首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5252篇
  免费   238篇
  国内免费   325篇
电工技术   92篇
综合类   227篇
化学工业   2138篇
金属工艺   835篇
机械仪表   37篇
建筑科学   97篇
矿业工程   127篇
能源动力   45篇
轻工业   749篇
水利工程   16篇
石油天然气   866篇
武器工业   16篇
无线电   37篇
一般工业技术   307篇
冶金工业   147篇
原子能技术   11篇
自动化技术   68篇
  2024年   17篇
  2023年   66篇
  2022年   290篇
  2021年   315篇
  2020年   150篇
  2019年   127篇
  2018年   119篇
  2017年   170篇
  2016年   185篇
  2015年   166篇
  2014年   249篇
  2013年   273篇
  2012年   386篇
  2011年   350篇
  2010年   245篇
  2009年   279篇
  2008年   204篇
  2007年   302篇
  2006年   275篇
  2005年   249篇
  2004年   224篇
  2003年   185篇
  2002年   174篇
  2001年   145篇
  2000年   122篇
  1999年   103篇
  1998年   74篇
  1997年   75篇
  1996年   58篇
  1995年   48篇
  1994年   39篇
  1993年   32篇
  1992年   30篇
  1991年   18篇
  1990年   17篇
  1989年   10篇
  1988年   13篇
  1987年   7篇
  1986年   3篇
  1985年   4篇
  1984年   7篇
  1983年   1篇
  1982年   2篇
  1981年   2篇
  1980年   1篇
  1978年   1篇
  1977年   1篇
  1976年   1篇
  1975年   1篇
排序方式: 共有5815条查询结果,搜索用时 15 毫秒
1.
含动力学抑制剂的天然气水合物相平衡研究对新型低剂量抑制剂的开发具有指导作用。在283.6 ~ 290.9 K和7.51 MPa ~ 15.97 MPa的温压范围内研究了抑制剂Inhibex501及其溶剂2-乙二醇单丁醚对甲烷水合物相平衡条件的影响。实验结果显示,0.5wt%和2.0wt%浓度的Inhibex501对甲烷水合物形成的热力学条件具有促进作用,能使甲烷水合物形成移向更高的温度或者更低的压力,而2-乙二醇单丁醚在浓度0.2wt% ~ 1.0wt%范围几乎不改变甲烷水合物形成的热力学条件,N-乙烯基己内酰胺与N-乙烯基吡咯烷酮的共聚物对水合物形成热力学条件的改变起主要作用。  相似文献   
2.
Sol–gel films are actively investigated during the last decade as possible candidates for environmentally friendly pre-treatments. However, the important drawback in this case is the lack of active corrosion protection and self-healing ability.  相似文献   
3.
低压铝箔交流腐蚀研究   总被引:4,自引:2,他引:2  
在30Hz频率下,通过铝箔在HCl+H2SO4+HNO3+H3PO4体系中的交流腐蚀,研究腐蚀液组成中腐蚀主体及缓蚀剂对铝箔腐蚀的作用,探讨腐蚀过程中电源频率、腐蚀液温度、电流密度及腐蚀时间对铝箔腐蚀的影响。腐蚀液组成的配比恰当,有利于比容的提高。在特定的频率下采用合适的腐蚀液温度、适宜的电流密度和腐蚀时间可以提高铝箔的静电容量。  相似文献   
4.
The presence of protease inhibitors in soybean prohibits the utilisation of the raw beans for food and feed. However, little information is available about environmental influences and the effects of nitrogen and sulphur supply on the antinutritional constituents of soybean. As these factors may influence protease inhibitors, soybean genotypes segregated according to the presence or absence of the Kunitz trypsin inhibitor have been evaluated for trypsin inhibitor activity (TIA) in field trials. TIA was affected significantly by environment (geographical location), fertilisation treatment and genotype. Environmental means of TIA were between 69.5 and 104.8 mg g?1. Nitrogen application, which caused an increase in seed protein content, resulted in a reduction in TIA by about 15% as compared with the control. Remarkably, simultaneous application of nitrogen and sulphur in the form of ammonium sulphate had a similar reductive effect on TIA to that of nitrogen application alone, although soybean protease inhibitors are rich in sulphur amino acids. Significant genetic variation in TIA was found both within the genotype class with the Kunitz inhibitor present as well as within the class lacking this inhibitor. The results suggest that TIA of soybean may be modified considerably by genetic improvement and appropriate agronomic management. Copyright © 2003 Society of Chemical Industry  相似文献   
5.
