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1.
High-purity mullite ceramics, promising engineering ceramics for high-temperature applications, were fabricated using transient liquid phase sintering to improve their high-temperature mechanical properties. Small amounts of ultrafine alumina or silica powders were uniformly mixed with the mullite precursor depending on the silica-alumina ratio of the resulting ceramics to allow for the formation of a transient liquid phase during sintering, thus, enhancing densification at the early stage of sintering and mullite formation by the reaction between additional alumina and the residual glassy phase (mullitization) at the final stage of sintering. The addition of alumina powder to the silica-rich mullite precursor resulted in a reaction between the glassy silica and alumina phases during sintering, thereby forming a mullite phase without inhibiting densification. The addition of fine silica powder to the mullite single-phase precursor led to densification with an abnormal grain growth of mullite, whereas some of the added silica remained as a glassy phase after sintering. The resulting mullite ceramics prepared using different powder compositions showed different sintering behaviors, depending on the amount of alumina added. Upon selecting an optimum process and the amount of alumina to be added, the pure mullite ceramics obtained via transient liquid phase sintering exhibited high density (approximately 99%) and excellent high-temperature flexural strength (approximately 320 MPa) at 1500 °C in air. These results clearly demonstrate that pure mullite ceramics fabricated via transient liquid phase sintering with compositions close to those of stoichiometric mullite could be a promising process for the fabrication of high-temperature structural ceramics used in an ambient atmosphere. The transient liquid phase sintering process proposed in this study could be a powerful processing tool that allows for the preparation of superior high-temperature structural ceramics used in the ambient processing atmosphere. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(12):7902-7914
In this work, assembly pressure and flow channel size on proton exchange membrane fuel cell performance are optimized by means of a multi-model. Based on stress-strain data of the SGL-22BB GDL obtained from its initial compression experiments, Young's modulus with different ranges of assembly pressure fits well through modeling. A mechanical model is established to analyze influences of assembly pressure on various gas diffusion layer parameters. Moreover, a CFD calculation model with different assembly pressures, channel width, and channel depth are established to calculate PEMFC performances. Furthermore, a BP neural network model is utilized to explore optimal combination of assembly pressure, channel width and channel depth. Finally, the CFD model is used to validate effect of size optimization on PEMFC performance. Results indicate that gap change of GDL below bipolar ribs is more remarkable than that below channels under action of the assembly pressure, making liquid water easily transported under high porosity, which is conducive to liquid water to the channels, reduces the accumulation of liquid water under the ribs, and enhances water removal in the PEMFC. Affected by the assembly force, change of GDL porosity affects its diffusion rate, permeability and other parameters, which is not conducive to mass transfer in GDL. Optimizing the depth and different dimensions through width of the flow field can effectively compensate for this effect. Therefore, the PEMFC performance can be enhanced through the comprehensive optimization of the assembly force, flow channel width and flow channel depth. The optimal parameter is obtained when assembly pressure, channel width and channel depth are set as 0.6 MPa, 0.8 mm, and 0.8 mm, respectively. The parameter optimization enhances the mass transfer, impedance, and electrochemical characteristics of PEMFC. Besides, it effectively enhances the quality transfer efficiency inside GDL, prevents flooding, and reduces concentration loss and ohmic loss. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(8):5609-5626
The demand for clean energy use has been increasing worldwide, and hydrogen has attracted attention as an alternative energy source. The efficient transport of hydrogen must be established such that hydrogen may be used as an energy source. In this study, we considered the influences of various parameters in the transportation of liquefied hydrogen using type C tanks in shipping vessels. The sloshing and thermal flows were considered in the transportation of liquefied hydrogen, which exists as a cryogenic liquid at ?253 °C. In this study, the sloshing flow was analyzed using a numerical approach. A multiphase sloshing simulation was performed using the volume of fluid method for the observation and analysis of the internal flow. First, a sloshing experiment according to the gas-liquid density ratio performed by other researchers was utilized to verify the simulation technique and investigate the characteristics of liquefied hydrogen. Based on the results of this experiment, a sloshing simulation was then performed for a type C cargo tank for liquefied hydrogen carriers under three different filling level conditions. The sloshing impact pressure inside of the tank was measured via simulation and subjected to statistical analysis. In addition, the influence of sloshing flow on the appendages installed inside of the type C tank (stiffened ring and swash bulkhead) was quantitatively evaluated. In particular, the influence of the sloshing flow inside of the type C tank on the appendages can be utilized as an important indicator at the design stage. Furthermore, if such sloshing impact forces are repeatedly experienced over an extended period of time under cryogenic conditions, the behavior of the tank and appendages must be analyzed in terms of fatigue and brittle failure to ensure the safety of the transportation operation. 相似文献
4.
5.
Sinan Zhang Yadonga Zhao Xueshuang Yao Zhenhong Zheng Chuyao Zheng Zhuo Jiang 《International Journal of Food Science & Technology》2022,57(7):4245-4253
Ripe carambolas are hard to store and transport, while freeze-dried ones are easy to store. However, its long production time leads to higher costs. This study shows that high hydrostatic pressure (HHP) treatment could shorten the freeze-drying time of carambola slices. After HHP treatment (25–250 MPa), the drying time of the fresh sample can be shortened by 33.3–44.4% and the distribution of water and pigment in tissues is much uniform. With the increment of the pressure, 2,2-diphenyl-1-picrylhydrazyl (DPPH) and hydroxyl radical scavenging rate are increased. At 250 MPa, the total phenolic content (TPC) increased from 11.34 to 13.36 mg GAE g−1, and the total flavonoid content (TFC) of the control sample was increased from 10.77 to 12.73 mg RE g−1. Compared with the untreated sample, HHP treatment can enhance the flavour and shorten the freeze-drying time. This work guides the application of HHP technology for drying food processing. 相似文献
6.
