排序方式: 共有4条查询结果,搜索用时 15 毫秒
1
1.
Imino‐/enaminophosphonates derived from amines and diethyl phenacyl phosphonates undergo oxidative cyclization via C H bond activation catalyzed by palladium chloride to provide a convenient route for the synthesis of substituted indol‐3‐yl and pyrrol‐3‐yl phosphonates.
2.
Xiubin Li Gaobo Hu Ping Luo Guo Tang Yuxing Gao Pengxiang Xu Yufen Zhao 《Advanced Synthesis \u0026amp; Catalysis》2012,354(13):2427-2432
A highly efficient palladium(II)‐catalyzed hydration of a wide range of alkynylphosphonates to the corresponding β‐ketophosphonates has been developed to give high yields at 80 °C in 1, 4‐dioxane, with no acidic or alkaline cocatalysts required. The described catalytic system should provide an efficient alternative to highly toxic mercury‐catalyzed methodologies and be useful in synthetic programs. 相似文献
3.
《Journal of Sulfur Chemistry》2013,34(3):249-256
The reaction of β-keto-δ-carbethoxyphosphonates and phosphineoxides with active methylene nitriles leads to the corresponding phosphonoalkylidenes. Treatment of these compounds with sulfur, under the classical Gewald reaction conditions, gives a ca. 1:1 mixture of novel aminophosphonothiophene derivatives 3 and 3 ′ . In order to improve the regioselectivity of the reaction, novel conditions have been developed for the Gewald condensation, in which we used an inorganic base NaH in THF as the solvent. These conditions afforded exclusively the 3-regioisomer in good yield. 相似文献
4.
Sandun Perera Vijaya Kumar Naganaboina Long Wang Bin Zhang Qunsheng Guo Laxmidhar Rout Cong‐Gui Zhao 《Advanced Synthesis \u0026amp; Catalysis》2011,353(10):1729-1734
The cross‐aldol reaction between enolizable aldehydes and α‐ketophosphonates was achieved for the first time by using 9‐amino‐9‐deoxy‐epi‐quinine as the catalyst. β‐Formyl‐α‐hydroxyphosphonates were obtained in high to excellent enantioselectivities. The reaction works especially well with acetaldehyde, which is a tough substrate for organocatalyzed cross‐aldol reactions. The products were demonstrated to have anticancer activities. 相似文献
1