被动锁模复合环形腔掺饵光纤激光器的自启动分析

本文对被动锁模复合环形腔掺饵光纤激光器的自启动工作特性进行了分析，指出谐振腔内残余反射面的存在是阻碍激光器实现自启动锁模的主要原因。利用半导体激光器有源区的折射率随注入电流的变化而改变的特性，在谐振腔中获得了一个可移动腔镜，克服了腔内残余反射面的影响，实现了锁模的自启动。     

Shape design of cerium oxide nanoparticles for enhancement of enzyme mimetic activity in therapeutic applications

Cerium oxide nanoparticles (CONPs), widely used in catalytic applications owing to their robust redox reaction, are now being considered in therapeutic applications based on their enzyme mimetic properties such as catalase and super oxide dismutase (SOD) mimetic activities. In therapeutic applications, the emerging demand for CONPs with low cytotoxicity, high cost efficiency, and high enzyme mimetic capability necessitates the exploration of alternative synthesis and effective material design. This study presents a room temperature aqueous synthesis for low-cost production of shape-selective CONPs without potentially harmful organic substances, and additionally, investigates cell viability and catalase and SOD mimetic activities. This synthesis, at room temperature, produced CONPs with particular planes: {111}/{100} nanopolyhedra, {100} nano/submicron cubes, and {111}/{100} nanorods that grew in [110] longitudinal direction. Enzymatic activity assays indicated that nanopolyhedra with a high concentration of Ce⁴⁺ ions promoted catalase mimetic activity, while nanocubes and nanorods with high Ce³⁺ ion concentrations enhanced SOD mimetic activity. This is the first study indicating that shape and facet configuration design of CONPs, coupled with the retention of dominant, specific Ce valence states, potentiates enzyme mimetic activities. These findings may be utilized for CONP design aimed at enhancing enzyme mimetic activities in therapeutic applications.

Open image in new window

     

基于刻面分类模式的构件库检索方法

可复用软件构件的检索是构件库和软件复用领域研究的一个重要课题。基于刻面分类模式的检索方式拥有准确、高效的优势,因而得到了广泛应用。论文介绍了刻面分类模式的相关概念以及刻面树的创建方式,分析了基于刻面分类模式对软件构件库进行检索的规则,该规则将用户选择的刻面和术语通过合理的并和交运算组合生成数据库查询条件来完成检索。最后根据规则提出了相应算法以及刻面分类模式检索在实际构件库系统中的实现方法。     

TiO2 nanoparticles with superior hydrogen evolution and pollutant degradation performance

The human life faces serious energy shortage and environmental pollution problems, therefore developing a facile and environmental friendly strategy for synthesizing nanoparticles (NPs) with improved photocatalytic activity could pave the way for different applications. In the present study, one-pot/in-situ fluorine-free synthesis process has been examined toward the solvothermal production of anatase TiO₂ nanoparticles with exposed facet orientation. This is an aim to achieve the excellent photocatalytic/photoelectrocatalytic performance. Most importantly addressing the global energy shortage, the synthesized TiO₂ NPs represent superior performance in photoelectrocatalytic water splitting toward hydrogen production. The overpotential required to drive the hydrogen evolution reaction was −391, −346 and −283 mV vs. Ag/AgCl for P25, cubic and truncated octahedral NPs, respectively. Additionally, TiO₂ NPs with exposed facets represent excellent photocatalytic performance toward environmental purification. As synthesized nanoparticles was examined via photocatalytic degradation of Acid Blue 5 and photocatalytic removal of NO gas. The enhanced photocatalytic and photoelectrocatalytic performance are associated to the effect of exposed facet orientation of final nanoparticles.     

五轴数控渐进成形中挤压工具姿态的确定

在基于STL模型的五轴数控渐进成形中,为了避免三角面片边界处挤压工具的姿态发生突变现象,提出一种挤压工具姿态确定方法。首先,根据挤压工具头中心点与三角面片的位置关系,将工具头中心点分为位于三角面片顶点、三角面片边和三角面片内部3种类型;然后,对不同类型的工具头中心点,分别采用不同的距离加权算法,计算工具头中心点的法向量;最后,根据工具头中心点的法向量和挤压工具轴相对于工具头中心点法向量的引导角和倾斜角,确定挤压工具姿态。采用VC++和OPENGL完成算法的系统实现。算法应用实例表明,所确定的挤压工具姿态变化平缓,在三角面片的边界处,没有发生挤压工具姿态突变现象,软件运行稳定可靠。     

端面反射率对单端反射半导体光放大器的影响

本文考虑了光子密度、增益谱色散、放大自发辐射噪声(ASE)、端面反射率和载流子浓度对折射率的影响,并采用细化分段法及四阶龙格-库塔法求解速率方程及光场传输方程,分析了不同端面反射率时单端反射半导体光放大器(RSOA)的动态特性。结果表明端面反射率的适当增加,可以使增益得到提高,增益恢复时间减少, ASE输出功率增加,消光比下降。理论分析为优化RSOA的动态特性具有一定的指导意义。     

外腔半导体激光器激射波长温度稳定性的研究

在考虑了光纤光栅(FG)的相位分布之后,根据光纤光栅外腔半导体激光器(FGESL)所满足的阈值条件,从理论上研究了前端面反射率对光纤光栅长外腔半导体激光器(LECFGSL)激射波长温度稳定性的影响.数值模拟的结果表明:随着温度的变化,LECFGSL的激射波长围绕光栅布拉格反射波长上下波动,激光器前端面反射率对激射波长波动幅度有较大的影响,当前端面反射率＜10-4时,激射波长与光栅布拉格反射波长基本一致,其温度稳定性较好.     

Facet engineered TiO2 hollow sphere for the visible-light-mediated degradation of antibiotics via ligand-to-metal charge transfer

Efficient removal of tetracycline (TC) under visible-light irradiation over TiO₂-based photocatalysts remains a challenge based on the fact that the reported photocatalytic systems still suffer from weak visible-light absorption and/or inefficient charge separation. Herein, we constructed {101} and {001} facets co-exposed TiO₂ hollow sphere (001-HT) via a gentle NaF treatment, in which the hollow mesoporous feature can trap incident light for a long time to improve photons efficiently. Meanwhile, the as-formed facet heterojunction significantly facilitates the charge separation. As a result, the 001-HT exhibits a high removal rate (~90.1%) of TC under visible-light irradiation, beyond the values of many reported TiO₂-based photocatalysts. Most importantly, we further expound the ligand-to-metal charge transfer mechanism towards TiO₂-assisted degradation of TC under visible-light irradiation, which effectively clarifies the confusion about the origin of pure TiO₂ visible-light activity towards TC degradation because both TiO₂ and TC do not exhibit any visible-light catalytic activity. Therefore, this work provides a new insight in revealing the mechanism of visible-light-mediated TC degradation over pure TiO₂ photocatalyst.     

Ag@AgCI修饰的具有高活性（001）晶面的锐钛矿相TiO2的制备和光催化性能研究

本文采用水热法合成具有高活性（001）晶面的锐铁矿相TiO2微球,利用沉积法将AgCl分散到TiO2微球表面,再通过光化学反应将部分Ag还原,获得Ag@AgCl等离了体负载的TiO2光催化剂,借助SEM、TEM、UV—ViSDRS等于段对催化剂的结构进行表征,并以酸性红作为模型污染物对样品的光催化性能进行评价。结果表明：经Ag@AgCl修饰后,样品对可见光的响应增强,光生载流了的分离得到有效促进,可见光催化活性有大幅度的提高,对酸性红的降解效率是修饰前的3倍。