Jing-jie Xie Xiao-Li Zou Yan-ping Li Zhuang-Li Kang Han-jun Ma 《International Journal of Food Science & Technology》2022,57(4):2459-2466
The effects of high-pressure-modified soy 11S globulin (0.1, 200, and 400 MPa) on the gel properties, water-holding capacity, and water mobility of pork batter were investigated. The high-pressure-modified soy 11S globulin significantly increased (P < 0.05) the emulsion stability, cooking yield, hardness, springiness, chewiness, resilience, cohesiveness, the a* and b* values, and the G′ and G′′ values of pork batter at 80 °C, compared with those of 0.1 MPa-modified globulin. In contrast, the centrifugal loss and initial relaxation time of T2b, T21, and T22 significantly decreased (P < 0.05). Meanwhile, the microstructure was denser, and the voids were smaller and more uniform compared with those of 0.1 MPa-modified globulin. In addition, the sample with 11S globulin modified at 400 MPa had the best water-holding capacity, gel structure, and gel properties among the samples. Overall, the use of high-pressure-modified soy 11S globulin improved the gel properties and water-holding capacity of pork batter, especially under 400 MPa. 相似文献
7.
为解决电镀砂轮磨削加工中容屑空间不足的问题,采用点胶微粘接的方法制备了磨料有序排布的电镀砂轮,分析了磨料粘接效果和镀层力学性能。通过SEM分析了磨料/镀层/导电胶的结合界面,并进行了干磨削试验。研究结果表明,直径约为磨料粒径40%的胶点可粘接住磨料,单个胶点上粘接多颗磨料的占比小于6%;双脉冲电镀工艺制备的镀层显微硬度大于500HV,表层残余应力小于100MPa,磨料/镀层/导电胶之间的界面贴合紧密,无明显缺陷;砂轮在磨削时没有出现磨料脱落现象。 相似文献
8.
《International Journal of Hydrogen Energy》2022,47(54):23006-23018
Hook and claw pumps are used for recirculation of excess hydrogen in fuel cells. Optimization of the pump design is essential. Computational Fluid Dynamic (CFD) is an effective method for performance optimization. However, it is difficult to conduct CFD simulation because of the sharp cusp of the rotor profile. Cut cell Cartesian mesh could be the solution to handle this complex and moving geometries. The aim of this paper is to evaluate ANSYS Forte for hook and claw pumps. Firstly, the conservation accuracy of the cut cell cartesian mesh is verified using an adiabatic piston cylinder case. Then, simulation results of hook and claw type pump are compared with experimental data. Finally, simulation results of air and hydrogen are compared. The results show that the CFD simulation of hook and claw pumps using cut cell cartesian mesh could provide an efficient and effective approach for the optimization of the system. 相似文献
9.
目的建立超高效液相色谱-串联质谱法同时测定糕点中6种常用合成甜味剂的分析方法。方法选用超纯水作为提取溶剂,涡旋和超声提取后,低温离心,取部分上清液加入正己烷除脂,Waters Atlantis■T3色谱柱、甲醇-5 mmol/L甲酸铵(含0.1%甲酸)作为流动相、亲水亲脂平衡型固相萃取柱HLB(hydrophile-lipophile balance)净化。结果6种甜味剂在质量浓度为10~200 ng/mL的曲线范围内呈良好线性关系,相关系数r均大于0.999,平均加标回收率在85.0%-98.2%之间,相对平均偏差(relative standard deviation,RSD)为1.3%~6.7%。结论该方法具有前处理简单、灵敏度高、检测速度快等优点,适合糖精钠、甜蜜素、三氯蔗糖、阿斯巴甜、阿力甜、纽甜的检测,但不适用于安赛蜜的检测。 相似文献
10.
Alison Willette Benjamin Fallen Hem Bhandari Carl Sams Feng Chen Virginia Sykes Chris Smallwood Kristin Bilyeu Zenglu Li Vincent Pantalone 《Journal of the American Oil Chemists' Society》2021,98(8):861-869
Soybean oil hydrogenation alters the linolenic acid molecule to prevent the oil from becoming rancid, however, health reports have indicated trans-fat caused by hydrogenation, is not generally regarded as safe. Typical soybeans contain approximately 80 g kg−1 to 120 g kg−1 linolenic acid and 240 g kg−1 of oleic acid. In an effort to accommodate the need for high-quality oil, the United Soybean Board introduced an industry standard for a high oleic acid greater than 750 g kg−1 and linolenic acid less than 30 g kg−1 oil. By combing mutations in the soybean plant at four loci, FAD2-1A and FAD2-1B, oleate desaturase genes and FAD3A and FAD3C, linoleate desaturase genes, and seed oil will not require hydrogenation to prevent oxidation and produce high-quality oil. In 2017 and 2018, a study comparing four near-isogenic lines across multiple Tennessee locations was performed to identify agronomic traits associated with mutations in FAD3A and FAD3C loci, while holding FAD2-1A and FAD2-1B constant in the mutant (high oleic) state. Soybean lines were assessed for yield and oil quality based on mutations at FAD2-1 and FAD3 loci. Variations of wild-type and mutant genotypes were compared at FAD3A and FAD3C loci. Analysis using a generalized linear mixed model in SAS 9.4, indicated no yield drag or other negative agronomic traits associated with the high oleic and low linolenic acid genotype. All four mutations of fad2-1A, fad2-1B, fad3A, and fad3C were determined as necessary to produce a soybean with the new industry standard (>750 g kg−1 oleic and <30 g kg−1 linolenic acid) in a maturity group-IV-Late cultivar for Tennessee growers. 相似文献