埋地管道在冻土带的热力变形分析

埋地油气管道通过永冻土地带时,由于管内介质与周围的冻土发生了热力作用,使冰土解冻,在管道周围形成融化圈。文章分析了永冻土的特点,建立了永冻土地带土壤传热数学模型:融化圈内外传热方程、管道向土壤和土壤表面向大气所放热量的守恒关系、融化圈界面处土壤温度、相变界面处固相变为液相的传热条件。还建立了埋地管道模型,并以穿过永冻土地带土壤的输油管道为例,分析并计算了各种应力的最大值所在的位置和大小,提出了在永冻土地带减小管道热力变形的措施。     

Prediction of brittle-to-ductile transitions in polystyrene

In this study it is attempted to predict brittle-to-ductile transitions (BDTs) in polystyrene blends, induced either by an increase in temperature or by a decrease in inter-particle distance. A representative, two-dimensional volume element (RVE) of a polystyrene matrix with 20% circular voids, is deformed in tension. During deformation a hydrostatic-stress based craze-nucleation criterion [1] is evaluated. The simulations demonstrate that crazes initiate at low temperatures while a transition from crazing to shear yielding (BDT) is found around 75 °C. The numerical results correlate well with tensile tests on similar heterogeneous polystyrene. The presence of an absolute length, as experimentally found, is more difficult to explain. Near a free surface a T_g-depression is measured for polystyrene and also the resistance to indentation in polystyrene is lower than expected from bulk properties. Both observations are rationalised by an enhanced segmental mobility of chains near a free surface. As a consequence of these findings, an absolute length-scale could be incorporated in the numerical simulations. For simplicity, the length-scale is modelled by taking a temperature gradient over a thin layer near the internal free surfaces of the RVE. Deformation of the RVE with different absolute length-scales shows that indeed also the experimentally found brittle-to-ductile transition can be predicted if the ligament thickness between the inclusions (‘voids’) in polystyrene is below a critical value of ca. 15 nm.     

井下乳化/水热催化裂解复合降黏开采稠油技术研究

实验考察了胜利孤东稠油井下催化水热裂解和乳化/催化水热裂解降黏效果。所用催化剂为水溶性铁镍钒体系,Fe3+∶Ni2+∶VO4+=5∶1∶1,100 g稠油与30 g 0.5%催化剂水溶液在240℃反应24小时。原始黏度(50℃)11.0和8.36 Pa.s的两种稠油裂解并静置除水后,黏度降低76.2%和75.6%,室温放置60天后降黏率下降小于3个百分点,气相色谱显示裂解后轻组分明显增加,红外光谱显示稠油组分发生脱羧反应且芳环数减少。讨论了稠油催化水热裂解反应机理。所用化学助剂JN-A在油水中均可溶,耐温达250℃,耐矿化度达50 g/L,其水溶液以30∶100的质量比与稠油混合时形成低黏度的O/W乳状液。当水相含1.0%JN-A和0.5%催化剂时,两种稠油水热裂解后的反应混合物为O/W乳状液,黏度仅为319和309 mPa.s,静置除水后的稠油降黏率增加到86.5%和87.3%,其中的轻组分含量进一步增加。该井下乳化/催化水热裂解复合降黏法成功地用于孤东两口蒸汽吞吐井,稠油井作业后初期采出的原油黏度由~9 Pa.s降低到1 Pa.s左右,随采油时间延长而逐渐升高,约50天后超过4Pa.s。图2表6参5。     

Effect of oxygen deficiency (δ) on transition temperature of yttrium cuprate superconductors

The nature of pairing mechanism as well as transition temperature of yttrium cuprates is discussed using the strong coupling theory. An interaction potential has been developed for the layered structure with two conducting CuO₂(a–b) layers in a unit cell. The interaction potential properly takes care of electron-electron, electron-phonon and electron-plasmon interactions. Furthermore, the electron-phonon coupling parameter (λ), the modified Coulomb repulsive parameter (μ*) and the 2D acoustic phonon (plasmon) energy as a function of oxygen deficiency is worked out. Finally, the superconducting transition temperature (T _c) is then evaluated by using these coupling parameters and obtainedT _c = 95(92)K for Y(Yb)Ba₂Cu₃O_7−δ superconductors withδ = 0·0. The model parameters estimated from the layered structure approach are consistent with the strong coupling theory. The result deduced on the variation ofT _c withδ are in fair agreement with the earlier reported data on yttrium cuprates. The analysis of the above results are discussed.     

