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1.
《International Journal of Hydrogen Energy》2022,47(63):27023-27031
Hexagonal boron nitride (h-BN) as a layered inorganic nonmetallic material has been widely used. Hydrogen peroxide (H2O2) modification can trigger exfoliation and afford abundant B–OH active sites at edge of h-BN, which can enhance methane activation ability. Introducing tungsten oxide (WO3) to h-BN produces a similar effect, because doping WO3 into h-BN resulted in electron transfer to N, inducing fracture of B–N bond, resulting in N vacancy (triboron center), exposing more B sites and promoting the generation of B–OH. Significantly, the introduction of WO3 on the modified h-BN dramatically increased the concentration of B–OH compared with the unmodified h-BN, because H2O2 modification weakened B–N bond. By means of XRD, TEM, XPS,EPR, FT-IR, it is proved that the high concentration of B–OH active sites contributed to activating C–H bond, thus methane conversion and CO and H2 selectivity were significantly improved. 相似文献
2.
Baofu Qiu Xiaoming Duan Zhuo Zhang Delong Cai Ning Liao Peigang He Dechang Jia Yu Zhou 《Ceramics International》2021,47(1):73-79
The effects of La2O3–Al2O3–SiO2 addition on the thermal conductivity, coefficient of thermal expansion (CTE), Young's modulus and cyclic thermal shock resistance of hot-pressed h-BN composite ceramics were investigated. The samples were heated to 1000 °C and then quenched to room temperature with 1–50 cycles, and the residual flexural strength was used to evaluate cyclic thermal shock resistance. h-BN composite ceramics containing 10 vol% La2O3–Al2O3 and 20 vol% SiO2 addition exhibited the highest flexural strength, thermal conductivity and relatively low CTE, which were beneficial to the excellent thermal shock resistance. In addition, the viscous amorphous phase of ternary La2O3–Al2O3–SiO2 system could accommodate and relax thermal stress contributing to the high thermal shock resistance. Therefore, the residual flexural strength still maintained the value of 234.3 MPa (86.9% of initial strength) after 50 cycles of thermal shock. 相似文献
3.
报道了在Fe70Ni30合金触媒和石墨系体中,掺杂六角立方氮化硼(h-BN)和硼(B)生长金刚石单晶的过程。研究发现,h-BN和B掺杂对于金刚石生长条件及形貌等具有较大的影响,其中h-BN掺杂生长金刚石的最低生长压力达到了6.2 GPa,同时晶体呈绿色条状。说明h-BN和B在金刚石晶体生长以及取代碳原子进入晶格时起到了不同的作用。通过X射线衍射及光电子能谱等表征手段,分析了硼氮对金刚石晶体结构的影响,以及硼氮在金刚石中的化学环境及成键方式。在此基础上阐述了硼氮掺杂的形成机制。 相似文献
4.
Boron and nitrogen-incorporated graphene thin films were grown on polycrystalline Ni substrates by thermal chemical vapor deposition using separate boron- and nitrogen-containing feedstocks. Boron and nitrogen atoms were incorporated in the film in almost equal amounts and the total content reached ∼28%. The film predominantly consisted of separate graphene and boron nitride domains. Carrier concentration in the graphene domains was estimated to be about 1 × 10−3 e/atom (3.8 × 1012 cm−2) from G band shift in Raman spectra. 相似文献
5.
为解决微型化电子电器设备内部的散热问题,本研究设计、制备了具有不同孔结构的六方氮化硼(h-BN)/TEMPO氧化纳米纤维素(TOCNF)气凝胶,后复合TOCNF,制备了h-BN/TOCNF复合膜。结果表明,当h-BN与TOCNF固含量比为3∶1时,在气凝胶内部,h-BN可以沿着TOCNF骨架形成三维网络状导热通道,此时TOCNF对h-BN间产生的热阻最小,且能够对h-BN起到良好的分散作用,导热通道的构建效率最高,制备的复合膜导热系数高达1.355 W/(m·K),相比于纯TOCNF膜提高了228%;体积电阻率为4.53×1014 Ω·cm,具有良好的绝缘性能。此外,通过热重(TG)分析发现,h-BN/TOCNF复合膜的初始分解温度约为210℃,具有良好的热稳定性;且h-BN/TOCNF复合膜具有优异的力学性能,其中h-BN和TOCNF固含量比为1∶1时,复合膜的强度最好,断裂伸长率约为13%,拉伸强度为24.8 MPa,随着h-BN含量的增加,复合膜的断裂伸长率变低,拉伸强度变化不大。 相似文献
6.
《Journal of the European Ceramic Society》2020,40(1):19-27
Carbon fiber reinforced lithium aluminosilicate glass-ceramic composites have been extensively studied and widely used in industry applications, because of its good mechanical properties and low thermal expansion coefficient. However, further investigation is also need to improve its oxidation resistance and mechanical performance to meet higher requirements. In this work, Cf/LAS glass-ceramic composites were fabricated by a slurry impregnation and hot-pressing method with different amounts of h-BN. Results indicate that composites with 2 wt.% h-BN addition exhibit excellent flexural strength and fracture toughness, reaching 910 ± 22 MPa and 21 ± 1 MPa·m1/2, respectively, and that after oxidation at 600, 800 and 1000 °C for 1 h, their strength residual ratio can reach 47%, 35% and 32%, respectively. TEM analyses suggest the improvement of oxidation resistance and mechanical properties should be attributed to the unique interface of composites caused by h-BN addition. 相似文献
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8.
J. M. Liu X. L. Liu X. Q. Xu J. Wang C. M. Li H. Y. Wei S. Y. Yang Q. S. Zhu Y. M. Fan X. W. Zhang Z. G. Wang 《Nanoscale research letters》2010,5(8):1340-1343
X-ray photoelectron spectroscopy has been used to measure the valence band offset (VBO) of the w-InN/h-BN heterojunction. We find that it is a type-II heterojunction with the VBO being −0.30 ± 0.09 eV and the corresponding conduction band offset (CBO) being 4.99 ± 0.09 eV. The accurate determination of VBO and CBO is important for designing the w-InN/h-BN-based electronic devices. 相似文献
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10.
Ni-Cr/h-BN self-lubricating composities were prepared by powder metallurgy (P/M) method. The effects of hexagonal boron nitride
(h-BN) content on the mechanical and tribological properties of the Ni-Cr/h-BN composites were investigated. The corresponding
frictional models were established to analyze the formation of the lubricant h-BN films on the surfaces of the Ni-Cr/h-BN
composites. The results show that, when the content of h-BN increases from 5% to 15% (mass fraction), the bending strength
of the Ni-Cr/h-BN composite decreases from 96.670 MPa to 17.319 MPa, and the hardness (HB) decreases from 33 to 14. The friction
coefficient of the Ni-Cr/h-BN composite decreases firstly from 0.385 to 0.216, and then increases to 0.284, while the wear
rate decreases firstly from 4.14×10−9 kg/(N·m) to 1.35×10−9 kg/(N·m), then increases to 2.36×10−9 kg/(N·m). The best comprehensive mechanical and tribological properties can be obtained between 10% and 12% h-BN addition. 相似文献