偶氮聚合物光存储研究进展

着重阐明了偶氮聚合物光存储纪录的原理,分析了其双折射特性的微观机制,介绍了该课题近年来实验和理论上的最新进展,对这一充满希望和挑战的多学科交叉研究专题作了展望。     

甲烷无氧芳构化研究进展及其工业应用前景

综述了最近20多年来甲烷无氧芳构化催化剂的制备、积炭失活和再生方面的研究进展，特别分析了催化剂再生过程的工程化问题及反应器型式；还根据甲烷芳构化技术产业化的需要，分析了甲烷芳构化技术的发展趋势。     

Cd-ZSM-5沸石催化剂的制备、表征和芳构化催化性能

采用离子交换、浸渍和混合三种方法制备镉改性ZSM-5沸石催化剂,考察了改性方法和镉含量对催化剂的表面酸性和Cd状态以及芳构化性能的影响。结果表明,加入镉降低了B酸性,Cd~(2+)与沸石结合形成了L_(1612)酸中心,其生成量取决于改性方法和Cd含量,并与芳构化活性提高有直接关系。     

新型重整催化剂的研究——Pt／L中沸石酸碱性的作用

Ｐｔ／ＫＬ、Ｐｔ／ＢａＫＬ及Ｐｔ／ＨＬ上的铂与沸石的酸碱位发生相互作用，导致催化剂上存在不同电子状态和粒度分布的铂位，从而产生有着完全不同催化作用、不同抗硫性能的两类催化剂，即以碱性沸石为载体的“单功能”催化剂和以酸性沸石为载体的“双功能”催化剂。在Ｐｔ／ＫＬ、Ｐｔ／ＢａＫＬ催化剂上，存在着对硫敏感的具有环化脱氢功能和对硫不敏感的仅具有脱氢功能的两类铂活性位。     

Influence of ZnO and P2O5 Content on Modified HZSM-5 on Aromatization of FCC Gasoline

Catalytic properties of different content of ZnO and P₂O₅ supported on HZSM-5 zeolites were studied in the conversion of FCC gasoline (75°C-120°C) into aromatic hydrocarbons with a temperature of 430°C, a liquid hourly space velocity of 1.0 hr^-1, and a pressure of 0.1 MPa. In the reaction, when the contents of ZnO and P₂O₅ are 2% and 4%, respectively, Zn-P/HZSM-5 showed the highest selectivity and activity to aromatic hydrocarbons and conversion of olefins. The content of aromatics in the liquid product and the yield of aromatics reached as high as 94.53%, 68.87%, and 51.74%, respectively.     

Optical data storage by novel photoelectrochromic polymer

A novel elastic polymer containing 4,4′-bipyridinium salts with tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as part of the main chain was synthesized. The cast film showed persistent and reversible colour changes due to photoinduced electron transfer upon excitation of an ion-pair charge-transfer band (_ex >365 nm) in vacuo. The lifetime of the coloured state markedly depended on temperature. The optically written data were stored without decay below 0°C and were erased thermally at elevated temperatures. The colour changes were reversibly repeatable for many times.     

载体及反应条件对Pt/BaKL沸石催化剂芳构化性能的影响

研究了γ-Al_2O_3或SiO_2载体,以及反应条件对Pt/BaKL沸石催化剂芳构化性能的影响。发现经过碱化或负载Sn的γ-Al_2O_3作为载体,能够较好地保持该催化剂在正己烷芳构化反应中的高活性和高选择性,并有益于改善Pt/BaKL沸石催化剂的抗硫性能。     

共轭聚合物／C60复合体系及其在光伏打电池中的应用

共轭聚合物／C60复合体系在有机太阳能电池中的应用引起了化学工作者的广泛兴趣。本文介绍了共轭聚合物／C60复合体系的光诱导电子转移，以及近年来该体系在光伏打电池中的研究进展。     

Hydrogen sorption sites in the gallium containing hybrid catalysts used for the aromatization of light alkanes

Gallium species which were incorporated initially in the oxide form, were all in the (+3) oxidation state in the hybrid catalyst and exhibited two types of hydrogen chemisorption sites, s_hw and s_hs. The stronger sorption sites shs which predominated at higher gallium dispersion, corresponded probably to the most effective surface configuration for gallium in the aromatization ofn-butane.     

2－芳基苯并噁唑的荧光猝灭和光诱导电子转移研究

本工作对两种不同的２－芳基苯并　唑化合物溶液荧光被四氯化碳所猝灭的机理进行了详细研究，通过多种途径研究表明该猝灭过程具有光诱导电子转移性质，工作还利用此电子转移所形成的活泼自由基来引发烯类单体的聚合，得到了有一定聚合度的聚甲基丙烯酸甲酯。