全文获取类型
收费全文 | 502篇 |
免费 | 26篇 |
国内免费 | 7篇 |
专业分类
电工技术 | 2篇 |
综合类 | 34篇 |
化学工业 | 296篇 |
金属工艺 | 3篇 |
机械仪表 | 1篇 |
建筑科学 | 3篇 |
矿业工程 | 7篇 |
能源动力 | 1篇 |
轻工业 | 91篇 |
水利工程 | 1篇 |
石油天然气 | 55篇 |
一般工业技术 | 23篇 |
冶金工业 | 14篇 |
原子能技术 | 2篇 |
自动化技术 | 2篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2022年 | 9篇 |
2021年 | 13篇 |
2020年 | 8篇 |
2019年 | 10篇 |
2018年 | 7篇 |
2017年 | 17篇 |
2016年 | 5篇 |
2015年 | 10篇 |
2014年 | 37篇 |
2013年 | 24篇 |
2012年 | 32篇 |
2011年 | 25篇 |
2010年 | 26篇 |
2009年 | 19篇 |
2008年 | 18篇 |
2007年 | 31篇 |
2006年 | 37篇 |
2005年 | 31篇 |
2004年 | 31篇 |
2003年 | 29篇 |
2002年 | 21篇 |
2001年 | 17篇 |
2000年 | 11篇 |
1999年 | 14篇 |
1998年 | 9篇 |
1997年 | 7篇 |
1996年 | 10篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1979年 | 2篇 |
排序方式: 共有535条查询结果,搜索用时 15 毫秒
1.
《Journal of dairy science》2022,105(5):4128-4143
Our objective was to evaluate the effects of unprotected choline chloride (Cho) on the ruminal microbiome at 2 dietary neutral detergent fiber (NDF) concentrations. We hypothesized that the effects of Cho on ruminal bacterial populations would depend on NDF. Eight dual-flow continuous-culture fermentors were arranged in a duplicated 4 × 4 Latin square as a 2 × 2 factorial with the following treatments: (1) 30% NDF-control (30% NDF diet, no supplemental choline); (2) 30% NDF-Cho (30% NDF diet plus 1.9 g of choline ion per kg of dry matter); (3) 40% NDF-control (40% NDF diet, no supplemental choline); and (4) 40% NDF-Cho (40% NDF diet plus 1.9 g of choline ion per kg of dry matter). We did 4 fermentation periods of 10 d each and used the last 3 d for collection of samples of solid and liquid digesta effluents for DNA extraction. Overall, 32 solid and 32 liquid samples were analyzed by amplification of the V4 variable region of bacterial 16S rRNA. Data were analyzed with R (R Project for Statistical Computing) and SAS (SAS Institute Inc.) to determine effects of Cho, NDF, and NDF × Cho on taxa relative abundance. The correlation of propionate molar proportion with taxa relative abundance was also analyzed. At the phylum level, relative abundance of Firmicutes in the liquid fraction tended to be greater when Cho was supplemented with a 30% NDF diet. At the order level, Cho increased Coriobacteriales in solid fraction and decreased Fibrobacterales in liquid fraction. Moreover, Cho decreased abundance of Clostridiales and increased Selenomonadales in the solid fraction, only with the 30% NDF diet. For genera, lower abundance of Pseudobutyrivibrio resulted from Cho in solid and liquid fractions. Greater abundance of Succinivibrio in solid and Selenomonas and Selenomonas 1 in liquid resulted from Cho with the 30% NDF diet. Propionate molar proportion was positively correlated with relative abundance of order Selenomonadales in solid and liquid fractions, and with genus Succinivibrio in solid and genera Selenomonas and Selenomonas 1 in liquid. Our results indicate that Cho primarily decreases abundance of bacteria involved in fiber degradation and increases abundance of bacteria mainly involved in nonstructural carbohydrate degradation and synthesis of propionate, particularly when a diet with 30% NDF is provided. 相似文献
2.
María Clara Verdi Constanza Melian Patricia Castellano Graciela Vignolo Mariana Blanco Massani 《International Journal of Food Science & Technology》2020,55(1):267-275
The effectiveness of antimicrobial mixtures against Listeria innocua 7, used as a L. monocytogenes surrogate, was investigated in broth and a food system. Synergistic effects were found for nisin (Nis), potassium sorbate (PS), calcium propionate (CP) and sodium lactate (SL), Nis + PS being the most effective binary mixture that exhibited listericidal activity in broth. To assess the effect of adding lactocin AL705 (AL705) to Nis + organic acid salt combinations, tridimensional isobolograms were generated. Sub-MIC combinations of the antimicrobials exerted bactericidal activity against L. innocua 7 after AL705 addition to the binary mixtures. However, when applied on Sardo cheese contaminated with L. innocua 7 (initial inoculum 4.45 ± 0.06 CFU g−1), only Nis + PS + AL705 produced count reductions respect to the control, reaching 3.04 ± 0.35 CFU g−1 counts after 15 days at 15 °C. Ternary combinations containing AL705 showed potential to reduce antimicrobial usages for L. innocua 7 inhibition. 相似文献
3.
4.
TiSiW12O40/TiO2催化合成丙酸正丙酯 总被引:2,自引:0,他引:2
研究了固载杂多酸盐TiSiW12O40/TiO2催化丙酸与正丙醇的酯化反应,探讨了催化剂用量,反应时间及醇酸摩尔比对酯收率的影响。当醇酸摩尔比为1.3:1,催化剂的量为醇酸总质量的1.5%。反应时间为1.0h,酯产率可达71.4%以上,采用该催化剂合成丙酸正丙酯不仅酯化反应温度低,反应时间较短,催化剂用量少,而且可较好地回收利用,可降低成本;因此,TiSiW12O40/TiO2是合成丙酸正丙酯的优良催化剂,具有良好的应用前景。 相似文献
5.
6.
Vapour-phase reactions of, in situ, prepared formaldehyde with methyl propionate were studied using X, Y and ZSM-5 zeolite catalysts. Base properties of these zeolites were enhanced by KOH or NaN3 treatment. The niobium and molybdenum ZSM-5 zeolite supported oxides were also tested for their catalytic activity. The results are discussed in terms of an ability of zeolite catalysts to synthesize methyl methacrylate. 相似文献
7.
8.
自行研制了氰乙基(25%,质量分数)甲基硅橡胶(XE-60)石英毛细管色谱柱。建立了对含游离酸的丙二醇单甲醚丙酸酯的色谱分析方法。该法具有分离效果好,分析速度快的优点。 相似文献
9.
10.
Poly(vinyl alcohol) (PVA) can be dissolved in a nonaqueous medium in the presence of catalytic concentration of ethyl nitrate dimethyl sulfoxide, C2H5ONO2·DMSO. From the PVA solution, poly(vinyl propionate), PVPR was prepared by the homogeneous esterification of PVA with propionic acid. The ester thus formed contained some unconverted hydroxyl group. The formation of the ester was confirmed by the IR and 1H‐NMR spectra. The molecular weight of the ester was determined by GPC and intrinsic viscosity (η) was determined by viscometric method. Glass transition temperature, Tg, was obtained from differential scanning calorimetric (DSC) analysis. Thermal stabilities of the ester were checked by thermogravimetric analysis (TGA) and differential thermogravimetric (DTG) analysis. The efficiency of the ester as a flow improver of crude oil was also examined. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5675–5679, 2006 相似文献