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1.
澳洲锂辉石在陶瓷釉料中的应用 总被引:2,自引:2,他引:2
本文介绍了澳洲锂辉石的特性及其在陶瓷釉料中的作用、机理及使用方法,并对使用澳洲锂辉石所产生的经济效益进行了分析。 相似文献
2.
通过正交试验方法优化釉料组成和烧成工艺,制备了R2O-RO-B2O3-SiO2-Al2O3-P2O5-CaF2多元系光亮无锆的分相-析晶乳浊釉。采用X射线衍射仪、透射电子显微镜/X射线能谱、场发射扫描电子显微镜等研究了釉的显微结构及分相与析晶的形成机理。结果表明:析晶与分相结构并存,分相促进析晶;尺寸接近可见光波长的孤立液滴和所析出的钙钠长石晶体是釉面产生乳浊的根本原因。研究了不同烧成制度对分相-析晶乳浊釉显微结构的影响,发现缓冷釉样的分相液滴尺寸明显大于急冷釉样,急冷釉样中的第二相形貌表里存在明显差异,内部呈球形液滴状,表面则为蠕虫状。 相似文献
3.
Thomas G. Hobbs 《Journal of research of the National Institute of Standards and Technology》2000,105(2):275-283
A variety of commonly available household and industrial ceramic items and some specialty glass materials were assayed by alpha pulse counting and ion chamber voltage measurements for radioactivity concentrations. Identification of radionuclides in some of the items was performed by gamma spectroscopy. The samples included tableware, construction tiles and decorative tiles, figurines, and other products with a clay based composition. The concentrations of radioactivity ranged from near background to about four orders of magnitude higher. Almost every nuclide identification test demonstrated some radioactivity content from one or more of the naturally occurring radionuclide series of thorium or uranium. The glazes seemed to contribute most of the activity, although a sample of unglazed pottery greenware showed some activity. Samples of glazing paints and samples of deliberately doped glass from the World War II era were included in the test, as was a section of foam filled poster board. A glass disc with known 232Th radioactivity concentration was cast for use as a calibration source. The results from the two assay methods are compared, and a projection of sensitivity from larger electret ion chamber devices is presented. 相似文献
4.
Miroslav Trojan 《Journal of the American Ceramic Society》1990,73(10):2892-2895
Zirconium silicate (zircon) pigments in new gray hues have been prepared from mineral zircon as a low-cost raw material. In the first step this material was deocmposed with a waste mixture of NaOH-KOH. In the second step the pigments were synthesized with addition of manganese, especially manganese(II) carbonate, as the chromophore. The optimum conditions for the syntheses of pigments have been estimated and the properties of products (hues, applicability to ceramic glazes) have been evaluated. 相似文献
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6.
Agustin Escardino 《Journal of the American Ceramic Society》2001,84(1):23-28
Theoretical equations have been developed for crystal growth rate in layers of small frit (glass) particles during firing. Throughout the process, the crystalline and the glassy phases have different compositions; therefore, the system can be considered a pseudo-two-component system consisting of a crystallizable component (structural unit) and a noncrystallizable mixture of several components. The concentration of the crystallizable component decreases in the residual glassy phase during the crystal growth process, on integrating at the surfaces of crystals having the same composition. Throughout the crystal growth process, a concentration gradient of the crystallizable component is therefore produced in the glassy phase, which results in mass transport by diffusion of this component from the bulk residual glassy phase to the surfaces of the crystals. Equations have been derived assuming that the diffusion step of the crystallizable component through the residual glassy phase is the overall crystal growth process rate-controlling step. 相似文献
7.
Effect of ZnO/MgO ratio on the crystallization and optical properties of spinel opaque glazes 下载免费PDF全文
Jingpei Cai Ming Lu Kang Guan Weixiong Li Fan He Peng Chen Cheng Peng Pinggen Rao Jianqing Wu 《Journal of the American Ceramic Society》2018,101(4):1754-1764
The effect of the ZnO/MgO ratio on the crystallization and optical properties of glass‐ceramic glazes from the SiO2–Al2O3–ZnO–MgO–CaO–K2O–Na2O–B2O3 system was studied. The glazes with different ZnO/MgO ratios were characterized by differential scanning calorimetry, X‐ray powder diffraction, Raman spectroscopy, scanning electron microscopy, energy dispersive spectroscopy analysis and a spectrophotometer. The results reveal that the A glaze without ZnO content contains forsterite and sapphirine. The B and C glazes with intermediate ZnO/MgO ratio contain enstatite and spinel solid solution. The D to F glazes with higher ZnO/MgO ratio crystallize spinel solid solution as the only crystalline phase. The amount of spinel solid solution, lightness values (L*), gloss values and the reflectance of the studied glazes increase with the ZnO/MgO ratio. 相似文献
8.
The production of a lead glaze with galena: Thermal transformations in the PbS–SiO2 system 下载免费PDF全文
Roberta Di Febo Judit Molera Trinitat Pradell Joan C. Melgarejo Josep Madrenas Oriol Vallcorba 《Journal of the American Ceramic Society》2018,101(5):2119-2129
Galena, also known as PbS, was widely used in the production of lead glazes from the beginning of the 18th century to the second half of the 20th century. Although the PbO‐SiO2 system has been studied for years, the PbS–SiO2 phase diagram, involved in the formation of a glaze with galena, has not yet been investigated. Temperature transformations for the system 75 wt% PbS‐25 wt% SiO2 are investigated in a high‐temperature resolved X‐ray diffraction experiment with synchrotron radiation and compared to those of the equivalent system 70 wt% PbO‐30 wt% SiO2. Lanarkite, PbO·PbSO4, is the phase predominantly formed as soon as galena decomposes during the heating. The results show that the system melts at a temperature higher than the PbO–SiO2 system, but far lower than those expected for the PbO–PbSO4–PbS system. A historical misfired lead glaze produced with galena is also studied. The presence of galena, lanarkite, and mattheddleite, Pb10(SiO4)3.5(SO4)2Cl2, is determined and discussed in terms of the composition of the galena mineral used and the firing conditions in light of the high‐temperature transformations previously obtained. 相似文献
9.
《Ceramics International》2017,43(2):1703-1709
The aim of this study was to develop new compositions of white glazes without the addition of ZrSiO4designed for sanitary products obtained in a 12-h firing cycles at a maximum temperature of 1230 °C.Alternative glazes with a good opacity and a high degree of whiteness were obtained, composed primarily of raw materials available on the domestic market in Poland. The opaque effect was achieved due to crystallisation of anorthite, which was identified as a major crystalline phase in the system. The glazes were characterised by a high whiteness value L*, greater than 90 in the CIELAB colour space, and a gloss, measured with a 60° light incident angle on the glaze surface, above 50%.The microstructure and structure of the glazes were measured with the use of a Scanning Electron Microscope (SEM) and X-ray Diffraction (XRD). The colour and gloss of glazes were measured with the use of a spectrophotometer and a gloss metre at a 60° angle of incidence. The topography of glazes surfaces, as well as the roughness level (Ra), were measured with the use of a confocal microscope. 相似文献
10.
我国色釉料产业现状及发展趋势分析 总被引:1,自引:0,他引:1
从我国色釉料行业的现状、发展趋势、仿古砖色料、全抛釉技术、喷墨打印技术、原料标准化以及加强基础研究和技术创新等角度进行了分析评述。 相似文献