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排序方式: 共有8132条查询结果,搜索用时 15 毫秒
1.
Aniruddha Nag Mohammed Asif Ali Jiabei Zhou Makoto Ogawa Tatsuo Kaneko 《大分子材料与工程》2021,306(11):2100459
Aromatic and functional polymers with processibility derived from biobased starting materials are prerequisite considering sustainable society. Poly(2,5-benzimidazole)s are rigid-rod polymers to show ultrahigh thermal stability such as flame retardance, while usually suffer from poor solubility. Here, poly(benzimidazole-co-amide)s are synthesized from two biobased monomers, 3,4-diaminobenzoic acid and a semirigid comonomer, 4-aminohydrocinnamic acid. The copolymers with an amide composition of 80 mol% and higher are soluble in widely used polar solvents to fabricate the films keeping high flame retardance, which is comparable with popular high-performance polymers such as aromatic polyimides, polyetheretherketone, polyphenylene sulfide, etc. 相似文献
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Thermally conductive polymers offer new possibilities for the heat dissipation in electric and electronic components, for example, by a three‐dimensional shaping of the heat sinks. To face safety regulations, improved fire performance of those components is required. In contrast to unfilled polymers, those materials exhibit an entirely different thermal behavior. To investigate the flammability, a phosphorus flame retardant was incorporated into thermally conductive composites of polyamide 6 and hexagonal boron nitride. The flame retardant decreased the thermal conductivity only slightly. However, the burning behavior changed significantly, due to a different heat propagation, which was investigated using a thermographic camera. An optimum content of hexagonal boron nitride for a sufficient thermal conductivity and fire performance was found between 20 and 30 vol%. The improvement of the fire performance was due to a faster heat release out of the pyrolysis zone and an earlier decomposition of the flame retardant. For higher contents of hexagonal boron nitride, the heat was spread faster within the part, promoting an earlier ignition and increasing the decomposition rate of the flame retardant. 相似文献
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Nitrile rubber (NBR) blends with excellent performance have always been a hot research topic in petroleum field. Due to the excellent performance and compatibility of polyamide 6 (PA6), it provides an opportunity for the preparation of high-performance NBR/PA6 blends. In this article, NBR/PA6 blends were prepared by the three-step molding process. Experimentally, it was found that PA6 has a prominent reinforcement effect in NBR matrix. The variation of this mechanical property was investigated from different aspects of the crystal structure, crystallinities, phase morphology, and so on. It can be cleared that the formation of fibrous structure of PA6 phase is the main factor for reinforcement of the polymer blends. Meanwhile, the formation mechanism of the special phase structure induced by the three-step process is deeply expounded and its structural evolution schematic is established. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47472. 相似文献
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In this article, the silver-plated polyamide fabrics (SPPAFs) with high electroconductibility and shielding effectiveness were fabricated by using in situ reduction of polydopamine and chemical silvering. The effects of SPPAFs dopamine (C8H11O2N) and silver nitrate (AgNO3) concentration on surface resistivity and electromagnetic interference shielding effectiveness were studied. The results showed that the surface resistivity of SPPAFs can reach a minimum value of 0.06 ± 0.014 Ω cm−1, when C8H11O2N concentration is 4 g L−1 and the AgNO3 concentration is 120 g L−1. The shielding effectiveness of SPPAFs in the wide frequency range of 10–3000 MHz increases with the increase in the concentration of AgNO3, and increases first and stabilizes afterward with increasing C8H11O2N concentration. When the concentration of C8H11O2N and AgNO3 is 3 and 120 g L−1, respectively, mean shielding effectiveness values in the low-, medium-, and high-frequency bands are 71.3, 73.8, and 76.1 dB, respectively. Moreover, the mean shielding effectiveness values is 83.79 dB in the frequency range of 1.2–2.3 GHz. The dominant shielding mechanism of SPPAFs is the reflected electromagnetic waves and the absorption shielding effectiveness is less than 2 dB. The average electromagnetic shielding values of SPPAFs are above 67 dB after 16 weeks of storage, when C8H11O2N concentration is 4 g L−1 and the AgNO3 concentration is 80 and 100 g L−1. The prepared SPPAFs show promising applications in military textiles and smart wearable clothing. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48227. 相似文献
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本文从理论上研究了控制初始弯曲引起的转子振动幅值的一种新方法。通过在与转轴初始弯曲方向成较大夹角的方向添加不平衡质量的方法 ,使转子新的不平衡方向与初始弯曲方向夹角接近 180° ,则可以减小转子在临界转速附近的振幅。无论新的不平衡参数大于或小于初始弯曲参数 ,只要新的不平衡参数不至于太大 ,则临界转速附近的振幅响应肯定会得到改善。特别是当新的不平衡参数近似等于初始弯曲参数时 ,无论转速高低 ,振幅都会大幅下降。当重力参数、外阻尼系数和内阻尼系数改变后仍有同样结论。本文援引文献 [2 ]中的实例对这种方法进行了验证 ,并给出了解决类似故障的步骤。本文的方法可用于处理生产实际中转轴初弯引起的振动问题 相似文献
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端电压比较法直接寻找无刷直流电动机换相点及其斩波调速 总被引:4,自引:0,他引:4
提供了一种利用端电压比较结合软件算法直接寻找直流无刷无位置传感器电动机换相点的方案,解决了直流无刷无位置传感器电动机控制的关键问题-转子位置检测,并以单片机PIC16C72为核心构成先进的数字控制系统,实现了软件斩波调速。 相似文献
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本文提出励磁电流可自动控制的他励式双高调速系统设计方案。系统在提升特别是在下放重物时,具有较硬的机械性;在负载10-100%的变化范围内,可实现最大偏差Δnmax/nmin100%≤10%,调速范围D≥10;在满载运行条件下,可节约电能80%以上。 相似文献