全文获取类型
收费全文 | 643篇 |
免费 | 75篇 |
国内免费 | 8篇 |
专业分类
综合类 | 13篇 |
化学工业 | 233篇 |
金属工艺 | 3篇 |
建筑科学 | 1篇 |
矿业工程 | 2篇 |
能源动力 | 12篇 |
轻工业 | 408篇 |
石油天然气 | 4篇 |
无线电 | 10篇 |
一般工业技术 | 35篇 |
冶金工业 | 3篇 |
原子能技术 | 2篇 |
出版年
2024年 | 2篇 |
2023年 | 8篇 |
2022年 | 16篇 |
2021年 | 16篇 |
2020年 | 27篇 |
2019年 | 25篇 |
2018年 | 25篇 |
2017年 | 36篇 |
2016年 | 30篇 |
2015年 | 17篇 |
2014年 | 26篇 |
2013年 | 34篇 |
2012年 | 57篇 |
2011年 | 52篇 |
2010年 | 32篇 |
2009年 | 34篇 |
2008年 | 21篇 |
2007年 | 41篇 |
2006年 | 51篇 |
2005年 | 35篇 |
2004年 | 28篇 |
2003年 | 25篇 |
2002年 | 18篇 |
2001年 | 13篇 |
2000年 | 9篇 |
1999年 | 9篇 |
1998年 | 16篇 |
1997年 | 5篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 2篇 |
排序方式: 共有726条查询结果,搜索用时 15 毫秒
1.
Ghurmallah H. Al‐Ghamdi E. David Sudol Victoria L. Dimonie Mohamed S. El‐Aasser 《应用聚合物科学杂志》2006,101(6):4504-4516
Miniemulsification technology was used to encapsulate TiO2 particles inside a styrene/n‐butyl acrylate copolymer with high loading levels (11 to 70% PVC (pigment volume concentration)). In this approach, a St/BA copolymer dissolved in toluene in the presence of a costabilizer (hexadecane) was mixed with a dispersion of TiO2 particles in toluene and sonified, and then emulsified in an aqueous surfactant solution by sonification. The effect of sonification time on both the dispersibility of the TiO2 particles in the presence of the copolymer and hexadecane and on the encapsulated particle size was investigated. Particle size analysis by dynamic light scattering showed that these composite latexes are quite stable. It was also found that as the TiO2 loading increased from 11 to 43% PVC, the particle size of the TiO2 dispersion decreased while the polymer‐encapsulated TiO2 particle size increased. The effect of surfactant concentration (sodium lauryl sulfate, SLS) on the encapsulated particle size was investigated using four different SLS concentrations in the 11% PVC system. The results showed that as the SLS concentration increased the particle size decreased, as expected. Also it was found that the minimum surfactant concentration that gives stable encapsulated TiO2 particles is above 10 mM SLS. The role of HD in the recipe was studied for an artificial latex containing no TiO2 and one prepared at 11% PVC, in terms of particle size before and after solvent stripping, and its effect on the Tg. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 4504–4516, 2006 相似文献
2.
Double‐shell‐structured microcapsules encapsulating phase‐change materials (micro‐PCMs) with an average diameter of 5–10 μm were successfully fabricated with a melamine–formaldehyde resin as the coating material. The mechanical properties of the obtained piled micro‐PCMs, tested under compression, were evaluated with a pressure sensor. Typical stress–strain curves showed that both the single‐shell‐ and double‐shell‐structured microcapsules had yield points and maximum point pressures. The morphological changes in the shell surface confirmed the existence of yield points by scanning electron microscopy. When the pressure was beyond the yield point, the microcapsules showed conventional plastic behavior, and the double‐shell structure was more mechanically stable than the single‐shell one. Differential scanning calorimetry analysis results revealed that the properties of the phase‐change materials experienced no variation after coating with a single‐shell‐ or double‐shell‐structured polymer. Thermogravimetric analysis showed that the double‐shell‐structured micro‐PCMs experienced a weight loss of only about 5% from 86.3 to 232°C but did so more rapidly from 232 to 416°C. Thermoregulation was determined with periodical heating and cooling tests. The data showed that the micro‐PCMs changed temperature in a narrow range of 20–25°C with a time lag of 20 min to reach the maximum or minimum temperature in comparison with a reference temperature of 18–28°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 1295–1302, 2007 相似文献
3.
Jong Suk Lee Yoon Sung Nam Byung‐Young Kang Sang‐Hoon Han Ih‐Seop Chang 《应用聚合物科学杂志》2004,92(1):517-522
To stabilize vitamin A in a cosmetic/dermatological formulation, we present here a new encapsulation method based on polymer microspheres having a localized “proton‐buffering” capacity. Poly(methyl methacrylate)‐g‐polyethylenimine (PMMA‐g‐PEI) was prepared by direct condensation grafting of PEI onto poly(methyl methacrylate‐co‐methyl acrylic acid). The reaction was confirmed by FT‐IR analysis showing the amide vibration at 1,550 cm?1. Elemental analysis indicated that the weight content of the grafted PEI was 1.6% (w/w). Vitamin A was encapsulated into PMMA‐g‐PEI microspheres by using an oil‐in‐water (O/W) single emulsion method. The presence of PEI moiety dramatically improved the chemical stability of vitamin A in microspheres. Vitamin A encapsulated within PMMA‐g‐PEI microspheres maintained 91% of its initial activity after 30‐day incubation at 40°C, while only maintaining 60% within plain PMMA microspheres. This study demonstrates that proton‐buffering within hydrophobic polymer matrix is a useful strategy for stabilizing “acid‐labile” active ingredients. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 517–522, 2004 相似文献
4.
