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1.
Nitrile rubber (NBR) blends with excellent performance have always been a hot research topic in petroleum field. Due to the excellent performance and compatibility of polyamide 6 (PA6), it provides an opportunity for the preparation of high-performance NBR/PA6 blends. In this article, NBR/PA6 blends were prepared by the three-step molding process. Experimentally, it was found that PA6 has a prominent reinforcement effect in NBR matrix. The variation of this mechanical property was investigated from different aspects of the crystal structure, crystallinities, phase morphology, and so on. It can be cleared that the formation of fibrous structure of PA6 phase is the main factor for reinforcement of the polymer blends. Meanwhile, the formation mechanism of the special phase structure induced by the three-step process is deeply expounded and its structural evolution schematic is established. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47472. 相似文献
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丁腈橡胶/导电粒子复合材料的正温度系数(PTC)特性 总被引:7,自引:0,他引:7
将导电粒子碳黑和铜粉分别与丁腈橡胶混合制备导电聚合物复合材料,其中碳黑(N550)/丁腈橡胶复合材料的电阻率随温度的变化呈现较强的正温度系数(PTC)效应。讨论了掺入导电粒子浓度、结构和表面性质以及混炼硫化工艺等对该类材料的室温电阻率及PTC效应的影响。 相似文献
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将聚丁二酸丁二醇酯(PBS)与氢化丁腈橡胶(HNBR)通过熔融共混的方法制备了可以降解的PBS/HNBR共混橡胶。利用X射线衍射(XRD)和扫描电子显微镜(SEM),分别对水解前后的PBS/HNBR共混橡胶的晶体结构、表面的微观形貌进行了表征。研究了不同的PBS/HNBR共混比对混炼胶的硫化特性、水解前后力学性能、降解性能的影响。结果表明:PBS与HNBR共混并未影响PBS的晶体结构,PBS能较均匀地分散在HNBR橡胶基体中。在150 ℃的强碱溶液条件下,PBS/HNBR共混橡胶出现了一定程度的降解,且随着PBS用量的增加,降解速率提高。当PBS用量为50 g时,共混橡胶的降解程度达到19.50%,拉伸强度、断裂伸长率和硬度都有下降。 相似文献
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The catalytic hydrogenation of acrylonitrile‐butadiene copolymer (nitrile rubber, NBR) using Pd(OAc)2 or RuCl2(PPh3)3 catalysts has been investigated in order to produce a totally saturated nitrile rubber. The hydrogenation of NBR is effective with both catalysts and achieved total conversion under the appropriate reaction conditions. In the case of palladium the effects of reaction parameters such as reaction temperature, pressure, time, catalyst concentration, and NBR concentration have been investigated. Even though both ruthenium‐ and palladium‐based catalysts are effective in the production of HNBR, the former requires harsh reaction conditions and has the drawback of gel formation under high conversion, motivating the migration to RuCl2 (PPh3)3 as an alternative catalyst. The degree of hydrogenation was determined by IR and NMR spectroscopy. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007 相似文献
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甲基丙烯酸锌在NBR/木质素中的应用 总被引:5,自引:5,他引:5
研究了α-甲基丙烯酸锌(MAA-Zn)对NBR/木质素(100/100,质量比)硫化胶性能的影响。结果表明,加入1.5~5.0份MAA-Zn,可提高硫化胺的100%的定伸应力,硬度和抗压缩永久变形能力,但对其他力学性能影响甚微,经分析可知,MAA-Zn还可以降低硫化反应活化能,提高硫化胶的交联密度和耐热老化性能。 相似文献
7.
Zinc oxide (ZnO) nanoparticles assembled in one dimension to give rod‐shaped morphology were synthesized. The effect of these ZnO nanoparticles (average particle size ~ 50 nm) as the curing agent for carboxylated nitrile rubber was studied with special attention to cure characteristics, mechanical properties, dynamic mechanical properties, and swelling. These results were compared with those of the conventional rubber grade ZnO. The study confirmed that the ZnO nanoparticles gave a better state of cure and higher maximum torque with a marginal decrease in optimum cure time and scorch time. The mechanical properties also showed an improvement. There was an increase in tensile strength by ~ 120%, elongation at break by ~ 20%, and modulus at 300% elongation by ~ 30% for the vulcanizate cured with ZnO nanoparticles, as compared with the one containing rubber grade ZnO. Dynamic mechanical analysis revealed that the vulcanizates exhibited two transitions—one occurring at lower temperature due to the Tg of the polymer, while the second at higher temperature corresponding to the hard phase arising due to the ionic structures. The second transition showed a peak broadening because of an increase in the points of interaction of ZnO nanoparticles with the matrix. The tan δ peak showed a shift towards higher Tg in the case of ZnO nanoparticle‐cured vulcanizate, indicating higher crosslinking density. This was further confirmed by volume fraction of rubber in the swollen gel and infrared spectroscopic studies. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
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