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排序方式: 共有2299条查询结果,搜索用时 46 毫秒
1.
Yu Zhao Zhigang Xu Zongshi Li Weihong Qiao Lubai Cheng 《Petroleum Science and Technology》2006,24(7):821-827
Heavy alkyl benzene sulfonates (HABS) were synthesized, and their interfacial tensions were measured and compared with those of petroleum sulfonates ORS-41. Effects of their coupling with lignosulfonate were also studied. The results showed that HABS exhibited good interfacial activities and the system of HABS blending with LS displayed better interfacial activities than ORS-41 and therefore reduced the prime cost. Their best proportions of synergism were from 3:1 to 4:1. HABS might be a more promising alkali-surfactant-polymer (ASP) flooding agent. 相似文献
2.
Biodegradation of monoaromatic hydrocarbons in aquifer columns amended with hydrogen peroxide and nitrate 总被引:1,自引:0,他引:1
The ability of indigenous microorganisms to degrade benzene, toluene, ethylbenzene and xylenes (BTEX) in laboratory scale flow-through aquifer columns was tested separately with hydrogen peroxide (110 mg/l) and nitrate (330 mg/l as NO3−) amendments to air-saturated influent nutrient solution. The continuous removal of individual components from all columns relative to the sterile controls provided evidence for biodegradation. In the presence of hydrogen peroxide, the indigeneous microorganisms degraded benzene and toluene (> 95%), meta- plus para-xylene (80%) and ortho-xylene (70%). Nitrate addition resulted in 90% removal of toluene and 25% removal of ortho-xylene. However, benzene, ethylbenzene, meta- and para-xylene concentrations were not significantly reduced after 42 days of operation. Following this experiment, low dissolved oxygen (< 1 mg/l) conditions were initiated with the nitrate-amended column influent in order to mimic contaminated groundwater conditions distal from a nutrient injection well. Toluene continued to be effectively degraded (> 90%), and more than 25% of the benzene, 40% of the ethylbenzene, 50% of the meta- plus para-xylenes and 60% of the ortho-xylene were removed after several months of operation. 相似文献
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The catalysts of CeO2 and the mixture of CeO2 and CuO were prepared, and the activities of these catalysts for completely oxidizing benzene were studied.The results show that the optimal proportion of CeO2/CuO is 6: 4.The highest temperature at which benzene was completely oxidized on these catalysts at different airspeed was measured.Compared these catalysts with the noble metal used, our catalysts had superiority in the resources and the industrial cost besides good activities. 相似文献
6.
借助于三相平衡体系的性能分析,提出了一步法复苏再生阴离子交换树脂的新思路,从而实现阴离子交换树脂的再生和有机污染去除的同步性.对三相再生体系的再生能力,循环再生能力和树脂的有机污染去除能力进行了研究,并进行了基本性能测试和理论分析.结果表明三相再生体系能够很好的保持再生和循环再生效果,缓解了树脂的有机污染,一步复苏再生法具有理论可行性。 相似文献
7.
在石家庄焦化厂两苯塔系统工艺的基础上,通过对生产中两苯塔波动引起轻苯质量不稳定的原因进行分析,找到了不稳定的原因,并提供了行之有效的解决方法。 相似文献
8.
New mesogenic homologous series having an azo central linkage was synthesized by fixing a rigid 4-methyl phenyl azo group
to resorcinol moiety. The terminal and lateral phenolic -OH groups were esterified, one by one, with 4-n-alkoxybenzoyl and acetyl group, respectively. All the twelve homologues synthesized exhibit mesomorphism. The methoxy ton-decyloxy andn-hexadecyloxy derivatives exhibit monotropic nematic mesophase whereas,n-dodecyloxy andn-tetradecyloxy derivatives exhibit enantiotropic nematic mesophase. The mesogenic properties of the present series was compared
with those of other structurally related mesogenic series.
Paper presented at the 5th National Seminar on Liquid Crystals, University of Jammu, Jammu, December 1997. 相似文献
9.
Development of a poly-functional catalyst that has higher hydrodealkylation activity based on 15% Cr/γ- Al2 O3 was researched for benzene production from an alkyl-aromatic mixture via hydrodealkylation. For this goal, the effects of the promoters like Fe, Co, or Ni and their concentrations on the activity of a Cr/Al2 O3 catalyst were investigated. Toluene + n-heptane + tetrahydrotiophene (89:10:1 w%) model mixture, which has the same content as industrial aromatics, was used as feedstock. The activities of catalysis in reactions of hydrodealkylation, hydrocracking, and hydrogenolize with respect to conversions of toluene, heptane, and tetrahydrotiophene were tested, respectively. As to the obtained results, the catalyst including 5% Fe has a higher hydrodealkylation activity, compared to the catalyst including Co, and especially to the alumocrom catalyst not including a promoter, while it has a lower coke formation and reduced activity to the catalyst including Ni. 相似文献
10.
磷铝杂原子固体酸催化剂催化合成乙酸异丙酯 总被引:5,自引:0,他引:5
高文艺 《精细石油化工进展》2003,4(12):30-31
以丙烯和乙酸为原料 ,自制的磷铝杂原子固体酸作催化剂催化合成了乙酸异丙酯 ,考察了反应温度、反应压力、反应空速 (LHSV)及催化剂用量对酯化反应的影响 ,同时考察了固体酸催化剂的重复使用性。确定了最佳合成条件 :反应压力 1 5MPa,反应温度 1 60℃ ,反应空速2 0h-1,催化剂用量 2 0g。在此条件下 ,酯化率可达 91 5 % ,乙酸异丙酯选择性达 99 0 % ,且催化剂的重复使用性良好。 相似文献