019,35(7):1309-1314
Degenerate pattern is a seemingly disordered morphology but it exhibits the inherently ordered crystal connected with tip-splitting and limited stability which makes it difficult to observe in the metallic system. Here we employ (100)[011] orientated planar-front seeds using directional solidification and reveal the fundamental origins of the degenerate pattern growth in an Al-4.5 wt% Cu alloy. We find that the spacing of the tip-splitting (λ) in the degenerate of the alloys followed a power law, λ∝V−0.5, and the frequency (f) of the splitting was related to the growth velocity (V) by ƒ∝V1.5. The dimensionless growth direction (θ/θ0) increased monotonously and approached 0.6 with faster velocity, attributed to its anisotropy in the interface kinetics. Once growth velocity exceeded a threshold, two types of pattern transitions from degenerate to regular dendrites were proposed. One of them exhibited a random and chaotic mode and the other underwent a rotation in growth direction. 相似文献
4.
《Intermetallics》2015
Raney-type Ni precursor alloys containing 75 at.% Al and doped with 0, 0.75, 1.5 and 3.0 at.% Ti have been produced by a gas atomization process. The resulting powders have been classified by size fraction with subsequent investigation by powder XRD, SEM and EDX analysis. The undoped powders contain, as expected, the phases Ni2Al3, NiAl3 and an Al-eutectic. The Ti-doped powders contain an additional phase with the TiAl3 DO22 crystal structure. However, quantitative analysis of the XRD results indicate a far greater fraction of the TiAl3 phase is present than could be accounted for by a simple mass balance on Ti. This appears to be a (TixNi1−x)Al3 phase in which higher cooling rates favour small x (low Ti-site occupancy by Ti atoms). SEM and EDX analysis reveal that virtually all the available Ti is contained within the TiAl3 phase, with negligible Ti dissolved in either the Ni2Al3 or NiAl3 phases. 相似文献
5.
Qun Ren Haijun Su Jun Zhang Haifang Liu Weidan Ma Guangrao Fan Di Zhao Min Guo Lin Liu Hengzhi Fu 《Ceramics International》2019,45(6):6632-6638
Directionally solidified microstructures of Al2O3-Er3Al5O12 eutectic and off-eutectic in situ composite ceramics were explored under abrupt-change pulling rate conditions. Corresponding temperature distributions and interface locations were studied. In eutectic composition, fluctuation of eutectic spacing occurred when the pulling rate increased abruptly. A gradually increase or abrupt increase in eutectic spacing was observed when the pulling rate decreased abruptly. In hypoeutectic and hypereutectic compositions, formation of the primary phases were suppressed when the pulling rate increased abruptly from 10?µm/s to 100?µm/s, while primary phases precipitated when the pulling rate decreased abruptly from 100?µm/s to 10?µm/s. The interface altitude decreased after the pulling rate increased abruptly, but increased after the pulling rate decreased abruptly. The liquid composition restriction (around the eutectic composition) at the eutectic interface plays an important role in the suppression of the primary dendrite and coupled eutectic oxides can be obtained in off-eutectic compositions even under higher solidification rate conditions. 相似文献
6.
《Intermetallics》2015
Drop-tube processing was used to rapidly solidify droplets of Ni64.7Fe10Si25.3 and Ni59.7Fe15Si25.3 alloys. In the larger droplets, and therefore at low cooling rates, only two phases, γ-Ni31Si12 and β1-Ni3Si were observed. Conversely, in the smaller droplets, and therefore at higher cooling rates, the metastable phase Ni25Si9 was also observed. The critical cooling rate for the formation of Ni25Si9 was estimated as 5 × 103 K s−1. SEM and TEM analysis reveals three typical microstructures: (I) a regular structure, comprising single-phase γ-Ni31Si12 and a eutectic structure between γ-Ni31Si12 and β1-Ni3Si; (II) a refined lamellar structure with a lamellar spacing <50 nm comprising γ-Ni31Si12 and β1-Ni3Si; (III) an anomalous structure with a matrix of Ni25Si9 and only a very small proportion of a second, and as yet unidentified, phase. These results indicate that there is an extended stability field for Ni25Si9 in the Ni-rich part of the Ni–Fe–Si ternary system in comparison to the Ni–Si binary system. With an increase of cooling rate, an increasing fraction of small droplets experience high undercoolings and, therefore, can be undercooled into the Ni25Si9 stability field forming droplets consisting of only the anomalous structure (III). The Fe atoms are found to occupy different substitutional sites in different phase, i.e. Fe substitutes for Ni in the γ phase and Si in the L12 (β1) phase respectively. 相似文献
7.
Ludmil Drenchev Jerzy Sobczak Rajiv Asthana Savko Malinov 《Journal of Computer-Aided Materials Design》2003,10(1):35-54
Ordered porosity metal materials belong to a relatively new class of porous materials named gasars. This paper presents a mathematical model of the complex physical phenomena in the production of gasars. Analyses for heat transfer, solidification kinetics and gas diffusion were coupled to describe the formation of unique gasar structure. Several criterial functions were introduced to provide significant quantitative information about the relationship between the operating technological parameters and the final structure. The computational outcomes of the numerical simulation were compared with the characteristics of real gasar ingots. The model was applied to determine the boundary conditions that would provide approximately constant physical conditions on the solidification front. The structure sensitiveness of gasars with respect to the different technological parameters is discussed. 相似文献
8.
Heat transfer of highly consistent shear-thinning fluids flowing in a horizontal cylindrical channel has been investigated numerically and experimentally when the outer channel wall is subjected to a constant convective heat exchange. The case considered being cooling, a possible ice deposit must be taken into account. The variation of the rheological properties with temperature must be considered as well. 相似文献
9.
PENGLiming MAOXiemin XUKuangdi DINGWenjiang 《稀有金属(英文版)》2002,21(1):62-66
In order to develop a new type of contact cable with high strength and high electrical conductivity, Cu-Cr alloy series were selected as materials and Cu-Cr alloy castings were produced by means of directional solidification continuous casting (DSCC) process. The results show that the fibrillar strengthening phase, 13-Cr, orderly arranges among the copper matrix phase along the wire direction; and a microstructure of in-situ composite forms, which retains the basic property of good conductivity of the copper matrix and meanwhile obtains the strengthening effect of [3-Cr phase. The production technology as well as the mechanical property, electrical property, and synthetic property of the in-situ composite contact cables was discussed. 相似文献
10.
Rotating-bending uniaxial fatigue tests and micro-fatigue crack initiation tests were carried out using a permanent mold cast
(PMC) and semi-solid die cast (SDC) with Al−7%Si−0.35%Mg composition in order to examine the relationship between solidification
structures and fatigue behaviors. The crack length was measured using a replication method. Fatigue strength was improved
in SDC, which was almost consistent with the predicted fatigue strength using the size of Si particle cluster. Resistance
to fatigue crack initiation and fatigue strength were improved in SDC owing to the finer Si cluster and to higher ultimate
tensile strength. Fatigue crack in PMC was preferentially initiated at pores. For SDC, the fatigue crack was initiated at
the Si particle/matrix interface, and then sucessively grew along eutectic cell boundaries. 相似文献