绿色再生混凝土利用途径与评定思路

就再生混凝土骨料进行深入系统的研究 ,建立了一套与现行评价天然骨料标准相一致的评定方法 ,具有工程实际意义 ,为将来实际应用作好了基础理论研究     

蒸汽凝结水除油试验研究

介绍了利用类萃取技术进行蒸汽凝结水除油的过程。利用具有亲油功能的HOL-100树脂,经过试验和工业应用证明,萃取除油可以达到1．0mg/L以下,可满足炼油化工装置锅炉用水对含油量的要求。HOL-100树脂具有在高温状态下(120℃)除油的特点。通过标定考核,萃取除油技术是一项节能、节水、环保措施,可在中石油和中石化企业推广应用。     

Polymer-Modified Bitumen Using Ethylene Terpolymers

Polymer modified bitumen (PMB) is used in various construction applications, especially in motorways. The aim of this study is to improve features of 60/70 penetration grade, modified bitumen used on highways. Increasing the sensitivity to temperature and oxidation resistance are very important points for the modified bitumen. This condition was provided by reacting the carboxylic acid groups in asphaltene with the reactive ethylene terpolymer to form ester. Reactive ethylene terpolymer (RETP) and ethylene terpolymer (ETP) manufactured by DuPont USA were used as additives in this study. Infrared Spectrophotometer (IR) graphics and optical pictures of the modified bitumen have been examined. It has been observed that the softening point has increased on the other hand, the penetration and ductility values have decreased according to the test results.     

Surface tailoring of an ethylene propylene diene elastomeric terpolymer via plasma‐polymerized coating of tetramethyldisiloxane

In the research presented here, we explore the use of a low‐energy plasma to deposit thin silicone polymer films using tetramethyldisiloxane (TMDSO) (H(CH₃)₂? Si? O? Si? (CH₃)₂H) on the surface of an ethylene propylene diene elastomeric terpolymer (EPDM) in order to enhance the surface hydrophobicity, lower the surface energy and improve the degradation/wear characteristics. The processing conditions were varied over a wide range of treatment times and discharge powers to control the physical characteristics, thickness, morphology and chemical structure of the plasma polymer films. Scanning electron microscopy (SEM) shows that pore‐free homogeneous plasma polymer thin films of granular microstructure composed of small grains are formed and that the morphology of the granular structure depends on the plasma processing conditions, such as plasma power and time of deposition. The thicknesses of the coatings were determined using SEM, which confirmed that the thicknesses of the deposited plasma‐polymer films could be precisely controlled by the plasma parameters. The kinetics of plasma‐polymer film deposition were also evaluated. Contact angle measurements of different solvent droplets on the coatings were used to calculate the surface energies of the coatings. These coatings appeared to be hydrophobic and had low surface energies. X‐ray photoelectron spectroscopy (XPS) and photoacoustic Fourier‐transform infrared (PA‐FT‐IR) spectroscopy were used to investigate the detailed chemical structures of the deposited films. The optimum plasma processing conditions to achieve the desired thin plasma polymer coatings are discussed in the light of the chemistry that takes place at the interfaces. Copyright © 2004 Society of Chemical Industry     

再生砖混骨料混凝土柱的小偏心受压性能

通过小偏心受压性能试验对比研究3根的天然骨料混凝土柱和3根同强度全再生砖混骨料混凝土柱,强度分别为C25、C30和C35. 对6根柱进行加载试验,分析再生砖混骨料混凝土柱相比于同强度天然骨料混凝土柱在受力过程、破坏特征、变形能力与承载力等方面的差异. 试验发现,再生砖混骨料混凝土柱在小偏心加载至破坏的过程中,具有与天然骨料混凝土柱相似的3个受力阶段,且符合平截面假定. 与同强度的天然骨料混凝土柱相比,变形较大,但再生砖混骨料混凝土柱的极限承载力略高,原因可能在于两者轴心抗压强度的差异.     

