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排序方式: 共有4329条查询结果,搜索用时 15 毫秒
1.
《International Journal of Hydrogen Energy》2022,47(14):8716-8728
In this study, lignin was gasified in supercritical water with catalysis of CuO–ZnO synthesized by deposition precipitation, co-precipitation and sol-gel methods. Sol-gel synthesized CuO–ZnO showed the highest catalytic performance, and the gasification efficiency was increased by 37.92% with it. The XRD, SEM-EDS and N2 adsorption/desorption analysis showed that the priority of the sol-gel catalyst was the smallest crystallite size, largest specific surface area and high dispersion. For sol-gel synthesized CuO–ZnO, the increase of CuO/ZnO ratio improved the gasification efficiency but reduced H2 selectivity. And the catalytic activity was reduced with the calcination temperature above 600 °C due to enlarged crystallites and reduced pores. During sol-gel preparation, both the addition of ethanol and PEG in the solvent reduced the agglomeration and improved the catalytic activity. With CuO–ZnO prepared with 1 g PEG + water as the solvent, the highest H2 yield of 6.86 mol/kg was obtained, which was over 1.5 times of that without catalyst. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(74):31833-31842
Biomass gasification technology under microwave irradiation is a new and novel method, and the energy conversion performances during the process play a guiding role in improving the energy conversion efficiencies and developing the gasification simulation models. In order to improve the energy utilization efficiency of microwave biomass gasification system, this study investigated and presented the energy conversion performances during biomass gasification process under microwave irradiation, and these were materialized through detailing (a) the energy conversion performance in the microwave heating stage, and (b) the energy conversion performance in the microwave assisted biomass gasification stage. Different forms of energies in the biomass microwave gasification process were calculated by the method given in this study based on the experimental data. The results showed that the useful energy (energy in silicon carbide (SiC), 18.73 kJ) accounted for 31.22% of the total energy input (electrical energy, 60.00 kJ) in the heating stage, and the useful energy (energy in the products, 758.55 kJ) accounted for 63.41% of the total energy input (electrical and biomass energy, 1196.28 kJ) in the gasification stage. During the whole biomass gasification process under microwave irradiation, the useful energy output (energy in the products, 758.55 kJ) accounted for 60.38% of the total energy input (electrical and biomass energy, 1256.28 kJ), and the energy in the gas (523.40 kJ) product played a dominate role in product energy (758.55 kJ). The energy loss mainly included the heat loss in the gas flow (89.20 kJ), magnetron loss (191.80 kJ) and microwave dissipation loss (198.00 kJ), which accounted for 7.10%, 15.27% and 15.76% of the total energy, respectively. The contents detailed in this study not only presented the energy conversion performances during microwave assisted gasification process but also supplied important data for developing gasification simulation models. 相似文献
3.
《International Journal of Hydrogen Energy》2020,45(7):4793-4803
As an industrial pollutant, tar derived from biomass gasification is used as the precursor for fabricating a novel carbon-metal hydroxides composite electrode. A slurry (the mixture of tar, KOH and melamine) is daubed uniformly onto the nickel foam, which is directly carbonized to form NPC@LDH electrode material. This electrode is further coated with NiCo-LDH nanosheets using an electrodeposition method to form NF@NPC@LDH. The newly made NF@NPC@LDH electrode exhibits a high specific capacity of 9.6 F cm−2 at a current density of 2 mA cm−2 and good rate performance (55.3% retention). Furthermore, a hybrid NF@NPC@LDH//NF@PC all-solid-state supercapacitor is fabricated, and the device exhibits high energy density of 1.28 mWh cm−3 at a power density of 8.04 mW cm−3, low resistance and good cycling stability. 相似文献
4.
壳牌煤气化工艺在荷兰德姆科列克IGCC工厂的应用 总被引:3,自引:0,他引:3
介绍采用壳牌煤气化工艺的荷兰德姆科列克250MW整体煤气化烧气--蒸汽联合循环发电厂的建厂过程及运行经验。阐述了IGCC能量平衡原理、SCGP系统流程和运行操作指标,对壳牌煤气化装置的优良性能和发展前景进行了总结和展望。 相似文献
5.
The reaction of lignite in a slagging gasifier produces reactants which in turn form 5,5-dimethylhydantoin (DMH) as a major constituent in the condensate water. Variations in plant operating conditions made it impossible to accurately study the kinetics of formation of DMH in the actual gasifier water, and thus a model system was chosen. The reaction of acetone cyanohydrin in the presence of excess ammonium carbonate at concentrations approaching those obtained in the condensate water were studied at 50,70, and 90 °C. Secondorder kinetics were obeyed, and the pseudo second-order rate constants at the respective temperatures were 1.86, 3.6, and 4.62 dm3 mol? 1 h? 1. Independent variation of the concentration of either acetone, cyanide, ammonia or carbonate gave results consistent with the interpretation that the formation of DMH is first order in all reactants: rate of formation of DMH = k[acetone][HCN][NH3][CO2]. The pseudo second-order rate constant is a complex rate constant including several rapid equilibria. A mechanism consistent with the kinetic data is presented. 相似文献
6.
对大化肥气化装置的安全系统的作用、硬件组成、信号的处理以及顺序控制和安全联锁进行了介绍,并详细描述了气化炉的开、停车及吹扫顺序的过程以及安全联锁的功能。 相似文献
7.
城市生活垃圾能源利用探讨 总被引:7,自引:0,他引:7
报道了城市有机废弃物转化为能源的几种途径。在管式反应器内甘蔗渣裂解气化制煤气以及在高压釜内湿式裂解气化制煤气液体产品,可得到中值煤气。也研究了甘蔗渣二步法糖化和糖发酵,当PH为3.6,酵母浓度为1.33%,乙醇产率可达理论值的64.86%。 相似文献
8.
9.
Ir.H.E.M. Stassen 《Renewable Energy》1994,5(5-8)
Within the European Community, the interest in energy generation from biomass and waste is increasing. A brief overview is given of several thermal conversion technologies, of biomass production and waste availability in the Netherlands. Based on this, the possibilities for energy generation from biomass and waste in the Netherlands are evaluated. 相似文献
10.
Spruce wood residues were treated in a vacuum pyrolysis Process Development Unit with a throughput capacity of 28 kg/h. Two aqueous phase condensate samples with COD concentration varying between 190 and 255 g/L were produced and sequentially extracted with dichloromethane and ethylacetate solvents. The soluble organic matter was composed of acidic, phenolic, alcoholic and ketonic compounds. The insoluble fraction was sequentially distilled at 100 and 110°C under atmospheric pressure. Mainly water was recovered in the first distillate, while the second distillate contained 30.4% formic and acetic acids, 69.4% water and 0.2% residual organic compounds. The distillation residue was rich in oxygen and was essentially insoluble in any organic solvent. The two aqueous phase pyroligneous samples were treated in Bat-telle's Thermochemical Environmental Energy System (TEESr?), a registered service mark of Onsite*Ofsite, Inc. of Duarte, California, U.S.A. The results of the tests showed that similar results were obtained with either feedstock. In batch tests a COD reduction of 99% was achieved. The product gas composition was typically about 49% methane, 5% hydrogen, 1 % ethane and 45% carbon dioxide. Tests in a continuous stirred-tank reactor produced reproducible data which can be used for process scale-up. Catalyst lifetime was identified as needing further improvement. The preliminary results demonstrated the technical feasibility of the catalytic gasification process as a useful step in the recovery of energy from the secondary condensate stream and the cleanup of the by-product water from vacuum pyrolysis of wood. 相似文献