In this study, a series of donor–acceptor–donor (D-A-D) type small molecules based on the fluorene and diphenylethenyl enamine units, which are distinguished by different acceptors, as holetransporting materials (HTMs) for perovskite solar cells is presented. The incorporation of the malononitrile acceptor units is found to be beneficial for not only carrier transportation but also defects passivation via Pb–N interactions. The highest power conversion efficiency of over 22% is achieved on cells based on V1359, which is higher than that of spiro-OMeTAD under identical conditions. This st shows that HTMs prepared via simplified synthetic routes are not only a low-cost alternative to spiro-OMeTAD but also outperform in efficiency and stability state-of-art materials obtained via expensive cross-coupling methods. 相似文献
Dithiacarbamates reacted with malononitrile dimer to give 1,4-dihydropyridine-2-thiols. The structures of the obtained products were proven by IR, mass, and NMR spectra and elemental analyses. The reaction mechanism is also discussed. 相似文献
The reactions of thiocarbohydrazones with malononitrile dimer under microwave irradiation are reported. These reactions give 6-imino-1,3,4-thiadiazines in good yields. The structures of products were elucidated by MS, IR and NMR spectra together with elemental analyses. The reaction mechanism was discussed. 相似文献
Anionic solution polmerization studies of benzylidene malononitrile, benzylidene ethyl cyanoacetate and their para chloro
derivtives in dimethyl formamide (DMF) as a reaction medium using pipridene as initiator under nitrogen atmosphere at 100
°C were carried out. Infrared, 1H NMR and ultraviolet-visible (UV-Vis) spectroscopic studies for the obtained polymers were investigated. The effect of γ-irradiation
on PMMA films doped with 1 % of the benzylidene polymers was investigated by uv-vis spectroscopy. A change in the intensity
of absorption bands with increasing irradiation dose was recorded. It is suggested that PMMA films doped with this type of
benzylidene polymer can be used as dosimeter. 相似文献
We have developed and optimized an enantioselective Michael reaction of malononitrile with β,β‐disubstituted nitroalkenes. This reaction was catalyzed by a cinchona alkaloid derived thiourea catalyst, producing products of high yields (up to 98 %) and stereoselectivities (up to 93 % ee). One of the adducts was used as an intermediate for the synthesis of dihydropyrrole derivative bearing a synthetically valuable quaternary chiral center.