以表面负载季铵盐阳离子型苯/丙乳胶粒为模板制备ZrO_2空心微球

以C9油与甲基丙烯酰氧乙基三甲基氯化胺的共聚物P(C9-DMC)为乳化剂制备苯/丙阳离子乳胶粒,并以其为模板,利用直接包覆法制备了由17 nm左右微晶体堆成的ZrO2空心微球。所制得的样品采用FT-IR、XRD、TEM和SEM等进行了表征。     

用SBR1502胶浆制取道路沥青改性用胶乳

用附聚法和降粘法浓缩ＳＢＲ１５０２胶浆制取道路沥青改性用胶乳。结果表明：总固物质量分数可由（２１±２）％上升到４５％～５０％。该胶乳与齐鲁石化公司炼油厂１００号乙沥青混合，改性后的道路沥青具有良好的使用性能，可满足高等级路面沥青的技术要求。     

高透明耐冲击聚氯乙烯接枝聚合研究

研究高透明耐冲击聚氯乙烯接枝聚合工艺，讨论了加料顺序、复合分散体系以及采用聚集粒子乳液、并用碱性物质调节其ｐＨ值等对接枝聚合物性能的影响，确定了接枝聚合最佳工艺条件。     

丁苯胶乳改性道路沥青的推广应用

用丁苯胶乳对胜利１００号沥青进行改性试验．发现随着胶乳掺量的增加．沥青的高温性能、粘结性能改善幅度也大。但综合考虑沥青生产成本等因素．认为：对丁苯胶乳改性胜利１００号道路沥青．掺胶量控制在２％即可满足一般高等级道路工程的需要。文中还介绍了丁苯胶乳沥青近年来的推广使用情况并做了相应的技术经济分析和建议。     

A comparative study of short nylon fiber—Natural rubber composites prepared from dry rubber and latex masterbatch

A novel method for the preparation of short nylon fiber–natural rubber composites was developed in which short fibers chopped to approximately 6 mm were incorporated in the latex stage and processed into sheet form. By this method, mixing cycle time was reduced without compromising the fiber dispersion. Fiber breakage during mixing was reduced. The new composites when compounded with a dry bonding system based on hexamethylenetetramine, resorcinol and hydrated silica (HRH) showed improved modulus, tensile strength and abrasion resistance compared to conventional composites. Tear strength, resilience, and compression set were similar to the conventional composites. SEM analysis indicated better interaction between matrix and fibers in the case of latex master batch. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Natural rubber-based nanocomposites by latex compounding with layered silicates

Natural rubber (NR) based nanocomposites with 10 wt% natural and synthetic layered silicates were produced via the latex compounding method. As layered silicates, sodium bentonite (natural) and sodium fluorohectorite (synthetic) were selected in addition to a non-layered inert filler (English India clay or commercial clay) as reference material. The nanocomposites were prepared by compounding the dispersions of clays and other latex chemicals necessary for vulcanization. The vulcanized nanocomposites were subjected to mechanical, thermal and swelling tests. The silicate dispersion was studied by transmission electron microscopy. Layered silicates outperformed the reference material (commercial clay) in all aspects. This was attributed to the intercalation/exfoliation of the silicates and to the formation of a skeleton ‘(house of cards)’ silicate network in the NR matrix.     

一种多官能团乳化剂在羧基丁苯胶乳合成中的应用

试验发现：一种阴离子型兼具非离子性的乳化剂A用于羧基丁苯胶乳聚合体系，可显著提高胶乳的质量，其质量分数即使下降到原配方乳化剂标准用量的25％，也能制备出合格的胶乳；与使用SDS的聚合体系相比，使用乳化剂A的聚合体系的聚合反应及产物质量重复性好，胶乳的钙离子稳定性显著提高。分析发现，乳化剂用量的大小会导致聚合反应机理的差异，从而影响聚合反应及产物质量；在酸性条件下，乳化剂本 身的稳定性也是造成这种差异的原因之一。应用试验结果表明：用乳化剂A代替SDS并在一定范围内改变其用量，不会影响胶乳的应用性能。     

纳米TiO_2改性苯丙乳液内墙涂料的研究

采用物理掺和法,在苯丙乳液中加入锐钛型纳米TiO2,制成内墙涂料,进行抑菌试验和甲醛降解实验研究,分析了纳米TiO2的光催化原理和抗菌机理。结果表明,随着TiO2含量增加,甲醛降解能力和抗菌性能增强,当TiO2含量为4%时效果最好。     

Tailoring HASE rheology through polymer design: Effects of hydrophobe size, acid content, and molecular weight

Hydrophobically modified alkali-soluble emulsion (HASE) polymers are an important class of rheology modifiers for waterborne coatings applications. They are typically prepared as terpolymers by emulsion polymerization of ethyl acrylate (EA), methacrylic acid (MAA), and an associative macromonomer. The viscosity development and shear responses of HASE solutions depend on a number of factors. This article presents rheological data reflecting the impacts of three key variables: hydrophobe size, acid content, and molecular weight, on model HASE thickening and rheological performance. The relative contributions of hydrophobic association, chain expansion, and polymer chain length are discussed. In steady shear flow, all thickener solutions approached some constant low-shear viscosity at small deformation rates. At the same molar composition, larger hydrophobe size resulted in higher viscosity development and greater shear thinning behavior. The amount of acid monomer in HASE polymers can influence the balance between hydrophobic attraction and electrostatic repulsion forces. It was found that a minimum of 15 wt% MAA was required to effect dissolution and thickening of the model HASE polymers. Increasing the MAA level yielded higher zero-shear viscosity and storage modulus G’ with maximal values being obtained at 40% MAA. The molecular weight of the model thickeners was controlled by the amount of chain transfer agent (CTA) added during polymerization. When the CTA level was below 0.1 wt% based on total monomers, the polymer solutions displayed shear-thinning behavior. A small increase in CTA concentration beyond 0.1% resulted in a dramatic change to Newtonian flow, and the solution viscosity was nearly two orders of magnitude lower. The model thickeners were also tested in a vinyl acrylic architectural paint formulation. The effects of each individual factor on paint thickener efficiency, high-shear, and low-shear properties are discussed and compared with solution rheology for predictive relationships. Presented at the 81st Annual Meeting of the Federation of Societies for Coatings Technology, November 11–12, 2003, in Philadelphia, PA.