NGO-Ⅲ催化剂的异构化性能评价

直馏汽油非临氢高效异构化使用最新一代NGO－Ⅲ型催化剂，生产的产品汽油辛烷值、产品收率及催化剂稳定性等全面超过现用的工业催化剂，达到目前国内同类产品的领先水平。     

Sodium silicate as a coke inhibitor during naphtha pyrolysis

Rates of coke formation during steam pyrolysis of naphtha have been investigated in a jet-stirred reactor both for sodium silicate coated and uncoated Inconel 600 surfaces in the temperature range of 1078–1108 K. Coke formation rates were significantly reduced on sodium silicate coated plates due to the passivation of the metal surface. However, the coking rates gradually increased with successive decokings of the coated surface.     

石脑油型加氢裂化催化剂的研制

采用共沉淀方法合成了石脑油一中氢裂化催化剂。在１００ｍＬ小型加氢装置上，对金属和分子筛含量等因素进行了考察，结果表明，研制的石脑油型加氢裂化催化剂具有初活性反应温度低，活性稳定性好等特点。     

Optimizing Naphtha Utilization Based on Molecular Scale Management

The technology of separating normal paraffins from naphtha through adsorption using 5A molecular sieves was studied. The separation efficiency of the normal paraffins was above 99.99%. Using the desorption oil as the feedstock of steam cracking, the ethylene yield increased from 29.7-35.0% to 41.4-49.2% compared to that of the naphtha. The research octane number of the raffinate oil reached more than 85 units with an increase of 20 units compared to that of naphtha.     

制备轻油蒸汽转化制氢镍催化剂新的共浸法

用一种新的共浸法制备一批轻油蒸汽转化催化剂样品。运用TG、DTG、DSC和XRD进行的研究发现,与一般共浸法相比,这种着重提高组份间相互作用的新制法有利于提高镍催化剂的活性、抗积炭性、稳定性和金属镍的分散度,并发现用新法制备的催化剂样品,在水热初期约30小时的过程中,出现了镍晶粒先聚集再分散的新现象。     

第二套常减压装置低温热回收技术的应用

常减压装置低温余热较多.利用较少,造成热量损失。利用初顶油气、稳定石脑油等低温余热加热除盐水建立热水站,在节汽、节电等方面取得了较好的效果。     

气相色谱法测定石脑油中含氧化合物含量

本文论述了利用气相色谱法检测石脑油中含氧化合物的方法,考察了无阀切换技术、分离模式的设计、操作条件的优化等方面的问题。提出利用多维气相色谱法,采用一根非极性柱和一根极性柱进行独立和串联分离,通过改变辅助载气压力的无阀切换方式进行柱分离,应用双FID检测器进行信号检测,数据利用Agilent的chemestation工作站采集和输出。该方法操作简单,分析时间在23 min以内,重复测定结果的相对标准偏差(RSD)小于1.5%,标准加入回收率在95～105%范围内,方法准确可靠。     

乙烯装置技术改造总结

由于原料变化，乙烯装置生产能力下降，为此，盘锦乙烯工业公司对乙烯装置进行改造，。使之适应石脑油加轻烃的生产，且达到并超过原设计生产能力。     

High efficient separation of olefin from fluid catalytic cracking naphtha: Separation mechanism and universal simulation method

The fluid catalytic cracking (FCC) naphtha critical component-oriented separation process is an efficient method to produce ultra-low-sulfur (<10 μg/g) gasoline with minimal loss of octane number (<1 RON). However, the product quality is highly dependent on the structure of the components of FCC naphtha. Aromatics and thiophene sulfides without a methyl side chain favor the separation of olefin. The major impulse of olefin separation is the solvent-induced dipole of aromatics or thiophene sulfides, leading to a “Plane-to-Plane” combination between the solvent and aromatics or thiophene sulfides, accompanied by a steric hindrance due to their side chains. This condition resulted in 2–3 times greater θ of benzene and thiophene compared with that of toluene and 3-methylthiophene. In addition, an improved non-random two-liquid model was proposed based on the above results, and a simulation method for FCC naphtha solvent extraction process was established. The calculation results accorded well with industry data.