含活性硅氧烷型大分子改性剂BA-MMA-VTES的合成与表征

针对弱极性天然/丁苯橡胶复合体系,从分子设计的角度出发,选择乙烯基三乙氧基硅氧烷(VTES)、丙烯酸丁酯(BA)、甲基丙烯酸甲酯(MMA)为单体,通过自由基溶液聚合并优化了反应条件:在85℃和115℃分别加入两种不同量的引发剂BPO和DCP,均保温反应2h,合成了三元共聚物BA-MMA-VTES大分子表面改性剂,用于纳米碳化硅、氮化硅陶瓷粉体的表面改性。采用FTIR、NMR、GPC、DSC、TGA等对所合成的三元共聚物的结构、性质和数均相对分子质量进行了分析和表征。通过FTIR、NMR测试结果,证实了BA-MMA-VTES三元共聚物的结构;通过GPC测试,证明BA-MMA-VTES三元共聚物的数均相对分子质量控制在3000～10000;DSC显示合成的大分子只有一个Tg,在3.3℃左右,表明它是无规共聚物,柔性适中;TGA显示三元共聚物主要热分解区间在280～500℃,热稳定性良好。     

动态三螺杆挤出机制备热塑性硫化胶的研究

对比分析了动态热塑性硫化胶(TPV)的加工设备,着重介绍了附加振动力场的三螺杆反应挤出机的结构特点以及利用该机进行三元乙丙橡胶/聚丙烯(EPDM/PP)的动态全硫化,对制品的物理力学性能和微观结构分别进行了测试分析和电镜扫描。结果表明,振动力场作用下EPDM/PP共混体系反应挤出动态硫化加工可有效地实现动态硫化反应、硫化橡胶的粉碎和分散以及相态反转,振动力场的作用明显提高了TPV性能。     

再生混凝土力学性能提升技术与应用

针对大量混凝土废弃物造成生态环境日益恶化及天然骨料资源日益缺乏的问题,通过配制不同强度等级和不同再生骨料掺量的再生混凝土,并结合锡澄运河三级航道整治工程对再生混凝土力学性能及其提升技术进行试验研究。结果表明:再生骨料的掺量对C35及以下中低强度混凝土力学性能影响较小,而对C40及以上中高强度混凝土有较大影响,随再生骨料掺量的增加,再生混凝土力学性能降低;通过合理选用再生骨料级配、与天然骨料复掺、对再生骨料进行强化以及优化配合比参数等措施能提升混凝土力学性能;锡澄运河三级航道整治工程实际应用取得了很好的技术经济效益。     

再生骨料的基本物理力学性能试验研究

再生骨料的物理力学性质是影响其运用范围、再生混凝土性能的本质因素。通过对公路废弃混凝土所制成的再生骨料和天然骨料同时进行物理力学性能试验研究,获得了骨料的表观密度、吸水率、压碎值、磨耗损失和针片状颗粒含量值。通过对再生骨料和天然骨料的试验结果进行对比分析发现,再生骨料除了针片状颗粒含量值会略优于天然骨料,其他四种物理力学性质均比天然骨料差,但两者的差异性不大。     

Mechanical properties of composites from sawdust and recycled plastics

Mechanical properties of wood plastic composites (WPCs) manufactured from sawdust and virgin and/or recycled plastics, namely high density polyethylene (HDPE) and polypropylene (PP), were studied. Sawdust was prepared from beech industrial sawdust by screening to the desired particle size and was mixed with different virgin or recycled plastics at 50% by weight fiber loading. The mixed materials were then compression molded into panels. Flexural and tensile properties and impact strength of the manufactured WPCs were determined according to the relevant standard specifications. Although composites containing PP (virgin and recycled) exhibited higher stiffness and strength than those made from HDPE (virgin and recycled), they had lower unnotched impact strengths. Mechanical properties of specimens containing recycled plastics (HDPE and PP) were statistically similar and comparable to those of composites made from virgin plastics. This was considered as a possibility to expand the use of recycled plastics in the manufacture of WPCs. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3641–3645, 2006