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1.
Abdul Rahman Mohtasebzadeh Longfei Ye Thomas M. Crawford 《International journal of molecular sciences》2015,16(8):19769-19779
We study magnetic-field directed self-assembly of magnetic nanoparticles onto templates recorded on perpendicular magnetic recording media, and quantify feature width and height as a function of assembly time. Feature widths are determined from Scanning Electron Microscope (SEM) images, while heights are obtained with Atomic Force Microscopy (AFM). For short assembly times, widths were ~150 nm, while heights were ~14 nm, a single nanoparticle on average with a 10:1 aspect ratio. For long assembly times, widths approach 550 nm, while the average height grows to 3 nanoparticles, ~35 nm; a 16:1 aspect ratio. We perform magnetometry on these self-assembled structures and observe the slope of the magnetic moment vs. field curve increases with time. This increase suggests magnetic nanoparticle interactions evolve from nanoparticle–nanoparticle interactions to cluster–cluster interactions as opposed to feature–feature interactions. We suggest the aspect ratio increase occurs because the magnetic field gradients are strongest near the transitions between recorded regions in perpendicular media. If these gradients can be optimized for assembly, strong potential exists for using perpendicular recording templates to assemble complex heterogeneous materials. 相似文献
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Fernando J Beltrn F Javier Rivas Olga Gimeno 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(9):973-984
Photocatalytic ozonation (1O3 + VUV + TiO2), ozonation (O3), catalytic ozonation (O3 + TiO2), ozone photolysis (O3 + VUV), photocatalysis (TiO2 + VUV) and photolysis (VUV) have been compared in terms of formation of intermediates, extent of, mineralization (TOC, COD, chloride, nitrate) and kinetics in the aqueous treatment of three phenols (phenol, p‐chlorophenol and p‐nitrophenol). In all cases, photocatalytic ozonation led to lower degradation times for chemical oxygen demand and total organic carbon removal. Intermediates formed were similar in the different oxidation systems with some exceptions. They can be classified into three different types: polyphenols (resorcinol, catechol, hydroquinone), unsaturated carboxylic acids (maleic and fumaric acids) and saturated carboxylic acids (glyoxylic, formic and oxalic acids). First order kinetic equations have been checked for the oxidation processes studied in the case of the parent compound. Rate constants of these systems have also been calculated. Copyright © 2005 Society of Chemical Industry 相似文献
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OomiG KagayamaT SmithJL LacerdaAH KajiS OhashiM 《中国稀土学报(英文版)》2004,22(1):7-12
Electrical resistance, thermal expansion, lattice constants of the intermediate valence materials, α-Ce and CeBe13, were measured at high pressure. It is found that the Grttneisen parameters of Kondo temperature TK are 13 and 42 for α-Ce and CeBe13, respectively, and it decreases with increasing pressure. The magnetoresistance of α-Ce shows H^2 dependence and its coefficient increases with pressure below 1 GPa, but becomes nearly constant above 1 GPa. The results indicate that the intermediate valence states are enhanced at high pressure indicating the enhancement of hybridization between the 4f electron and conduction band. 相似文献
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利用垂直阵列构作了一类Cartesian认证码,计算了它们的参数,并且在编码规则按等概率分布选取时,成功的模仿攻击和成功的替换攻击概率也被算出。 相似文献
8.
Studies on Catalytic Side-Chain Oxidation of Nitroaromatics to Aldehydes with Oxygen 总被引:2,自引:0,他引:2
The side-chain oxidation of 2-nitrotoluene in liquid phase in the presence of catalytic amount of manganese sulfate and stoichiometric amount of potassium hydroxide with oxygen was studied. In the most favorable conditions, over 80% of conversion of 2-nitrotoluene and 50% of selectivity to 2-nitrobenzaldehyde was achieved. Effects of the reaction parameters on the conversion of the reactant and the selectivity of the product were examined. These results, together with EPR spectroscopic study, show that a benzyl anion was formed in the early stage of the reaction, which was then converted to the final product via a free radical mechanism. 相似文献
9.
The single-pole tip (SPT) heads made of the high saturation FeCo ferromagnetic metals are crucial for the actualization of ultrahigh density perpendicular recording. The effective head field distribution in the medium is of key importance for the design of the SPT head, which would be analyzed by micromagnetic simulations in this work. Two 3D micromagnetic models of the SPT head were established to select a more appropriate method of modeling, with a magnetostatic image effect or a real soft magnetic material to model the image of the SPT head in soft under layer (SUL). The results from these two designs were tested and compared to the ideal head field calculated by the Jacobi finite element method (FEM); and the design with the real soft magnetic material as image was proved suitable for simulating the ultrahigh density perpendicular recording write head. 相似文献
10.
实验考察了8种市售水溶性破乳荆对长庆油田陕北区有代表性的宝塔区、安塞和子长原油(均为低硫中间基-石蜡基原油)的脱水效果(加量100mg/L,脱水温度55℃,时间3h)。目前长庆采油一厂使用的YT-100和延炼集团使用的GT-940对这3种原油的脱水效果均较好,但对子长原油的脱水率不高,分别为69.7%和58.9%。在由所选性能较好的破乳刺组成的4种二元复配物中,GT-940 HQ96-1对3种原油的脱水效果均高于单剂,最佳配比分别为4:1,4:1,3:2;其余3种复配物则对原油有选择性,其中GT-940 YT-100相近(97.5%);YT-100 HQ96-1仅能改善子长原油的脱水效果,配比为4:1时脱水率最高(76.4%);SP-169 HQ96-1仅能改善宝塔区原油的脱水效果.配比3:2和2:3时脱水率最高(92.9%)。表5参6。 相似文献