流媒体技术及应用

主要介绍了流媒体技术、原理及其应用，详述了作为流媒体实现的关键技术-流式传输和传输的过程，以及目前支持流媒体传输的协议和使用较多的流式视频格式。     

PowerPoint2000动画设计应用

PowerPoint2000是Microsoft公司办公自动化软件Office2000的重要构件之一。其自身具有强大的处理功能，尤其是PowerPoint2000所提供的基本动画效果，更是给演示文稿增添了很多色彩。如果能将这些基本动画效果巧妙地组合在一起，就会创作出更富感染力的作品。就创作中的技巧并结合应用举例分析如下。相信人们可以利用这些设计思想，创作出更加精彩的作品。     

砂砾岩储集层含油性解释方法

LJ地区砂砾岩地层具有岩石结构复杂，储集层非均质性强，稠油和稀油并存的特点，利用测井资料解释含油性难度很大，以地层测试资料为依据，综合利用多种测井信息，提取反映含油性变化的测井特征参数；应用测井参数交会法和测井相分析法建立有效，快速识别稠油，油层和水层的标准，测井相分析法消除了用测井单参数和两参数交会解释含油性存在的多解性，提高子解释结果的成功率，用编制的解释软件处理了LJ地区58口井的资料，解释结果与试油资料对比吻合程度较高，为砂岩储层含油性解释提供了一种有效，快速的方法，为该区先导性试验提供了可靠的依据。     

大港白水头地区低阻油气层测井评价

在对白水头地区低阻油层的地质特征、物性特征及成因环境进行了分析研究后 ,应用测井曲线特征集法 ,把白水头油田常规油气层、低阻油气层、油水同层、水层等看成是独立的地质事件 ,建立了它们与测井曲线特征之间的对应关系 ,利用这种关系对未知地质事件进行了预测划分。最后根据所建模型定量计算储层各种参数 ,收到了良好的地质效果 ,表明测井曲线特征集法对于识别多成因的低阻油层是一种有效方法     

Modeling and assimilation of root zone soil moisture using remote sensing observations in Walnut Gulch Watershed during SMEX04

Soil moisture status in the root zone is an important component of the water cycle at all spatial scales (e.g., point, field, catchment, watershed, and region). In this study, the spatio-temporal evolution of root zone soil moisture of the Walnut Gulch Experimental Watershed (WGEW) in Arizona was investigated during the Soil Moisture Experiment 2004 (SMEX04). Root zone soil moisture was estimated via assimilation of aircraft-based remotely sensed surface soil moisture into a distributed Soil-Water-Atmosphere-Plant (SWAP) model. An ensemble square root filter (EnSRF) based on a Kalman filtering scheme was used for assimilating the aircraft-based soil moisture observations at a spatial resolution of 800 m × 800 m. The SWAP model inputs were derived from the SSURGO soil database, LAI (Leaf Area Index) data from SMEX04 database, and data from meteorological stations/rain gauges at the WGEW. Model predictions are presented in terms of temporal evolution of soil moisture probability density function at various depths across the WGEW. The assimilation of the remotely sensed surface soil moisture observations had limited influence on the profile soil moisture. More specifically, root zone soil moisture depended mostly on the soil type. Modeled soil moisture profile estimates were compared to field measurements made periodically during the experiment at the ground based soil moisture stations in the watershed. Comparisons showed that the ground-based soil moisture observations at various depths were within ± 1 standard deviation of the modeled profile soil moisture. Density plots of root zone soil moisture at various depths in the WGEW exhibited multi-modal variations due to the uneven distribution of precipitation and the heterogeneity of soil types and soil layers across the watershed.     

Influence of ethyl methacrylate content on the volume‐phase transition of temperature‐sensitive poly[(N‐isopropylacrylamide)‐co‐(ethyl methacrylate)] microgels

A novel series of temperature‐sensitive poly[(N‐isopropylacrylamide)‐co‐(ethyl methacrylate)] (p(NIPAM‐co‐EMA)) microgels was prepared by the surfactant‐free radical polymerization of N‐isopropylacrylamide (NIPAM) with ethyl methacrylate (EMA). The shape, size dispersity and volume‐phase transition behavior of the microgels were investigated by transmission electron microscopy (TEM), ultraviolet–visible (UV–Vis) spectroscopy, dynamic light scattering (DLS) and differential scanning calorimetry (DSC). The transmission electron micrographs and DLS results showed that microgels with narrow distributions were prepared. It was shown from UV–Vis, DLS and DSC measurements that the volume‐phase transition temperature (VPTT) of the p(NIPAM‐co‐EMA) microgels decreased with increasing incorporation of EMA, but the temperature‐sensitivity was impaired when more EMA was incorporated, causing the volume‐phase transition of the microgels to become more continuous. It is noteworthy that incorporation of moderate amounts of EMA could not only lower the VPTT but also enhance the temperature‐sensitivity of the microgels. The reason for this phenomenon could be attributed to changes in the complicated interactions between the various molecules. Copyright © 2004 Society of Chemical Industry