ABSTRACT: A new natural apple polyphenol oxidase (PPO) inhibitor(s) from housefly ( Musca domestica L.) was discovered. Crude inhibitor (s) isolated by buffer extraction, heat treatment, and dialysis from housefly pupae inhibited the activity of apple PPO up to 90% at pH values above 5.0. Inhibition was strictly pH-dependent. The inhibitor(s) was further characterized by employing heat, freezing and thawing, irradiation, pH adjustment, and ultrafiltration studies. The potential PPO inhibitor(s) was stable to heating at 100 °C for 1 h, repeated freezing and thawing, and irradiation. The inhibitor(s) was most stable at pH around 5.0 and least stable at alkaline pH. The PPO inhibition profile of housefly during metamorphosis also was evaluated.  相似文献   
6.
钼酸盐阻燃抑烟剂研发现状   总被引:2,自引:1,他引:1  
简要地叙述了钼酸盐类阻燃抑烟剂 ,如八钼酸铵、钼酸锌、钼酸钙、钼酸钴和三氧化钼等阻燃抑烟剂的研发现状  相似文献   
7.
Preexposing rats to the context facilitates subsequent contextual fear conditioning. This effect depends on the hippocampus (J. W. Rudy, R. M. Barrientos, & R. C. O'Reilly, 2002). The authors report that inactivating the basolateral region of the amygdala (BLA) by injecting muscimol, a GABAA agonist, before or after preexposure reduced this effect. In contrast, bilateral injections of anisomycin, a protein synthesis inhibitor, into BLA did not impair the consolidation of the context memory. However, when injected after fear conditioning, anisomycin impaired consolidation of both contextual and auditory-cue fear conditioning. Results are consistent with 2 ideas about the amygdala's contribution to memory: (a) It modulates memory formation in other regions of the brain, and (b) it is a storage site for cue-shock associations. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
8.
为控制CO2腐蚀,合成了含氮杂环季铵盐缓蚀剂9912-1,通过电化学实验,研究了该缓蚀剂在CO2-3%NaCl-H2O体系中对碳钢于25℃和90℃下的缓蚀行为。实验结果与挂片失重法测试的结果基本一致。低温下缓蚀效果优于高温下的缓蚀效果。而且该缓蚀剂与硫脲有很好的协同效应。Tafel曲线表明,该缓蚀过程是以控制阴极腐蚀为主,并对其缓蚀机理进行了初步探讨。  相似文献   
9.
油气田开发中的CO2腐蚀及防护技术   总被引:17,自引:1,他引:16  
综述了二氧化碳均匀腐蚀和局部腐蚀的机理,分析了二氧化碳腐蚀的各种影响因素,并对二氧化碳腐蚀的防护技术进行了概括,着重介绍了缓蚀剂防护技术研究进展,并提出了研究CO2腐蚀及其缓蚀剂应注意的几个问题。  相似文献   
10.
A study based on the corrosion inhibition properties of copper phthalocyanine is described. Coverage degrees of copper phthalocyanine (Cu-phcy) on ASTM-A606-4 steel, obtained by weight loss measurements, were fitted to Langmuir, Frumkin, Temkin and Flory–Huggins adsorption isotherms. A better fit to the Langmuir isotherm was obtained. The polarization curves showed that polarization of both the anodic and cathodic reactions were verified for concentrations higher than 10–4 M, indicating a mixed type action. Only the anodic reactions were polarized for lower concentrations. At high frequencies the Nyquist diagrams showed one capacitive loop attributable to double layer charging and a small one at intermediary frequencies attributable to the faradaic process of hydrogen evolution. The formation of an adsorbed film was characterized by increasing charge transfer resistance values in the low frequency range for increasing inhibitor concentrations. According to the techniques used in this study, copper phthalocyanines showed a high corrosion inhibiting efficiency for all concentrations.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号