Dynamic-mechanical properties of polybutadiene rubbers

The dynamic properties of high-cis (98%) and cis-trans (42% cis) polybutadienes, crosslinked with 0.1 to 1.0% of crosslinking agent, have been studied using a torsion pendulum method over the temperature range ?170 to +20°C. For the high-cis rubber plots of damping factor (tan δ) against temperature showed the expected peak in the glass-transition region with an additional peak in the neighbourhood of 0°C attributable to crystallization. The cis-trans rubber showed two damping maxima in the transition region, separated by 30 to 40°C (depending on the degree of crosslinking), suggesting incipient phase separation of the component structures. The rebound resilience of the high-cis rubber at room temperature exceeded that of the cis-trans, reaching 92% at the highest crosslink density. Plots of resilience versus temperature for both rubbers showed a single minimum in the glass transition region.     

Linear viscoelastic properties of mixtures of 3- and 4-arm polybutadiene stars

The viscoelastic properties of a three-arm and a four-arm star polybutadiene with the same arm molecular weight (M_a) were studied. The zero-shear recoverable compliance (J⁰_e) and plateau modulus (G⁰_N) for these stars are the same. The zero-shear viscosity (η₀) of the three-arm star is 20% lower than that of the four-arm star. Mixtures of the stars had J⁰_e and G⁰_N unchanged. A $\text{50}\text{50}$ mixture of the three- and four-arm star was diluted with a low molecular weight linear polybutadiene. G⁰_N∝ø²; J⁰_e∝ø^?1 and M_e∝ø^?1, as expected for dilution with a θ-solvent.     

顺丁橡胶生产过程"门尼升值"的原因研究

研究了顺丁橡胶生产过程中门尼升值的原因。结果表明，顺丁橡胶生产后处理的膨胀干燥过程存在门尼升值现象。不同内在质量的顺丁橡胶门尼升值不同，正常条件下门尼升值发生于门尼粘度的测试过程。     

含RDX的硝胺丁羟推进剂能量特性研究

采用最小自由能平衡流法对RDX/AP/Al/HTPB推进剂能量特性进行了理论计算。通过BSF165mm和BSF315mm发动机点火试验,研究了RDX含量、燃烧室压强对RDX/AP/Al/HTPB推进剂能量特性的影响规律。根据理论计算和发动机试验结果,对配方进行了优化设计,与某型号760mm全尺寸发动机的实测结果对比,其实测比冲高达2428.1N·s·kg-1(pc=6.86MPa),验证了RDX的加入对RDX/AP/Al/HTPB推进剂比冲有较突出贡献。     

液体聚丁二烯的环氧化

分析了影响环氧化聚丁二烯合成条件的诸多因素、原料以及产物的结构，为该产品的实际应用创造条件。     

Aging and mechanical properties of NR/BR blends

The mechanical properties and post-thermal aging properties of natural rubber (NR) and polybutadiene rubber (BR) blends at different blending ratios are investigated herein. The experimental results show that both tensile and tear strengths of NR/BR blends increase with increasing NR content. BR has a higher compression stiffness than NR. The deformation of BR is less than that of NR under the same load conditions. With regard to aging properties, both tensile stress and strain of NR/BR blends decrease after prolonged aging. In addition, the stress loss of BR is lower than that of NR, meaning that the aging resistance property of BR is superior to that of NR. Furthermore, accumulated thermal history has shifted the glass transition temperature (T _g) of NR/BR blends toward lower temperatures while the loss tangent (tan δ) value increases with prolonged thermal aging.     

镍系聚丁二烯橡胶生产技术进展

介绍了近几年国内外镍系顺丁橡胶生产技术的进展情况，内容涉及分子量调节技术、催化剂配置技术、节能降耗的气相聚合、本体聚合工艺及橡胶后处理过程中使用的热泵技术、螺杆挤压工艺，同时也对国内外顺丁橡胶新型防老剂的使用情况及其新品种的开发进行了简要介绍。     

Plasma graft polymerization of acrylamide onto crosslinked HTPB based PU membrane for pervaporation

Pervaporation of water-ethanol mixtures through plasma graft polymerization of acrylamide onto crosslinked hydroxyl terminated poly-butadiene (HTPB) based PU membranes, plasma graft polymerization of acrylamide onto crosslinked PU membrane (AAm-p-CPU), were investigated. The grafting was dependent on the discharge power and pretreatment period. The effects of crosslinking, plasma treatment conditions, feed compositions, and feed temperature on the performance of these membranes were studied. The physical properties of crosslinked membrane were better than those of the uncrosslinked membrane. In addition, compared with crosslinked PU membranes (CPU), the plasma modified crosslinked PU membranes effectively improve the pervaporation separation performances.     

高柔韧性聚氨酯丙烯酸酯的合成及应用

选用不同结构的多元醇作骨架，合成一系列高性能的聚氨酯丙烯酸树脂，并通过对聚氨酯丙烯酸树脂性能的对比研究，发现以聚丁二烯二元醇为骨架的聚氨酯丙烯酸酯树脂具有极佳的柔韧性和优异的低温耐曲折性。