Ring‐opening polymerization of lactones initiated by diphenylzinc–coinitiator systems

Diphenylzinc, alone or in combination with water and butanone as coinitiators, was used as a polymerization initiator system for a variety of lactones at varying temperatures. The resulting data indicate that the course of the polymerization is greatly influenced by the lactone structure, as well as by the molar ratio of coinitiator to diphenylzinc. When used alone, diphenylzinc exhibited high activity as an initiator in δ‐valerolactone polymerizations, although it was less efficient when used in the β‐butyrolactone and the β‐propiolactone polymerizations. Activity in the polymerization of β‐lactones was increased by adding small amounts of butanone or water. It was also observed that the diphenylzinc–butanone combination was more effective than the diphenylzinc–water mixture in the polymerizations of β‐butyrolactone and β‐propiolactone. Copyright © 2003 Society of Chemical Industry     

Ring‐opening polymerization of D,L‐lactide by rare earth 2,6‐dimethylaryloxide

Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)₃) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)₃ exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 10⁴ g mol^?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)₃ has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)₃ is 69.6 kJ mol^?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry     

火焰图像特征在火灾数字图像识别中的运用

火焰尖角数目和圆形度是早期火灾火焰的主要特征,本文主要论述了如何在数学形态学基础上,利用火灾火焰的两个特点判断和识别早期火情。实验中,对火焰的二值图像进行开运算,即先腐蚀,再膨胀,目的是为了对火焰图像进行形态学滤波,去噪。从实验结果可以看出,该算法可以很好的识别火焰和干扰源。     

Surface modification of starch nanocrystals through ring‐opening polymerization of ε‐caprolactone and investigation of their microstructures

Bionanoparticles of starch obtained by submitting native potato starch granules to acid hydrolysis conditions. The resulted starch nanoparticles were used as core or macro initiator for polymerization of ε‐caprolactone (CL). Starch nanoparticle‐g‐polycaprolactone was synthesized through ring‐opening polymerization (ROP) of CL in the presence of Sn(Oct)₂ as initiator. The detailed microstructure of the resulted copolymer was characterized with NMR spectroscopy. Thermal characteristic of the copolymer was investigated using DSC and TGA. By introducing PCL, the range of melting temperature for starch was increased and degradation of copolymer occurred in a broader region. X‐ray diffraction and TEM micrographs confirmed that there was no alteration of starch crystalline structure and morphology of nanoparticles, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Kinetics study of Ti[O(CH2)4OCHCH2]4 initiated ring‐opening polymerization of ε‐caprolactone by differential scanning calorimetry

Chemical shrinkage was used for the in situ measurement of the progressing chemical stabilization reactions and the influence of ozone during the stabilization of polyacrylonitrile. A method for evaluating the activation energy through the sensitivity temperature is presented. The calculated results show that the activation energies were 161.57 kJ/mol in air and 181.23 kJ/mol in ozone-enriched air. Therefore, the chemical reactions were postponed during stabilization in ozone-enriched air. Ozone seemed to act in three ways: first, ozone promoted the formation of the serious skin–core structure. Second, ozone accelerated the chemical reactions and shortened the stabilization time at lower heating rates. Third, ozone postponed the chemical reactions. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

BINELOCA 程序与广东岭澳核电站大破口失水事故分析

ＢＩＮＥＬＯＣＡ程序是在吸收国外先进大破口失水事故分析计算机程序的基础上，针对我国现有大破口失水事故分析程序的不足和工程应用方面的问题，采用了一些成熟的、新型的和当今国际公认的瞬态热工水力数学物理模型以及水和蒸汽性质参数计算公式改编而成的大破口失水事故分析程序。通过对广东岭澳核电站大破口失水事故的计算表明，ＢＩＮＥＬＯＣＡ程序计算的结果与法国计算的结果是一致的。     

Decentralized weighted control for a class of large‐scale systems with multi‐modes

In this paper, the control synthesis problem for a class of large‐scale systems with multi‐modes that are called large‐scale switched systems is addressed. By introducing the concept of decentralized switching signal and the relevant decentralized average dwell time, the asymptotic stability and weighted ?₂ gain performance are investigated. It should be noted that the decentralized switching covers general switching cases for large‐scale switched systems, namely, it admits both time‐dependent switching signal and arbitrary switching signal blended in the decentralized switching. Then, on the basis of the analysis results, the decentralized weighted control scheme including state feedback controller gains and switching signals is studied. Several design algorithms are proposed to meet different controller design problems. Finally, numerical examples are provided to illustrate theoretical findings within this paper. Copyright © 2013 John Wiley & Sons, Ltd.     

The kinetics of B‐a and P‐a type copolybenzoxazine via the ring opening process

The structure of benzoxazines is similar to that of phenolic resin through thermal self‐curing of the heterocyclic ring opening reaction that neither requires catalyst nor releases any condensation byproduct. These polybenzoxazine resins have several outstanding properties such as high thermal stability and high glass transition temperature. To better understand the curing kinetics of this copolybenzoxazine thermosetting resin, dynamic and isothermal differential scanning calorimetry measurements were performed. Three models, the Kissinger method, the Flynn–Wall–Osawa method, and the Kamal method, were used to describe the curing process. Dynamic kinetic activation energies based on Kissinger and Flynn–Wall–Osawa methods are 72.11 and 84.06 KJ/mol, respectively. The Kamal method based on an autocatalytic model results in a total order of reaction between 2.66 and 3.03, depending on curing temperature. Its activation energy and Arrhenius preexponential are 50.3 KJ/mol and 7959, respectively. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 730–737, 2005     

大内跨小边跨框架结构预应力筋优化布置方法

预应力筋的优化布置是大内跨小边跨的多跨预应力混凝土框架结构合理设计计算的关键.为满足控制截面承载力最大的需要,以往常将大跨所需预应力筋布置为连续曲线,并按水平直线延伸通过其相邻的两小跨,按这种布置方式仅使大跨内产生竖向向上的预应力等效荷载,可较好平衡大跨的竖向外荷载;而若将大跨及相邻的两小跨统一考虑,预应力筋按连续曲线布置,张拉产生的预应力等效荷载不但可有效平衡大跨的竖向外荷载而且也可平衡小跨的竖向外荷载,可以使荷载平衡得到优化实现.以一典型工程为例,分析了在相同条件下两种预应力筋布置过程中张拉引起的综合弯矩、主弯矩和次弯矩的分布和量值上差异,比较了两类布筋形式对正截面承载力计算结果的影响,验证了对大内跨小边跨框架结构统一考虑后整体上按三段连续正反抛物线预应力筋布置的合理性.     

Genetic algorithm‐based neural‐network modeling approach applied to AlGaN/GaN devices

An accurate equivalent circuit large‐signal model (ECLSM) for AlGaN‐GaN high electron mobility transistor (HEMT) is presented. The model is derived from a distributed small‐signal model that efficiently describes the physics of the device. A genetic neural‐network‐based model for the gate and drain currents and charges is presented along with its parameters extraction procedure. This model is embedded in the ECLSM, which is then implemented in CAD software and validated by pulsed and continuous large‐signal measurements of on‐wafer 8 × 125‐μm GaN on SiC substrate HEMT. Pulsed IV simulations show that the model can efficiently describe the bias dependency of trapping and self‐heating effects. Single‐ and two‐tone simulation results show that the model can accurately predict the output power and its harmonics and the associated intermodulation distortion (IMD) under different input‐power and bias conditions. © 2012 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2013.