5.
电子纸技术及其研究现状与展望 总被引:5,自引:4,他引:5
就电子纸显示的基本原理和技术特征及其研究进展几个方面做了综合评述 ,并展望了电子纸在未来显示技术和设备中的应用前景。 相似文献
6.
使用几种不同的壁材及乳化剂对天然维生素E进行微胶囊化,通过对比微囊化效果确定最佳选材及条件,并对最终产品各项性能指标进行测定.结果表明,最佳壁材为纯胶(GUM 2000)与蔗糖,最佳乳化剂为蔗糖酯S1570(HLB 15),壁材比例m(纯胶)∶ m(蔗糖)为2∶1,乳化剂加入量为0.5%,喷雾干燥进风口温度180~19... 相似文献
7.
A role for isothiocyanates in plant resistance against the specialist herbivore Pieris rapae 总被引:8,自引:1,他引:8
We experimentally reanalyzed the classic interaction between Pieris rapae, a specialist lepidopteran herbivore, and isothiocyanates (mustard oils) that are characteristic phytochemicals of the Brassicaceae. Previous investigations have suggested that P. rapae is unaffected by isothiocyanates. Using whole plants, root extracts, and a microencapsulated formulation of allyl isothiocyanate, we now show that isothiocyanates reduce herbivore survival and growth, and increase development time, each in a dose-dependent manner. Neither the substrate allyl glucosinolate, nor myrosinase, the enzyme that results in the breakdown of glucosinolates, negatively affected P. rapae. Thus, we present strong evidence for a role for isothiocyanates in plant resistance against the specialist herbivore P. rapae. 相似文献
8.
用超临界流体技术制备微胶囊的方法 总被引:2,自引:0,他引:2
介绍了目前国内外使用超临界技术制备微胶囊的原理和方法.通过利用该技术在高分子材料、无机材料和有机材料方面制备微胶囊的应用实例,综合分析了各种制备微胶囊技术的特点、研究现状和存在的问题. 相似文献
9.
Microencapsulation of Nigella sativa seeds oil containing thymoquinone by spray‐drying for functional yogurt production
下载免费PDF全文
![点击此处可从《International Journal of Food Science & Technology》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Abdol‐Samad Abedi Marjan Rismanchi Mehrnoush Shahdoostkhany Abdorreza Mohammadi Hedayat Hosseini 《International Journal of Food Science & Technology》2016,51(10):2280-2289
The present work reports on the microencapsulation of Nigella sativa seeds oil containing thymoquinone (TQ) by spray‐drying, using modified starch (MS) and maltodextrin (MD) mixture as wall materials aimed at producing functional yogurt. First, the impact of different ratios of MS/MD on microencapsulation efficiency (ME) and TQ retention was investigated. The highest ME (90.10%) was found in microcapsules prepared from emulsion with 80/20 ratio of MS/MD; however, the microcapsules prepared with 50/50 ratio was selected for considering TQ stability under storage conditions and functional yogurt production due to an acceptable ME (89.48%) and better TQ retention (61.12%). The results showed that the microcapsules stored at refrigerator temperature had the highest content of TQ after 4 weeks. Moreover, the results of chemical and sensory analysis suggest that N. sativa seeds oil microcapsules can be used for producing functional yogurt due to high stability of TQ and proper chemical and sensory properties. 相似文献
10.
Asteria Luzardo‐Álvarez Álvaro Antelo‐Queijo Victor H. Soto José Blanco‐Méndez 《应用聚合物科学杂志》2012,123(6):3595-3604
Hydrophobically modified chitosan containing β‐cyclodextrin (CD) units was synthesized by using tosylated β‐CD. The final product was characterized by Fourier transform infrared (FTIR) spectroscopy, elemental analysis and TGA, and rheometry. The polymer bearing β‐CD moieties was used to obtain crosslinked microparticles by spray‐drying which could then be used in a controlled release system for drugs. FTIR confirmed the formation of an amide linkage between cyclodextrin and chitosan. As fluorescence spectroscopy demonstrated, hydrophobic microenvironments were formed by chitosan bearing cyclodextrin in solution at lower concentrations than for chitosan. Rheometry and FTIR showed the crosslinking of the new polymer using genipin, a molecule of natural origin. Microspheres (MS) obtained by spray‐drying showed narrow size distribution when β‐CD was grafted onto chitosan and ξ‐potential of MS was slightly lower although it remained positive. In conclusion, β‐CD linked chitosan polymer can be considered as a very promising controlled drug delivery system for drugs. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献