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Relationship of structure to properties of surfactants. 16. Linear decyldiphenylether sulfonates 总被引:1,自引:0,他引:1
Milton J. Rosen Zhen Huo Zhu Xi Yuan Hua 《Journal of the American Oil Chemists' Society》1992,69(1):30-33
The properties of some well-characterized sodium linear decyldiphenylether (C10DPE)sulfonates have been studied. Among the properties investigated are dynamic and equilibrium surface tension, critical
micelle concentration (CMC), area per molecule at the aqueous solution/air interface, wetting time by the Draves technique,
foaming by the Ross-Miles method, solubilization, and hydrotropy. The decyldiphenylether moiety appears to be equivalent to
a terminally substituted straight alkyl chain of 16 carbon atoms. The trialkyl- and dialkyl-mono-sulfonates have solubilities
of < 0.01 g/dm3 in water, but are readily soluble in hexane. The didecyldiphenyl ether disulfonate (DADS) has a very low CMC value (1.0 ×
10−5 mol dm−3) in aqueous 0.1 N Na+ solution (NaCl), characteristic of surfactants with two hydrophilic and two hydrophobic groups. It also has a much larger
area per molecule at the aqueous solution/air interface than the monodecyldiphenyl-ether monosulfonate (MAMS) and a much higher
surface tension at the CMC. MAMS has a much lower surface tension at a surface age of 1 second (γ1s) than either DADS or the monodecyldiphenylether disulfonate (MADS). In agreement with γ1s and γeq values, wetting times increase in the order: MAMS < DADS < MADS and initial foam heights decrease in the order: MAMS > DADS
> MADS. Solubilization for three water-insoluble surfactants decreases in the order: DADS > MAMS > MADS, while hydrotropy
is most pronounced with the disulfonates. 相似文献
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《分离科学与技术》2012,47(6):1115-1134
Abstract An aqueous solution based extraction process for andrographolide from Andrographis paniculata leaves has been developed using alkyl benzene sulfonates and carboxylates as hydrotropes. The plant cells are permeabilized by the hydrotrope solutions followed by solubilization of andrographolide into the solutions. The extraction and solubilization of andrographolide is affected by structure and concentration of hydrotrope, temperature and particle size. Sodium cumene sulfonate (Na‐CS) shows the most efficient solubilization of andrographolide amongst the hydrotropes studied. The solubility of andrographolide increased by two orders of magnitude in Na‐CS aqueous solutions and ~96% andrographolide extraction was achieved in just 20 min. 相似文献
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Abstract A comprehensive investigation of the solubility and mass transfer coefficient enhancement of benzene through hydrotropy has been undertaken. The solubility and mass transfer coefficient studies were carried out using hydrotropes such as citric acid, urea, nicotinamide, and sodium salicylate under a wide range of hydrotrope concentrations (0 to 3.0 mol/L) and different system temperatures (303 to 333 K). The effectiveness of hydrotropes was measured in terms of Setschenow constant KS and reported for all hydrotropes used in this study. 相似文献
4.
Claudia R. E. Mansur Luciana S. Spinelli Clara M. F. Oliveira Gaspar Gonzlez Elizabete F. Lucas 《应用聚合物科学杂志》1998,69(12):2459-2468
The effect of the hydrotropic agent, sodium p-toluenesulfonate (NaPTS), was evaluated on the micelle formation process and on phase behavior of aqueous solutions containing poly(ethylene oxide-b-propylene oxide) (PEO–PPO) copolymers. We have studied monofunctional diblock copolymers coupled with hydrocarbons groups (R—PEO—PPO—OH and R—PPO—PEO—OH, where R length is linear C4 and C12–14). The critical micelle concentration (CMC) and critical micelle temperature (CMT) values of the aqueous copolymers solutions were obtained from both surface tension versus concentration plots and the dye solubilization method. The influence of the hydrocarbons groups length and PPO segment position in the structure of the copolymers were also analyzed. The same measures were obtained for the aqueous solutions of hydrotropic agent which, in turn, also presented molecular aggregation. The presence of the hydrotropic agent in the aqueous copolymers solutions altered the surface tension of these solutions and the occupied molecular area per copolymer molecule at air–water interface and CMC and CMT values of the copolymers. On the other hand, the aggregation points and the surface tension of the NaPTS solutions were dependent on the copolymer structure and composition. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 2459–2468, 1998 相似文献
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