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在碳化铁超微粒子(UFP)催化剂制备的基础上,采用内径5mm连续流动加压固定床微型反应器对该催化剂性能做了系统评价,在无原料气循环条件下的试验结果表明,在1.5MPa、320℃和空速(VHSV)约600h-1条件下,反应20h达到催化剂活性稳定期,测得20—48h期间CO的平均转化率达96.1%,丙烯在气相产物中的平均摩尔百分含量可达67.3%。同时讨论了反应温度、压力、原料配比、还原温度等对催化剂活性和选择性的影响。与国内外现有的F-T合成催化剂相比,碳化铁超微粒子催化剂是一种催化活性高、选择性强、反应条件温和的新型催化剂 相似文献
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Microreaction technology is one of the most innovative and rapid developing fields in chemical engineering, synthesis and process technology. Many expectations toward enhanced product selectivity, yield and purity, improved safety, and access to new products and processes are directed to the microreaction technology. Microfluidic mixer is the most important component in microfluidic devices. Based on various principles, active and passive micromixers have been designed and investigated. This review is focused on the recent developments in microfluidic mixers. An overview of the flow phenomena and mixing characteristics in active and passive micromixers is presented, including the types of physical phenomena and their utilization in micromixers. Due to the simple fabrication technology and the easy implementation in a complex microfluidic system, T-micromixer is highlighted as an example to illustrate the effect of design and operating parameters on mixing efficiency and fuid flow inside microfluidic mixers. 相似文献
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基于连续、可控合成开发微反应系统与工艺,设计搭建了由注射泵、聚四氟乙烯毛细管以及油浴锅组成的毛细管微反应系统。利用注射泵,通过调节注射泵流速,从而控制反应时间,在极短的时间内合成出三维Bi2S3纳米棒簇。通过改变配体及反应时间,Bi2S3由纳米颗粒向一维纳米棒过渡。利用XRD、TEM对其结构和形貌进行了表征。 相似文献
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Yue Cao Jian-Xiao Wang Chen Lin Yu-Qian Geng Cheng Ma Jun-Jie Zhu Leyong Wang Wenlei Zhu 《Advanced functional materials》2023,33(18):2214294
The competence to construct sensing platforms capable of selective manipulation in complex biological fluids undoubtedly underpins critical future advances in healthcare. Despite the fact that electrochemiluminescence (ECL) has long been an influential technology for clinical diagnosis worldwide, ECL interface that optimizes fouling resistance has been mimicked less often, especially in an integrated platform. Herein, ECL transducer is prepared by the integration of protonated g-C3N4 and Ti3C2Tx MXene nanosheets, displaying enhanced charge injection/transfer, and inherent catalytic capacities for coreactant ECL. Mussel-bioinspired polydopamine was exploited as a thin, surface-adherent substrate to coat the solid-state transducer and further initiate secondary reactions via Michael Addition for tailing recognition element and zwitterionic segment. This architecture guarantees not only the least suppression of ECL performance but also desired antifouling properties, ensuring < 7.45% of ECL loss after 96 h of exposure to complex biological fluids. Creatively, a highly integrated platform is equipped with the established biointerface, gas diffusion electrode, and fluidic ECL microreactor, affording high-performance exosome checking and dynamics tracking in a non-label manner. Our study provides a general design strategy to obtain a robust antifouling ECL sensing interface based on zwitterionic chemistries and provides a fresh perspective in developing point-of-care and implantable ECL devices. 相似文献
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4-Bromo-3-methylanisole is mainly used to synthesize black fluorane dye(2-anilino-3-methyl-6-dibutylaminofluorane, ODB-2), which is one of the most important heat and pressure-sensitive dyes in the manufacture of thermal papers. Compared to the industrial heterogeneous batch process, a continuous homogeneous bromination technology in a modular microreaction system has been developed, and 4-bromo-3-methylanisole has been successfully prepared through high-selective mono-bromination of 3-methylanisole with Br_2 solution in CHCl_3. In optimal conditions, the content of bis-brominated byproducts can be controlled less than 0.5%,which is superior to the industrial standard with 99.5% 3-methylanisole conversion at very short residence time and mild reaction temperature. 相似文献
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微化学工程中的微反应技术 总被引:9,自引:0,他引:9
微化学工程包括微型单元操作设备,如微型构造的传质、传热、混合、分离和反应设备等、微型传感技术,以及利用微型构造设备进行化学化工研究和生产的微化学工艺体系,其中微反应技术代表了新的化学加工途径,本文重点介绍了微反应技术的概念和一些研究应用实例。 相似文献
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作为一项全新的过程强化技术,连续化微反应技术在香料、香精和化妆品合成中的应用与日俱增。综述了近年来微反应技术在香料合成研发和生产方面的进展。与传统的间歇式反应器不同,连续化微通道反应器的主要特点是连续进料、传质换热能力大大加强以及可以精确控制反应参数等。该技术在许多香料合成常用的反应中都体现出了常规反应器无法比拟的优势,同时在合成香料工业应用的成功范例也展示了微反应技术可以预见的广阔前景。 相似文献
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