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Abstract Southern pine and aspen flakes were acetylated with acetic anhydride alone without cosolvent or catalyst by a simple dip procedure. The new procedure greatly shortens reaction time and simplifies chemical recovery. Acetylation weight gains of 15% to 20% can be achieved in 1 to 3 hours with southern pine flakes and in 2 to 4 hours with aspen flakes. Flakeboards made from acetylated southern pine or aspen flakes absorbed much less water, both in water-soaking tests and when subjected to humid air, and swelled at a lower rate and to a lower extent than did control boards. Hygroscopicity of the resulting flakeboards decreased with increased level of wood acetylation. The equilibrium moisture content (EMC) for flakeboards made from acetylated flakes was lower at each relative humidity tested than that of control boards. 相似文献
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刨花施胶效果的定量表征与分析 总被引:1,自引:0,他引:1
在回顾国内外刨花施胶效果检测技术研究状况的基础上,建立了全新的量化刨花施胶效果表征参数体系,并采用胶黏剂扫描(GlueScan)系统对刨花施胶效果进行量化分析.结果表明,该法可高效、准确地测定刨花表面的胶黏剂分布状况,通过对各参数的分析,为刨花施胶工艺改进的效果提供依据. 相似文献
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落叶松生物油/酚醛树脂胶粘剂制备刨花板的工艺研究 总被引:1,自引:0,他引:1
以生物油替代45%苯酚(质量分数)制备生物油/酚醛树脂(PF)胶粘剂,并以此作为制备刨花板用胶粘剂。以热压温度、热压时间、刨花含水率以及施胶量为试验因素,静曲强度、内结合强度和甲醛释放量为评价指标,采用正交试验法优选出制备刨花板的最佳工艺参数。结果表明:制备刨花板的最佳工艺参数为热压温度180℃、热压时间8min、含水率12%和施胶量10%;在此工艺条件下制备的刨花板,其强度满足GB/T4897-2003标准要求、甲醛释放量达到GB/T18580-2001标准中E0级要求。 相似文献
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Flakeboards made from control flakes bonded with an isocyanate resin outperformed phenolic-bonded control boards in thickness swelling tests in both liquid water and water vapour. Less irreversible swelling occurred in isocyanate-bonded control boards as compared to phenolic-bonded control boards. Flakeboards made from acetylated flakes, using either a phenolic or isocyanate resin, swelled in thickness much slower and to a lesser extent in liquid water and water vapour tests compared to control boards. Isocyanate-bonded control and acetylated aspen flakeboards had higher internal bond and modulus of rupture values and approximately equal modulus of elasticity properties when compared to a similar series of boards bonded with a phenolic resin, as reported in Part 1 of this series. 相似文献
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根据刨花板施胶施蜡工段的生产工艺,对施胶施蜡控制原理进行了分析,介绍了微机控制系统的软、硬件设计方法,为国产刨花板生产线的自动化改造提供了有益的经验. 相似文献
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以三聚氰胺、甲醛和乙二醛为原料,在碱性条件下成功合成了均一透明的三聚氰胺-乙二醛-甲醛共缩聚树脂(MGF),并将MGF胶粘剂用于刨花板的制备。以红外光谱(FT-IR)法、差示扫描量热(DSC)法和核磁共振(13C-NMR)法等为测试手段对MGF的结构和性能进行了表征和测定,并采用正交试验法优选出合成MGF的最佳工艺条件。结果表明:当n(甲醛)∶n(三聚氰胺)∶n(乙二醛)=2.2∶1∶0.4、反应温度为75℃和pH=9.0时,MGF的综合性能相对最好,并且其室温储存期超过30 d。 相似文献
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